Flame Retardants. Bromine. Magnesium. Nitrogen. Phosphorus

Transcription

1 Flame Retardants Bromine Nitrogen Magnesium Phosphorus

2 ICL INDUSTRIAL PRODUCTS Dear customer! ICL Industrial Products (ICL-IP), the industrial chemicals division of Israel Chemicals Limited, is the world s largest producer of elemental bromine, supplying over 33% of global demand. The company is a leader in the production and marketing of bromine and bromine compounds, and phosphorus-based compounds which are a fundamental component of many products that enhance well-being and, ultimately, save lives. With a heritage dating back to the early 20th Century, ICL has maintained an unwavering focus on innovation, striving to achieve the highest standards across all aspects of our business. We believe that what sets us apart from others are: The quality of our people and our products The world s highest concentration of bromine is found in the Dead Sea, which provides a virtually unlimited supply. ICL-IP s highly skilled workforce uses the latest technologies to harness this rich natural resource, enabling us to produce bromine and bromine-based chemicals as well as minerals of the highest quality, in the most efficient manner. Furthermore, we have applied these skills and technologies to integrate the complementary chemistry of phosphorus, thus developing sustainable products with a broad variety of applications including flame retardants, plasticizers, hydraulic fluids, organic intermediates, water treatment, pharmaceutical chemicals, stabilizers, curing activators, viscosity enhancers, refractory materials, and so on. ICL-IP utilizes Total Quality Management, Lean and Six Sigma methodologies across all its plants worldwide to ensure consistent quality and to achieve improvements in its processes. Our unique approach to customer service ICL-IP is dedicated to meeting, and exceeding, our customers expectations. We offer the advantages of geographic proximity to major markets with internationally based subsidiaries coordinating the supply of finished products to the customers doorstep. We provide experienced technical support, and a workforce fully committed to quality and the protection of the environment. The scale of our production facilities and our integrated supply chain We are where our customers need us to be. ICL-IP s bromine compounds plants in Israel and the Netherlands, along with Sinobrom, a JV in China, offer customer-oriented manufacturing facilities based on long-standing technological expertise. Our market-leading phosphorus-based flame retardants, plasticizers, lubricants and hydraulic fluids, are produced in plants in the US, Germany and China. The company s worldwide marketing subsidiaries are: ICL-IP Europe B.V., The Netherlands; ICL-IP Israel Sales Office; ICL-IP America Inc., USA; ICL-IP Japan Ltd., Japan; ICL Asia Ltd., Hong-Kong; ICL China, PR China and ICL Brazil, Brazil. We serve hundreds of customers in five continents via an integrated supply chain which includes these production facilities and logistical centres, and a large fleet of unique transportation vessels, especially designed for the safest delivery of ICL-IP s products. Our commitment to upholding the highest environmental and safety standards Strict adherence to international regulations on safety and environmental issues are fundamental business practices at ICL-IP, whose major plants have been granted ISO and OHSAS accreditation for Environmental and Safety Management Systems. Beyond this, ICL-IP has actively initiated and developed a program to reduce environmental emissions through a code of good practice known as the Voluntary Emission Control Action Program VECAP. ICL-IP fully complies with the requirements of all regulatory systems worldwide for all its existing and new flame retardants, including the EU REACH regulation (EC 1907/2006) covering the Registration Evaluation, Authorization and Restriction of Chemicals. ICL has recently developed SAFR, Systematic Assessment of Flame Retardants, a framework that provides a rigorous evaluation of specific flame retardants in their applications, thus enabling users to choose the most sustainable product for the intended use. As such, SAFR is committed to the sustainable management of chemicals from the very first stage of the product design. For further details please consult: icl-group.com/sustainability/focusareas/systematic_assessment and safrworks.com 2

