: Acetic Acid Assay Kit (ACS Manual Format)

Transcription

1 K-ACET Date of issue: 05/06/2013 Revision date: 14/03/2017 Supersedes: 03/06/2013 Version: 1.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Name : Acetic Acid Assay Kit (ACS Manual Format) K- ACET Bottle Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : For professional use only : Use as laboratory reagent Uses advised against 1.3. Details of the supplier of the safety data sheet Megazyme, Bray Business Park, Bray, Co. Wicklow, A98 YV29, Ireland. T F cs@megazyme.com Emergency telephone number Emergency number : Country Official advisory body Address Emergency number IRELAND (REPUBLIC OF) UNITED KINGDOM SECTION 2: Hazards identification National Poisons Information Centre Beaumont Hospital National Poisons Information Service (Birmingham Centre) City Hospital 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit. 2 H319 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Beaumont Hospital Beaumont Road Dublin 9 Dudley Road Birmingham B18 7QH (UK only) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : H319 - Causes serious eye irritation : P264 - Wash Both hands thoroughly after handling P280 - Wear Personal protective equipment P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 14/03/2017 EN (English) 1/6

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC triethanolamine (CAS No) (EC No) Xi; R36 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] triethanolamine (CAS No) (EC No) Full text of R-, H- and EUH-phrases: see section Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. : Ensure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTRE or doctor/physician. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTRE or doctor/physician. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Causes severe skin burns and eye damage. Suspected of damaging fertility. May damage the unborn child. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapours Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid fire-fighting water entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 14/03/2017 EN (English) 2/6

3 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe Vapours. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Wash Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from direct sunlight. Keep container closed when not in use. : Sources of ignition. Direct sunlight. Belgium Limit value (mg/m³) 5 mg/m³ Italy - Portugal - USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless Odour : Characteristic Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow 14/03/2017 EN (English) 3/6

4 Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms > 5000 mg/kg (6400 mg/kg bodyweight; Rat; Rat; Experimental value, 6400 mg/kg bodyweight; Rat; Rat; Experimental value) > 5000 mg/kg (Rat) > mg/kg (> 2000 mg/kg bodyweight; Rabbit; Rabbit; Experimental value, > 2000 mg/kg bodyweight; Rabbit; Rabbit; Experimental value) Causes severe skin burns and eye damage. : Causes serious eye irritation. Causes severe skin burns and eye damage. 14/03/2017 EN (English) 4/6

5 SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 TLM fish 1 > mg/l (48 h; Leuciscus idus) 2038 mg/l (24 h; Daphnia magna; LOCOMOTOR EFFECT) mg/l (96 h; Lepomis macrochirus) ,Pisces TLM other aquatic organisms Threshold limit algae ,168 h; Scenedesmus quadricauda Threshold limit algae ,168 h; Microcystis aeruginosa Persistence and degradability K- ACET Bottle 1 Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oyxgen demand (COD) ThOD BOD (% of ThOD) Photolysis in the air. Readily biodegradable in water g O 2/g substance 1.50 g O 2/g substance 2.04 g O 2/g substance 0.02 % ThOD Bioaccumulative potential K- ACET Bottle 1 Bioaccumulative potential BCF fish 1 Log Pow Bioaccumulative potential Bioaccumulation unlikely Mobility in soil Results of PBT and vpvb assessment < 3.9 (Cyprinus carpio; TEST DURATION: 6 WEEKS) Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR/RID/ADNR/IMDG/ICAO/IATA UN number Not dangerous goods in sense of transport regulations UN proper shipping name Transport hazard class(es) Packing group Environmental hazards : No supplementary information available 14/03/2017 EN (English) 5/6

6 14.6. Special precautions for user Overland transport Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Indication of changes: Revision - See : *. Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of R-, H- and EUH-phrases:: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation R36 Irritating to eyes Xi Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 14/03/2017 EN (English) 6/6