GB Translated English of Chinese Standard: GB NATIONAL STANDARD
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1 Translated English of Chinese Standard: GB NATIONAL STANDARD GB OF THE PEOPLE S REPUBLIC OF CHINA GB Natial Food Safety Standard Plastic Resin used in food-ctact 食品安全国家标准食品接触用塑料树脂 Issued : October 19, 2016 Implemented : April 19, 2017 Issued by: Natial Health and Family Planning Commissi of People s Republic of China Page 1 of 20
2 Table of ctents Foreword Scope Terms and definitis Basic requirements Technical requirements Other... 5 Appendix A Plastic resin allowed to use and use requirements Page 2 of 20
3 Foreword The standard replaces GB Hygienic standard for polyvinyl chloride resin used as food ctainer and packaging material, GB Hygienic standard for polyethylene resin used as food packaging material, GB Hygienic standard for polystyrene resin used as food packaging material, GB Hygienic standard for polypropyrene resin used as food packaging material, GB Hygienic standard for polyethylene terephthalate resin used as food ctainers and packaging materials, GB Hygienic standard for polycarbate resin used as food ctainers and packaging materials, GB Hygienic standard of vinylidene chloride-vinyl chloride copolymer resins for food ctainers and packaging materials, the resin part of GB Hygienic standard for unsaturated polyester resin and glass fiber reinforced plastics used as food ctainers and packaging materials, GB Hygienic standard of nyl 6 resin for food packaging material, AND the relevant parts plastic resin in the Announcement the publicati of the list of 107 resins available for food packaging material including polyhexamethylene adipamide (No. announcement in 2011, original Ministry of Health). This standard, as compared with the above standards and announcements, has the following main changes: - MODIFY the standard name into Natial Food Safety Standard - Plastic Resin used in food-ctact ; - MODIFY the scope; - ADD terms and definitis; - ADD the basic requirements; - ADD the raw material requirements; - MODIFY the physical and chemical indicators; - ADD the general requirements for migrati test; - ADD the marking requirements; - ADD Appendix A. Page 3 of 20
4 Natial Food Safety Standard Plastic Resin used in food-ctact 1 Scope This standard applies to the resin and resin blends used for the producti of food ctact plastic materials and products, including n-vulcanized thermoplastic elastomer resin and its blends. 2 Terms and definitis 2.1 Resin It refers to the macromolecular substances AND the chemically modified natural macromolecules, also known as polymers synthesized by the polymerizati reacti such as additi polymerizati, cdensati polymerizati and microbial fermentati polymerizati, using the momers with lower relative molecular mass and other starting materials as the main materials. 2.2 Resin blends It refers to the macroscopically uniform solid polymer materials as formed by physical and/or chemical mixing of two or more polymers having the same or different chemical structures and physical states, with each polymer being used as the main structural compents or phases of the resin material and its product, which is also known as polymer blends or polymer alloys. 3 Basic requirements Food ctact plastic resin shall comply with the requirements of GB Technical requirements 4.1 Raw material requirements Raw materials for the producti of the food ctact plastic resin shall ensure that under normal and expected cditis of use, it shall not harm to human health. Page 4 of 20