3 Responding to the needs of markets and industries by constant innovation The Flame Retardant Business Unit takes an in-depth and long-term view of the plastic industry s supply chain, so that its products and solutions are directly responsive to each market segment s special needs and challenges. We continuously study and monitor the requirements and trends of these market segments, including those of supporting industries, which enables us to offer a valuable contribution to our customers by meeting their current needs and future requirements. ICL-IP R&D division translate these needs into new products and adapted solutions. Flame retardants for diverse applications Using the vast natural resource of bromine and minerals in the Dead Sea, ICL-IP produces a series of highquality flame retardant products, applicable to a wide range of plastics, polymers and polymer alloys. ICL- IP also offers the world s most comprehensive range of phosphorus-based flame retardants, fire resistant plasticizers and hydraulic fluids for high demanding applications. Bromine- and Phosphorus-based flame retardants are considered to be the two most efficient flame retardant families, constituting approximately 55% (in value) of total flame retardant usage. ICL-IP s portfolio also includes a few additional non-halogen and non-phosphorus based flame retardants such as high purity grades of Magnesium Hydroxide. SaFRon & TexFRon Series As part of the FR BU s focus on market needs, we have initiated a unique approach by developing tailormade solutions: SaFRon series for high demanding polyurethane foam applications. TexFRon series for high quality textile coating applications. Polymeric and reactive flame retardants the next generation Polymeric flame retardants are sustainable products complying with national and international human health and environmental regulations. They have long been recognised as the safest and most elegant flame retardants of high molecular weight man-made materials. Specifically, their beneficial qualities include: Non-leaching Due to their low solubility in water, once polymeric flame retardants are incorporated into the end-product plastic matrix, they become integrated with the plastic and leaching is not expected to occur. Non-bio-accumulative Their high molecular weight makes them unlikely to penetrate through the cell membranes of living tissues. Non-blooming They are not expected to migrate to the surface of the plastic during aging, thus eliminating any potential blooming in the finished product. ICL-IP is promoting a wide range of brominated polymeric flame retardants for various applications: FR-1025: brominated polyacrylate F-2000 series: brominated epoxy polymers with a wide range of molecular weight F-3000 series: end-capped brominated epoxy polymers with various molecular weights FR-803P: brominated polystyrene FR-122P: Brominated butadiene / styrene block copolymer TexFRon P, TexFRon 4000 Reactive flame retardants chemically react with the polymeric matrix in which they are incorporated and as such become an intrinsic, non- blooming, non-leaching part of the final article. Reactive flame retardants offered by ICL IP include: FR-1524(TBBA) for Printed Wired Boards FR-513(TBNPA) and SaFRon 6605 for rigid PU foams FR-522 (DBNPG) for UPE applications Fyrol 6, non-halogen FR for rigid PU foams and urethane elastomers. VeriQuel R100, non-halogen FR for rigid PU foams PolyQuel P100, polymeric phosphorus-based FR for epoxy resins in printed wiring boards 3

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5 safrworks.com For more information visit our website: 5

6 Selection Table APPLICATIONS Brominated Flame Retardants HIPS EPS / XPS ABS Polyethylene Polypropylene TPE / TPU PBT / PET Nylon = Polyamide PC / PC ABS Alloys PVC / Flexible Rubbers / Elastomers Epoxy Resins Phenolic Resins Unsaturated Polyesters Flexible PU Rigid PU Chip / Particle Boards Textiles / Fibers Latex / Adhesives FR-11 (Ammonium Bromide) FR-122P FR-245 FR-370 FR-513 FR-522 FR-613 FR-720 FR-803P FR-1025 FR-1410 FR-1524 Brominated Epoxy Flame Retardants F-2001 F-2200HM F-2016 F-2100, F-2400 F-3014, F-3020 F-3100 Inorganic Flame Retardants FR-20 FR-1120 (synergist) 6

