Let s progress together

Size: px

Start display at page:

Download "Let s progress together"

Tyrone Peters
6 years ago
Views:

1 Specialty Polyolefins Let s progress together Evasin

2 Arkema Specialty Polyolefins With five brands sold globally, Arkema offers the widest range of reactive and non-reactive specialty polyolefins: Evatane ethylene vinyl acetate copolymers (18-42% VA) Lotryl ethylene acrylate copolymers Evasin* EVOH ethylene vinyl alcohol Lotader reactive polyolefins (up to 8% reactive group) Orevac T reactive EVA copolymers Orevac G grafted polyolefins (PE,PP, EVA) Arkema Specialty Polyolefins are used in applications as diverse as: Packaging Tie layer for multilayers barrier films and extrusion lamination Oxygen barrier layer Sealing and Seal/Peel resins Hot melt adhesives EVA binder High stability hot melt Deep freeze hot melt adhesives Construction Additives for bitumen rutting resistance Adhesive for pipe coating Aluminum panels Plastic compounds Impact modifiers for PA, PET, PBT, PPS, POM Coupling agents for HFFR and composites Automotive compounds Compatibilization of recycled plastics Automotive Fuel tank Sound deadening foams Thermo adhesive film Energy Cables compounds (LV, MV, HFFR) Photovoltaic panels Evasin* EVOH Oxygen barrier Ethylene content (% mol) (g/10min) 190 C kg 210 C kg Melting point ( C) Crystalization point ( C) Glass transition point ( C) O 2 Transmission Rate (65% RH) (20 C) Main applications EV 2951F Bottles, pipes EV 3251F Bottles, sheets, films EV 3851F Sheets, thermoforming, films EV 4405F EV 4451F Test method ASTM D1238 / ISO 1133 DSC ISO DSC ISO DMA ISO *Evasin is a brand of Chang Chun Petrochemicals ASTM D3985 / ISO Sheets, thermoforming, shrinks, films Sheets, thermoforming, shrinks, films

3 Ethylene - Acrylate copolymers lotryl.com Bases Specified properties* Typical properties** Main applications Comonomer content (%) (g/10 min) (190 C 2.16 kg) Melting point ( C) Vicat softening Ring and ball Flexural modulus (MPa) Hardness Shore A/D 18MA /25 20MA /- EMA 24MA /- Autoclave 24MA /- 29MA < / ** 11 ** /21 Bestpeel ** 7 ** 69 < /22 17BA /32 28BA /- EBA 30BA >190 <10 75/- Autoclave 35BA < <10 70/- 35BA <40 85 <10 52/- 20MA08T EMA 24MA02T Tubular 29MA03T < BA40T EBA < <10 HMA Tubular high content < <10 FTIR ASTM D1238 DSC ASTM D1525 ASTM E28 ASTM D790 ASTM D2240 Internal method ISO 1133 ISO ISO 306 NF EN1238 ISO 178 ISO 868 Hot melt adhesives Films / Sheets coating Foams / Sound dampening Modification of thermoplastic polymers EBA (Ethylene-Butyl Acrylate copolymer) EMA (Ethylene-Methyl Acrylate copolymer) Extrusion coating / Lamination Cables Combined with Lotryl, some masterbatches are available to enhance slip and antiblock properties.

4 Ethylene - Vinyl acetate copolymers evatane.com Bases Specified properties* Typical properties** Main applications Comonomer content (%) (g/10 min) (190 C 2.16 kg) Melting point ( C) Vicat softening Ring and ball Hardness Shore A Hot Melt adhesives Films / Sheets Foams Cables Bitumen Bitumen Bitumen Bitumen Crude oil *** < Solar panel < Crude oil EVA < Crude oil < Crude oil < Crude oil < < PV < Solar panel < < > < Ink FTIR ASTM D1238 DSC ASTM D1525 ASTM E28 ASTM D2240 Internal method ISO 1133 ISO ISO 306 NF EN1238 ISO 868 EVA (Ethylene-Vinyl Acetate copolymer) * Properties routinely measured during the standard quality control procedure ** indicative average values *** Photovoltaic (PV) quality available Sound dampening Others