5 Appendix A Plastic resin allowed to use and use requirements A.1 Table A.1 specifies the plastic resin allowed for use AND the use requirements. A.2 The specific migrati total limit [] and grouping in Appendix B of GB apply to this standard. Table A.1 Plastic resin allowed to use and use requirements Copolymer of (3R) 3- hydroxybutyric acid and 4-hydroxybutyric acid Polymer of 1, 1, 1, 2, 2, 3, 3-heptafluoro 3 [(trifluoroethenyl) oxy] propane and tetrafluoroethylene Polymer of 1,12- dodecanedioic acid and 1,6-ethylenediamine (polydodecanedioethyle ne diamine, polyamide 612) Polymer of 1, 12- dodecanedioic acid with acid and 1, 4-butanediol Polymer of 1, 1- dichloroethylene and methyl acrylate Polymer of 1, 3, 5- trioxane and 1, 3- dioxolane Poly (3HBco-4HB), P (3, 4HB) PFA PA PBT PVDC ; POM 0.05 (tetrafluoroethylene: 2.4 (1, 6- ethylenediamine: 5 (1, 4-butanediol: ND (1, 1- dichloroethylene, DL = 0.01 : OR 5 (1, 1- vinylidene chloride: QM) 5 (trioxymethylene: ; 5 (1, 3- dioxolane: ; 1 [1, 4-bis (2, 3- glycidoxy) butane, based epoxy group: QM] 5 1, 4-butanediol) 7.5 ( acrylic) The produced plastic materials or products shall not be used to ctact the ethanol ctaining food; AND the use temperature shall not exceed 100 C 121 C Page 6 of 20
6 QM) 25 Acrylitrile-styrene copolymer AS ND (acrylitrile, DL = Acrylitrile-butadienestyrene - ABS ND (butadiene, DL = 0.01 : or 1 (butadiene: QM); ND (acrylitrile, DL = 00.1 : 27 Polymer of butyl acrylate and butyl methacrylate, 2- (dimethylamino) ethyl methacrylate and methyl methacrylate PMMA 0.02 ( acid (dimethylamino) ethyl methacrylate: acrylic); 6 22, 28 Polymer of acrylic acid methyl ester, butadiene and acrylitrile PAN ND (acrylitrile DL = 0.01 ; ND (butadiene, DL = 0.01 : or 1 (butadiene: QM) acrylic) Polymer of propylene and e or more of the following momers (wherein propylene has the maximum mass fracti): maleic anhydride, ethylene, 1- butene, other alphaolefins, ctaining 5- ethylidene-2- norbornene as modified momer Polymer of acrylic acid methyl ester, 1, 1- dichloroethylene and acrylitrile Unsaturated polyester resin Grafted copolymer of acid, 1, 4- butanediol, fumaric acid, ethylene glycol, ; ; ; ; Table A.1 (ctinued) PP PVDC - UP - Modified PBT 0.05 (5-ethylidene norbornene: maleic ND (acrylitrile, DL = 00.1 : or ND (vinylidene chloride DL = 00.1 or 5 (1, 1-dichloroethylene: QM) 0.2% (resin template, styrene: QM) acrylic) 30 ethylene glycol); ; 28; 30 When the 5-ethylidene- 2- norbornene detecti method is not available, 0.05 mg/6 dm 2 (QM) can be used as the limiting value. The ratio between the ctacting area of plastic materials and products ctaining 5-ethylidene-2- norbornene and food AND the food mass shall not be higher than 2 dm 2 /kg It is ly used to ctact the food ctaining fat Page 10 of 20
7 40 Polymer of dimethyl terephthalate, 1, 4- butanediol and α- hydrogen-ω hydroxyl poly (1, 4-butanediol) (polyester elastomer) TPC-ET 0.6 (tetrahydrofuran: ; 5 the sum of trimellitic acid and trimellitic anhydride: QM) 7.5 (based terephthalate ); 5 (based 1, 4- butanediol) 28; 30 It shall not be used to ctact ctaining alcohol of more than 8%; AND the temperature for use shall not exceed 66 C Polymer of dimethyl terephthalate, 1, 4- butanediol and α- hydrogen-ω-hydroxy poly (oxy-1, 4- butanediyl) Polymer of acid and [1, 1'- biphenyl]-4, 4'-diol, 4- hydroxybenzoic acid, 6- hydroxy-2 naphthoic acid and N- (4- hydroxyphenyl) acid and potassium salts Polymer of the erephthalic acid and 1, 6-hexanediamine (1: 1) polymer AND caprolactam P-tert-butylphenolterminated poly (carbic acid-4, 4'- isopropylidiphenyl) Diethylene glycolisophthalic acidmodified polyethylene terephthalate copolymer; cdensati of dimethyl terephthalate or acid and ethylene glycol with diisophthalic acid Methyl ester, isophthalic acid and diethylene glycol Table A.1 (ctinued) Modified PBT thermoplas tic elastomer (TPE) LCP PA PC ; ; ; PET 46 Trans-1, PCCD 0.05 (tetrahydrofuran: 0.05 (6-hydroxy-2 naphthoic acid: ; 6 (4, 4'- dihydroxybiphenyl: ; 0.05 [N- (4- hydroxyphenyl) acetamide: SML] 2.4 (1, 6- ethanediamine: 0.6 [4, 4'- isopropylidene diphenol (bisphenol A): SML]; 0.05 (ptert-butylphenol: ; 1 (carbyl dichloride: QM) 0.04 antimy: 5 1, 4- butanediol) 7.5 (based 15 caprolactam) ; 7.5 (based 30 ethylene glycol); 5 isophthalic ; ; 28 2; 27; 28 When used as a polyester elastomer, it is ly used to ctact dry solid food It shall not be used to ctact ctaining alcohol of more than 8%, or the solid food surfaced with fat It shall not be used to produce the material and products ctacting with the special food for infants. Page 12 of 20