7 Phosphorus Flame Retardants Fyrol Series HIPS / PPO EPS / XPS ABS Polyethylene Polypropylene TPE / TPU PBT / PET Nylon = Polyamide PC / PC ABS Alloys PVC / Flexible Rubbers / Elastomers Epoxy Resins Phenolic Resins Unsaturated Polyesters Flexible PU Rigid PU Chip / Particle Boards Textiles / Fibers Latex / Adhesives Cellulosic Plastic Composite Fyrol A710 Fyrol HF-5 / HF-5-HP (Low Emission) Fyrol 6 Fyrol PCF / Fyrol PCF-LO (Low Odour) Fyrol PNX / Fyrol PNX-LE (Low Emission) Fyrol HF-9 / Fyrol HF-10 Fyrolflex Fyrolflex RDP/ RDP-HP Fyrolflex Sol-DP Phosflex Phosflex 4 Phosflex T-BEP Phosflex 31L/41L Phosflex 375 Phosflex 71B Phosflex 362 Phosflex 390 Phosflex 418 Lindol Lindol Lindol XP Plus Tailor Made FR Solutions 6605 series VeriQuel R100 PolyQuel P100 7

8 Products & Properties M.W. Specific Gravity Bromine Content Melting Range/Point- Softening Range TGA %WT. Temp. Brominated Flame Retardants FR-11 Ammonium bromide APPLICATIONS: Chipboard, Wood Paper, Textile NH4Br % M.P. 452 C CAS No FR-122P ( polymer) Brominated Butadiene/Styrene Block Copolymer APPLICATIONS: EPS and XPS ADVANTAGES: non blooming, non leachable, low loading and good FR efficiency CAS No % S. R C 257 C 264 C FR-245 Tris(tribromophenoxy) triazine APPLICATIONS: HIPS, ABS ADVANTAGES: combination of good flow and impact, UV and thermal stability, non-blooming % M.P. 230 C 360 C 385 C 400 C CAS No FR-370 Tris(tribromoneopentyl) phosphate APPLICATIONS: PP, HIPS, ABS, Alloys, Adhesives, Fibers ADVANTAGES: UV and light stability. CAS No % (3% P) M.P. 181 C 282 C 309 C 319 C FR-513 Tribromoneopentyl alcohol APPLICATIONS: PU rigid and flexible foams, FR intermediate ADVANTAGES: meets high FR standards, high thermal stability, non-leaching, reactive CAS No % M.P. 65 C 139 C 155 C 169 C FR-522 Dibromoneopentyl glycol APPLICATIONS: UPE, PU rigid foams ADVANTAGES: high level of flame retardancy, light stability, transparency, reactive, nonleaching CAS No % M.P C 200 C 225 C 245 C FR-613 Tribromophenol APPLICATION: FR Intermediate, end capping of brominated epoxies % M.P. 93 C 120 C 132 C CAS No FR-720 Tetrabromobisphenol A - bis(2,3 dibromopropyl ether) APPLICATIONS: PP, HIPS, ABS ADVANTAGES: good FR efficiency and thermal stability CAS No % M.R C 291 C 306 C 313 C 8

9 M.W. Specific Gravity Bromine Content Melting Range/Point- Softening Range TGA %WT. Temp. Brominated And Brominated Epoxy Flame Retardants FR-803P (polymer) Brominated polystyrene APPLICATIONS: Nylon, PBT, PET ADVANTAGES: good CTI, thermal stability, non-blooming % min. S.R C 340 C 358 C 374 C CAS No FR-1025 (polymer) Brominated polyacrylate APPLICATIONS: PBT, Nylon, Alloys ADVANTAGES: excellent thermal aging, CTI, good impact, compatibility with fiber reinforcement,recycling, non blooming CAS No FR-1410 Decabromodiphenyl ethane APPLICATIONS: HIPS, PE, PP, PBT, nylon, UPE, Epoxy ADVANTAGES: FR efficiency, exceptional thermal stability and multi-purpose CAS No % M.R C % M.P. > C 330 C 335 C 322 C 345 C 360 C FR-1524 Tetrabromobisphenol-A APPLICATIONS: Epoxy, Polycarbonate Resins, ABS ADVANTAGES: high reactivity with epoxy, low color, high clarity, good FR efficiency good solubility CAS No % M.P. 181 C 262 C 284 C 301 C F-2000 series - Brominated Epoxy F-2200 HM (Proprietary) APPLICATIONS: XPS, HIPS, Polyolefins ADVANTAGES: Thermal stabilizer, corrosion resistant, processing aid CAS No % M.R C 289 C 326 C 343 C F-2000 series - Brominated Epoxy polymer F-2001 (polymer) APPLICATIONS: Unsaturated polyester and vinyl ester resins ADVANTAGES: High UV stability, solubilty in styrene % M.R C 280 C 320 C 340 C CAS No For more information visit our website: 9