5 Reactive terpolymers lotader.com orevac.com Lotader Orevac T Typical Properties* Main applications Reactive Co-monomer group (%) Reactive group (%) (g/10 min) Melting point Vicat softening Extrusion coating / Thermoadhesive Plastic modification (190 C 2.16 kg) ( C) Lamination films Coupling agent Bitumen Cables HFFR additives Others AX8700 BA (25%) PET, PBT, PPS Foams AX8750 BA (25%) PET, PBT, PPS AX8820 GMA PET, PBT, PPS Toners AX8840 Epoxide group PET, PBT, PPS Toners AX8900 MA (24%) <40 PET, PBT, PPS Foams AX8930 MA (25%) <40 PET, PBT, PPS Foams 4210 BA (6.5%) Concentrate 3210 BA (6%) PA 3410 MAH BA (17%) PA 3430 MA (15%) PA LX4110 Maleic anhydride EA (5%) High content EA (6.5%) EA (6.5%) Hot melt TX8030 EA (13%) Pipe coating 4700 EA (29%) <40 PA 4503 MA (20%) MAH MA (24%) Y VA (14%) Maleic anhydride 9318 VA (18.5%) Low content 9304 VA (25%) VA (28%) <40 Hot melt FTIR FTIR ASTM D1238 DSC ASTM D1525 Int. method Int. method ISO 1133 ISO ISO 306 MA (Methyl Acrylate) BA (Butyl Acrylate) EA (Ethyl Acrylate) VA (Vinyl Acetate)

6 Grafted polyolefi ns (LDPE, LLDPE, HDPE, VLDPE, EVA) orevac.com Orevac PE Orevac PP Types Base polymer Reactivity (+ medium) (++ high) Typical Properties* (g/10min.) (190 C, 2.16k) Melting point ( C) Vicat softening Extrusion coating / Lamination Cast / Blown film coex Main applications Plastic modification/ Coupling agent / Cables HFFR Sheet coex Blow molding/ Tube coex Adhesion to / Affinity with EVA PE / PET / PS / PA / EVOH 18302N LLDPE Coupling agent PE / Mineral fillers / natural fibers LLDPE PE / PA / EVOH LLDPE Concentrate Coupling agent Concentrate Concentrate Concentrate PE / Mineral fillers / PA/ EVOH 18342N HDPE PE / Epoxy primer / EVOH / 3LPE coating PE/EVA LLDPE PE / PA / EVOH grades HDPE Coupling agent PE / Mineral fillers / natural fibers LLDPE PE / PS / PA / EVOH IM300 VLDPE <40 Impact modifier PA IM800 VLDPE <40 Impact modifier PA OE825 LLDPE Concentrate Concentrate Concentrate Concentrate PE / PA/ EVOH OE850 LLDPE Concentrate Concentrate PE: Alu / Primed films / EVOH Random PP + 7.0** PP, PA, EVOH 18725N Random PP + 13** PP,PA, Epoxy, Metals Homo PP + 4.5** PE, PA, EVOH PP Copo PP + 8.0** PP, PA, EVOH, Alu, Epoxy grades Homo PP + 35** PP, PA, EVOH, Alu Homo PP + 35** PP, PA, EVOH, Alu CA100/CA100N Homo PP 1% 10*** Concentrate Coupling agent PP / mineral fillers / glass & natural fibers FTIR ASTM D1238 DSC ASTM D1525 internal method ISO 1133 ISO ISO 306 * Indicative average values ** (230 C, 2.16 kg) *** (190 C, 325 g)

7 A global presence Arkema produces more than 100 Specialty Polyolefins grades in four sites in Europe and one in North America and is represented in several sales offices in Asia, Latin America. Several of our production lines have online quality control to deliver consistent quality. ISO certificates are available in our web sites. Arkema France - A French «Société Anonyme» registered with the Commercial and Companies Register of Nanterre (France) under number Dircom E/ /30 - pof Photos: Arkema, Thinkstock, Fotolia - Design: Rythmic Production plant R&D Sales office Depending on the grade, we offer the following packaging: 25 kg bags, 500/550 kg cardboard boxes and 1000/1100 kg big bags. Arkema operates in more than 50 countries. For help finding a local representative, please consult our web sites or contact one of the following regional customer contact centers. EUROPE Headquaters Arkema France 420, rue d Estienne d Orves Colombes FRANCE Tel.: (+33) Fax: (+33) NORTH AMERICA Altuglas International 100 PA Route 413 Bristol, PA USA Tel.: (+1) ASIA Arkema Pte Ltd Representative offi ce 19th Floor, ITF Tower 140/41 Silom Road, Suriyawonge Bangrak B THAILAND Tel.: (+66) SOUTH AMERICA Arkema Quimica Ltda Av. Ibirapuera andar - Bairro Moema CEP São Paulo BRAZIL Tel.: (+55) Disclaimer: Please consult Arkema s disclaimer regarding the use of Arkema s products on Regulatory information: for information on regularoty compliance, consult your local representative. Read and understand the Material Safety Data Sheet (MSDS) before using these products. evatane.com lotader.com lotryl.com orevac.com Headquarters: Arkema France 420, rue d Estienne d Orves Colombes Cedex France Tel.: 33 (0) Fax: 33 (0) arkema.com

Let s progress together

Specialty Polyolefins Let s progress together Evasin Ethylene - Acrylate copolymers lotryl.com Bases Specified properties* Typical properties** Main applications Comonomer content (%) (g/10 min) (190 C