8 57 Polymer of butyl methacrylate, hydroxyethyl methacrylate, methyl methacrylate and methacrylamide PMMA ND (methacrylamide, DL = 0.01 : Polymer of butyl methacrylate, ethylene, methyl methacrylate and propylene Polymer of methyl methacrylate, styrene and maleic anhydride Copolymer of methyl methacrylate and ethyl acrylate Copolymers of methyl methacrylate, butadiene, styrene and acrylitrile Polymers of methyl methacrylate and methyl acrylate Polymero of acid, methyl methacrylate and methyl methacrylate Polymer of acid and methyl methacrylate Polymer of acid, methyl methacrylate and methyl acrylate Polymer of dimethyl isophthalate, 1, 4- butanediol, acid and poly (1, 4- butanediol) Table A.1 (ctinued) PMMA PMMA PMMA ABS PMMA PMMA PMMA PMMA PBT ND (butadiene, DL = 0.01 : SML or 1 (butadiene: QM); ND (acrylitrile, DL = 00.1 : 30 maleic ; acrylic); 6 acrylic); 6 acrylic); (based ; 5 1, 3; 22; 22; 22; 28; C. Page 14 of 20
9 (propylene homopolymer) 75 Polybutylene succinate PBS, PBSU 5 1, 4- butanediol) C Polybutylene terephthalate; poly (oxo-1, 4- butyleneoxyhydroxy-1, 4-phenylenehydroxy) Polymer of Polybutylene terephthalatepolytetrahydrofuran ether block copolymer and maleic anhydride anhydride Polybutylene terephthalate Polyethylene terephthalate resin Polyhexamethylene adipamide (polyamide) Polycaprolactam (polyamide 6) Table A.1 (ctinued) PBT PBT PBAT - PET ; PA PA 82 Polymethylmethacrylate PMMA 83 Polyformaldehyde ; POM 84 Polyvinyl chloride - PVC 0.6 (tetrahydrofuran: 0.04 antimy: 7.5 (based ; 5 1, 4-butanediol) 30 maleic ; 5 1, 4- butanediol) 7.5 (based ; 5 1, 4-butanediol) 30 ethylene glycol); caprolactam) 15 formaldehyd e) ND (1, 1- dichloroethane, DL = 0.01 : or 5 (1, 1, 1- dichloroethane, DL = 0.01 : or 1 (vinyl chloride: 28; 30 3; 30 28; C. 100 C; AND it shall not be used to ctact the frozen food or refrigerated food. 2; 28 SEE note C Page 16 of 20
10 processing and so. Nature: when it is higher than 120 C, the viscosity is > 3 Pa s; the softening temperature is > 95 C; the bromine value is < 40; the color of this soluti ctaining 50% toluene shall be <11 (Gardner color); aromatic momer residue total amount is Melamine formaldehyde resin Polymer of carbyl chloride and 4, 4 - cyclohexa bis (2- methylphenol), 4, 4'- isopropylpropylphenol (bisphenol A) and bis [4- (1-methyl- 1- phenylethyl) phenyl] ester Polymer of pentafluoroethyl trifluoroethylene ether and tetrafluoroethylene Polymer of (oxide-1, 4- phenylene sulfyl-1,4- phenylene) polymer, 4, 4'-sulfyl diphenol (bisphenol S) and 1, 1'- sulfylbis (4-chloro Benzene) Vinyl alcohol homopolymer (polyvinyl Table A.1 (ctinued) - MF PC PFA ; PESU PVA or PVOH 2.5 (melamine: 0.6 [4, 4'- isopropylidene diphenol (bisphenol A): SML]; 1 (carbyl dichloride: QM) 0.05 (tetrafluoroethylene: 0.05 [4, 4'-sulfyl diphenol (bisphenol S): SML]; 0.05 (4, 4 - dichlorodiphenylsulf e: 12 (vinyl acetate: 15 formaldehyd e) 15 When it is used to produce the plastic materials or products ctacted with infant foods, the specific migrati limit of triamine is 1 ; the material or product produced shall not be used for microwave heating It shall not be used to produce the material and products ctacting with the special food for infants. It is ly used to ctact the fat of low Page 18 of 20
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