10 Products & Properties M.W. Specific Gravity Bromine Content Melting Range/Point- Softening Range TGA %WT. Temp. Brominated Epoxy Flame Retardants F-2000 series - Brominated Epoxy polymer* F-2016 (polymer) APPLICATION: ABS ADVANTAGES: good processability, high thermal and UV stability, non-blooming F-2100L (polymer) APPLICATIONS: PBT, PC/ABS ADVANTAGES: high thermal and UV stability, nonblooming, non corrosive, excellent processability F-2100 (polymer) APPLICATIONS: PBT, PC/ABS ADVANTAGES: high thermal and UV stability, nonblooming, non-corrosive, excellent processability F-2100H (polymer) APPLICATIONS: PBT, PET, Alloys (PC/ABS) ADVANTAGES: good mechanical, physical and flow properties, high thermal, UV stability, non blooming F-2400E (polymer) APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABS ADVANTAGES: high thermal and UV stability, nonblooming, excellent processability F-2400 (polymer) APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABS ADVANTAGES: high thermal and UV stability, nonblooming, excellent processability F-2400H (polymer) APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABS ADVANTAGES: high thermal and UV stability, nonblooming, excellent processability CAS No % S.R C 328 C 348 C 363 C % C 355 C 364 C 367 C % S.R C % Tg C % Tg C % Tg C F-3000 series - End capped Brominated Epoxy* % Tg C 350 C 357 C 361 C 348 C 355 C 359 C 345 C 352 C 357 C 345 C 352 C 357 C 345 C 352 C 357 C F-3014 APPLICATIONS: HIPS, ABS ADVANTAGES: good processability, non-blooming, high thermal and UV stability, good HDT impact strength, low metal adhesion F-3020 (polymer) APPLICATIONS: HIPS, ABS ADVANTAGES: good processability, nonblooming, hight thermal and UV stability, good HDT impact strength, low metal adhesion F-3060 (polymer) APPLICATIONS: PBT ADVANTAGES: good processability, nonblooming, hight thermal and UV stability, good HDT impact strength, low metal adhesion F-3100 (polymer) APPLICATIONS: PBT, Nylon, Alloys, ABS ADVANTAGES: processing - aid, excellent flow properties, non-blooming low metal adhesion and good thermal and UV stability CAS No For U.S: CAS No CAS No For U.S: CAS No CAS No For U.S: CAS No CAS No For U.S: CAS No * Molecular weight can be tailored to specific requirements % S.R C % S.R C 8, % S.R C % S.R C 293 C 330 C 350 C 318 C 349 C 357 C 344 C 354 C 359 C 343 C 352 C 358 C 10

11 Specific Gravity Phosphorus Content Chlorine Content Viscosity mpa.s - 25 C TGA %WT. Temp. Phosphorus Flame Retardants Fyrol series Fyrol HF-5 / HF-5-HP (High Purity) Proprietary halogen-free FR additive APPLICATIONS: Flexible PU foam ADVANTAGES: FR efficiency, low viscosity, low fogging and low VOC emissions. Fyrol HF-9 Proprietary halogen-free phosphate ester flame retardant APPLICATIONS: Flexible PU foam ADVANTAGES: Highly effective in producing flame retardant flexible polyurethane foam meeting MVSS-302 criteria Fyrol HF-10 Proprietary halogen-free phosphate ester flame retardant APPLICATIONS: Flexible PU foam ADVANTAGES: Highly effective in producing flame retardant flexible polyurethane foam meeting MVSS-302 and BS5852 Fyrol A710 Proprietary halogen-free flame retardant APPLICATIONS: Flexible PU foam ADVANTAGES: Excellent processing, low viscosity, low scorch. Proprietary % C 213 C 259 C % % 1, % 70 Fyrol PNX Oligomeric ethyl ethylene phosphate APPLICATIONS: Flexible PU foam, paper treatment ADVANTAGES: very high efficiency. Fyrol PNX-LE (Low Emission) Modified oligomeric ethyl ethylene phosphate APPLICATIONS: Flexible PU foam ADVANTAGE: Low emission version of Fyrol PNX, low fogging/voc for automotive Fyrol 6 Diethyl N,N bis (2-hydroxyethyl) aminomethylphosphonate APPLICATIONS: Reactive non halogen FR for rigid PU foam and urethane elastomers ADVANTAGES: Excellent for spray, pour-in-place systems and slab foams. Permanency in PU foams CAS No CAS No CAS No % C 215 C 235 C % C 215 C 235 C % C 195 C Fyrol PCF Tris (2-chloroisopropyl) phosphate. APPLICATIONS: Isocyanurate and rigid PU foams, flexible PU foam (BS5852), unsaturated polyesters and phenolics ADVANTAGES: Hydrolytic stability, low viscosity CAS No Fyrol PCF-LO (Low Odour) Tris 2-chloroisopropyl phosphate. APPLICATIONS: Flexible PU foam for BS5852 applications ADVANTAGES: Hydrolytic stability, low viscosity CAS No % 32.5% C 165 C 180 C % 32.5% C 166 C 180 C For more information visit our website: 11

12 Products & Properties Specific Gravity Phosphorus Content Chlorine Content Viscosity Mpa.s - 25 C Melting Range TGA %WT. Temp. Phosphorus Flame Retardants Fyrolflex Series Fyrolflex RDP Resorcinol bis(diphenyl phosphate) APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics, phenolic laminates, TPU ADVANTAGES: High efficiency, high thermal stability CAS No % C 320 C 335 C Fyrolflex RDP/RDP-HP (High Purity) High purity oligomeric phosphate ester flame retardant with low triphenyl phosphate content % C 356 C 374 C Fyrolflex Sol-DP Proprietary aromatic phosphate APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, UL94/V-2 ABS, processing aid for engineering resins, TPU ADVANTAGES: Easy to handle solid free-flowing, high efficiency and good hydrolytic stability Proprietary, solid dust free pastilles % M.R C 300 C 335 C 350 C Phosflex Series Phosflex 4 Tributyl phosphate APPLICATIONS: De-airing additive, extraction agent in metal and phosphoric acid production, high-boiling solvent for inks and paints. ADVANTAGE: Low viscosity % C 135 C 150 C CAS No Phosflex T-BEP Tris(butoxyethyl) phosphate APPLICATIONS: Emulsions of floor finishes, leveling agent in latex paints, processing aid for acrylonitrile rubber, antiblock agent for cast polyurethanes ADVANTAGE: Low viscosity % C 200 C 225 C CAS No Phosflex 31L/41L Isopropylated triphenyl phosphate mixture APPLICATIONS: PVC film and sheeting compounds, PVC plastisols. ADVANTAGES: High thermal stability, good solvating properties % 60/ C 230 C 245 C CAS No

13 Specific Gravity Phosphorus Content Viscosity Mpa.s - 25 C Melting Range TGA %WT. Temp. Phosphorus Flame Retardants Phosflex Series Phosflex 375 Proprietary plasticizer blend of alkyl diphenyl phosphate and triaryl phosphate ester. APPLICATIONS: PVC films and sheeting compounds, PVC plastisols. ADVANTAGES: Blended alternative FR plasticizer for isopropylated TPPs, excellent FR % C 240 C 257 C Phosflex 71B / 71B - HP (High Purity) t-butylated triphenyl phosphate mixture APPLICATIONS: Plasticizer for PVC and PVC foams, polyvinyl acetate emulsion, FR for modified HIPS ADVANTAGE: High thermal stability % C 235 C 250 C CAS No and and Phosflex ethylhexyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC (plastisols, textile coatings), and vinyl/nitrile rubber foamed alloys, cellulosic polymers, PMMA, PS ADVANTAGES: Good performance at low temperature, low smoke, FDA approved in coatings for food packaging. CAS No % C 200 C 210 C Phosflex 390 Isodecyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting, foamed vinyl/nitrile rubber alloys, wire insulation, coatings for apparel and upholstery, polyvinyl acetate adhesives ADVANTAGES: Good performance at low temperature, low smoke CAS No % C 220 C 235 C Phosflex 418 Linear alkyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting and wire insulation ADVANTAGES: Excellent plasticizing efficiency at low temperature, low smoke and low volatility CAS No , and % C 235 C Lindol Series Lindol & Lindol XP Plus Tri(m,p-cresyl) phosphate mixture APPLICATIONS: Plasticizer for PVC, synthetic rubber, cellulosic films, FR for phenolic laminates ADVANTAGE: High efficiency % C 235 C 250 C CAS No For more information visit our website: 13

14 Products & Properties M.W. Specific Gravity Avg. Particle Size Bulk Density Kg/m3 TGA %WT. temp. Mineral And Nitrogen Flame Retardants Inorganic Flame Retardants FR-20 Magnesium Hydroxide GRADES: S5 (BET 5 m 2 /g) uncoated or coated S7 (BET 7 m 2 /g) uncoated or coated S10 (BET 10 m 2 /g) uncoated or coated APPLICATIONS: Wire and Cables, Electrical connectors, TPO for roofing, Foils and sheets, LD and HDPE, PP, Soft PVC, PA ADVANTAGES: excellent smoke suppressant, acid scavenger, thermal stability. All above grades are available with Stearic acid surface treatment. Mg(OH)2 CAS No µm µm µm C 385 C 402 C FR-1120 Calcium Borate on a silicate carrier. APPLICATIONS: Antimony Trioxide replacement in polyolefins, polyamides, styrenics and polyesters. Zinc Borate replacement in polyolefins and PVC. ADVANTAGES: Highly cost-efficient. CAS No µm C 319 C 392 C Specialty Flame Retardants, Tailor-Made Solutions PolyQuel P100 APPLICATIONS: reactive, polymeric phosphorus-based flame retardant curing agent for epoxy resins in printed wiring boards. ADVANTAGES: high glass transition temperature and thermal stability; high flame retardant efficiency; low Dk and Df; especially recommended for lead-free, halogen-free, high Tg applications. VeriQuel R100 APPLICATIONS: phosphorous-rich reactive intermediate for PIR roof and wall insulation, closed cell spray foam insulation and rigid polyurethane foam. ADVANTAGES: Efficient TCPP replacement; non-emissive in PIR and closed cell spray foam formulation; low viscosity liquid, very good viscosity cutting characteristics, efficient processing aid in high viscosity PUR and PIR systems. Specific Phosphorus Viscosity TGA 0 C, M.W. Gravity Content Mpa.s C Tg, 0 C 5% % SaFRon and TexFRon Series Strengths: A - Antimony oxide free E - FR efficiency T - Thermal stability D - Dust-free P - Polymer & Non-blooming HIPS / PPO EPS / XPS ABS Polyethylene Polypropylene PBT / PET Nylon = Polyamide PC / PC ABS Alloys PVC / Flexible Rubbers / Elastomers Epoxy Resins Phenolic Resins Unsaturated Polyesters Flexible PUF Rigid PUF Chip / Particle Boards Textiles / Fibers Latex / Adhesives Cellulosic Plastic Composite 6605 E 9000 and 3000 Series P and 4000 Series* 5000 Series AG * TexFRon 4002 is OEKO-TEX Standard 100 certified E T E T P E P D 14

15 Applications Thermoplastics and Styrenic Alloys HIPS V-1/V-0 PROPERTIES good very good excellent FR-1410 FR-245 F-3000* Thermal stability Melt flow FR efficiency Impact UV / Light stability Heat distortion temp. Non-blooming Cost efficiency Recycling * Polymer HIPS V-2 PROPERTIES Fyrolflex Sol-DP FR-720 FR-1410 FR-245 FR-370 Thermal stability Melt flow FR efficiency Impact UV / Light Stability Heat distortion temp. Non-blooming Cost efficiency Dust-free For more information visit our website: 15

16 Applications Thermoplastics and Styrenic Alloys ABS V-1/V-0 FR-1524 FR-245 F-2000* FR-1410 F-3000* PROPERTIES Thermal stability Melt flow FR efficiency Impact UV / Light stability Heat distortion temp. Non-blooming Cost efficiency Recycling ATO free option * Polymer PC/ABS and HIPS/PPO alloys V-1/V-0 PROPERTIES Fyrolflex RDP /RDP-HP Fyrolflex Sol-DP F-3000* Phosphorus (P)/Bromine (Br) Based P P Br Thermal stability Melt flow FR efficiency Impact UV / Light stability Hydrolytic stability Heat distortion temp. Non-plate-out Cost efficiency Liquid/solid handling Liquid Solid Solid * Polymer 16

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18 Applications Engineering Plastics Polyamide Non reinforced PA 6 and 6,6 V-O FR-803P* FR-1025* FR-1410 F-2400* FR-20 PROPERTIES Thermal stability Melt flow FR efficiency Impact Comparative tracking index Thermal aging Recycling UV / Light stability Heat distortion temp. Non-blooming Cost efficiency * Polymer Polyamide Glass reinforced PA 6 and 6,6 V-O FR-803P* FR-1025* FR-1410 F-2400* F-3100* PROPERTIES Thermal stability Melt flow FR efficiency Impact Comparative tracking index Thermal aging Recycling UV / Light stability Heat distortion temp. Non-blooming Cost efficiency ATO free option * Polymer 18 good very good excellent

19 Engineering Plastics PBT V-0 PROPERTIES FR-1025* F-3100* F-2000* series FR-803P* FR-1410 FR-1025 & F-2000* series Thermal stability Melt flow to FR efficiency Impact Comparative tracking index Thermal aging Recycling UV / Light stability Heat distortion temp. Non-blooming Cost efficiency ATO free option * Polymer good very good excellent For more information visit our website: 19

20 Applications PVC & Textile Adhesives Coating (TAC) Flexible PVC Phosflex 31L/41L Phosflex 375 Phosflex 71B Phosflex 362 Phosflex 390 Lindol PROPERTIES FR efficiency Plasticizing performance Low temperature flexibility Low smoke Low volatility/surface migration Low smell Chemical resistance (oil fats) Food approval * Cost efficiency * FDA Contact in coatings for confectionary applications 20

21 Textile Adhesives & Coating (TAC) TAC PROPERTIES: Phophorus (P) / Bromine (Br) based TexFRon 9001 TexFRon 4002 TexFRon P TexFRon 5001 FR-1410 Br Br Br P Br Solid/Liquid S S L L S FR efficiency Transparency Wash durability UV stability Low melt tmp. Low fogging Self binding Polymeric Cost efficiency FABRIC TYPE Polyester Polyester/Cotton blends Nylon & Nylon blends Cotton * * with additive - TexFRon AG Back coating Coating/padding AG: provides anti smoldering for BFRs combinations in cotton rich applications Textile Exhaustion application 3000 provides flame retardancy to synthetic fibers yarns and fabrics good very good excellent For more information visit our website: 21

22 Applications Polymeric Foams Flexible PU PROPERTIES Fyrol A710 Fyrol PCF Fyrol PNX Fyrol PNX LE Fyrol HF-9 Fyrol HF-10 Low viscosity FR efficiency Low scorch Low fogging Compression set Reactive Cost efficiency Rigid PU PROPERTIES VeriQuel R100 Fyrol 6 Fyrol PCF SaFRon 6605 Fyrol PNX Low viscosity FR efficiency System stability Reactive Cost efficiency EPS / XPS Expanded and extruded polystyrene foams for building, construction and packaging industries are available in many forms: Sheets (thermal insulation), Profiles (decorative), Molded shapes (packaging). ICL-IP offers several flame retardants to match market needs in the various applications: FR-122P Polymeric FR FR efficiency similar to FR-1206 Non-leaching and non-blooming F-2200HM and F-2016 Proprietary co-fr for XPS applications Heat /UV stabilized applications Processing-aid effect 22

23 Polyolefins PP FR-370 FR-720 FR-1410 FR-1025* FR-20 PROPERTIES Thermal stability Processability FR efficiency Impact UV / Light stability Non-blooming Cost efficiency Rating V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 * Polymer PE FR-720 FR-1410 FR-1025* FR-20 PROPERTIES Thermal stability Melt flow FR efficiency Impact UV / Light stability Non-blooming Cost efficiency * Polymer good very good excellent For more information visit our website: 23

24 ICL - Industrial Products Head Office ICL-IP Makleff House, 12 Kroitzer St., P.O.B. 180 Beer Sheva 84101, Israel Tel: Fax: frinfo@icl-group.com Europe ICL Europe Konigin Wilheminaplein 30, 1062 KR, Amsterdam, The Netherlands P.O. Box 465, 1000 AL Amsterdam, The Netherlands Tel: +31 (0) Fax: +31 (0) fr.europe@icl-group.com South America ICL Brasil Ltda. Rua George Ohm, º andar Torre B Brooklin Zip Code: Tel: Fax : fr.sam@icl-group.com Asia Pacific China ICL CHINA Floor 14th of No. 2 Tower of Jin Chuang Building, No Jin Ke Road Pudong New District, Shanghai , China Tel: fr.china@icl-group.com Other Asia Pacific ICL Asia ltd. 25 th Floor, One Capital Place 18 Luard Road, Wanchai, Hong Kong Tel: (852) Fax: (852) fr.asia@icl-group.com Other parts of the World ICL-IP Israel Sales Office Makleff House, 12 Kroitzer St., P.O.B. 180 Beer Sheva 84101, Israel Tel: Fax: fr.row@icl-group.com North America and Mexico ICL-IP America Inc. 622 Emerson Road, Suite 500 St. Louis, Missouri 63141, USA Tel: Fax: fr.nam@icl-group.com Japan ICL Japan Ltd. Sumitomo Fudosan Iidabashi Building, 5th fl , Koraku, Bunkyo-ku, Tokyo , Japan Tel: Fax: fr.japan@icl-group.com Visit our website: Itsuvey ha-negev 3/2018 Although the information and recommendations set forth herein (hereinafter Information ) are presented in good faith and believed to be correct as of the date hereof, ICL INDUSTRIAL PRODUCTS. makes no representations as to the completeness, accuracy, quality or suitability of any information for any purpose. The use of the Information supplied herein shall be subject to and conditioned on that the persons receiving it and making use of it will make their own determination as to its safety and suitability for their purposes and applicable laws and other statutory demands prior to acquisitions, importations, exportations, transportations, implementations or uses of any kind. In no event will ICL INDUSTRIAL PRODUCTS. be responsible for damages of any nature whatsoever resulting, directly or indirectly, from the use or reliance upon Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.