For our Environment GWP 1. Chemical nomenclature Formula / Composition. Industrial nomenclature
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1 For our Environment Global Warming Potential (GWP) of certain substances and mixtures that contain such substances, based on the Fourth Assessment Report of the Intergovernmental Panel on Climate Change and a hundred years time period Table 1: Table 2: Table 3: Global Warming Potentials (GWP100) of hydrofluorocarbons, hydrochlorofluorocarbons, and perfluorocarbons (HFCs, HCFCs and PFCs), as well as other perfluorinated compounds... 1 Global Warming Potentials (GWP100) of chlorofluoroethers, fluorinated ethers (HCFE, HFE), fluorinated alcohols and perfluoropolyethers (PFPE)... 3 Global Warming Potentials (GWP100) of HFC-mixtures / Refrigerant blends... 5 Table 4: Global Warming Potentials (GWP100) of halogen free substances Table 1: Global Warming Potentials (GWP100) of hydrofluorocarbons, hydrochlorofluorocarbons, and perfluorocarbons (HFCs, HCFCs and PFCs), as well as other perfluorinated compounds Industrial Chemical Formula / GWP 1 Hydrofluorocarbons and hydrochlorofluorocarbons (HFCs, HCFCs) HFC-23 Trifluoromethane CHF HFC-32 Difluoromethane CH2F2 675 HFC-41 Fluoromethane CH3F 92 HFC-125 1,1,1,2,2-Pentafluoroethane CF3-CHF HFC-134 1,1,2,2-Tetrafluoroethane CHF2-CHF HFC-134a 1,1,1,2-Tetrafluoroethane CF3-CH2F HFC-143 1,1,2-Trifluoroethane CHF2-CH2F 353 HFC-143a 1,1,1-Trifluoroethane CF3-CH HFC-152 1,2-Difluoroethane CH2F-CH2F 53 HFC-152a 1,1-Difluoroethane CHF2-CH3 124 HFC-161 Fluoroethane CH2F-CH3 12 HFC-227ea 1,1,1,2,3,3,3-Heptafluoropropane CF3-CHF-CF HFC-236cb 1,1,1,2,2,3-Hexafluoropropane CF3-CF2-CH2F HFC-236ea 1,1,1,2,3,3-Hexafluoropropane CF3-CHF-CHF HFC-236fa 1,1,1,3,3,3-Hexafluoropropane CF3-CH2-CF HFC-245ca 1,1,2,2,3-Pentafluoropropane CHF2-CF2-CH2F 693 HFC-245fa 1,1,1,3,3-Pentafluoropropane CF3-CH2-CHF
2 Chemical Formula / GWP 1 HFC-365mfc 1,1,1,3,3-Pentafluorobutane CF3-CH2-CF2-CH3 794 HFC-43-10mee 1,1,1,2,2,3,4,5,5,5- Decafluoropentane CF3-CF2-CHF-CHF-CF HFC-1234yf 2,3,3,3,Tetrafluoroprop-1-ene CH2=CF-CF3 4 2 HFC-1234ze (E) trans-1,3,3,3-tetrafluoroprop-1-ene CHF=CH-CF3 (E) 7 2 HFC-1336mzz (Z) 1,1,1,4,4,4-Hexafluorobut-2-ene CF3-CH=CH-CF3 (Z) 9 2 HCFC-1233zd (E) trans-1-chloro-3,3,3-trifluoroprop-1- ene CHCl=CH-CF3 (E) 4,5 2 HCFC-1233xf 2-Chloro-3,3,3-trifluoroprop-1-ene CH2=CCl-CF3 1 3 Perfluorocarbons (PFC) PFC-14 PFC-116 PFC-216 PFC-218 PFC-c-318 PFC PFC PFC PFC Tetrafluoromethane (Perfluoromethane) Hexafluoroethane (Perfluoroethane) Hexaafluorocyclopropane (Perfluorocyclopropane) Oktafluoropropane (Perfluoropropane) Octafluorocyclobutane (Perfluorocyclobutane) Decafluorobutane (Perfluorobutane) Dodecafluoropentane (Perfluoropentane) Tetradecafluorohexane (Perfluorohexane) Octadecafluorodecaline (Perfluorodecaline) Other perfluorinated compounds CF C2F c-c3f C3F c-c4f C4F C5F C6F C10F Sulphur hexafluoride SF Nitrogen trifluoride NF Trifluoromethyl sulphur pentafluoride SF5CF If not indicated otherwise, GWP100 from: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 996 pp. 2 GWP100 from: WMO (World Meteorological Organization), Scientific Assessment of Ozone Depletion: 2010, Global Ozone Research and Monitoring Project Report No. 52, Geneva, Switzerland, Standard value, GWP100 not available. 2
3 Table 2: Global Warming Potentials (GWP100) of chlorofluoroethers, fluorinated ethers (HCFE, HFE), fluorinated alcohols and perfluoropolyethers (PFPE) Industrial Chemical Formula / GWP 1 Chlorofluoroethers and fluorinated ethers (HCFE und HFE) HCFE-235ca2 (Enflurane) HCFE-235da2 (Isoflurane) CHF2-O-CF2-CHFCl CHF2-O-CHCl-CF3 350 HFE-125 CHF2-O-CF HFE-134 (HG-00) CHF2-O-CHF HFE-143a CH3-O-CF3 756 HFE-227ea CF3-CHF-O-CF HFE-236ca12 (HG-10) HFE-236ea2 (Desflurane) CHF2-O-CF2-O-CHF CHF2-O-CHF-CF3 989 HFE-236fa CF3-CH2-O-CF3 487 HFE-245cb2 CF3-CF2-O-CH3 708 HFE-245fa1 CHF2-CH2-O-CF3 286 HFE-245fa2 CHF2-O-CH2-CF3 659 HFE-254cb2 CH3-O-CF2-CHF2 359 HFE-263fb2 CF3-CH2-O-CH3 11 HFE-329mcc2 CF3-CF2-O-CF2-CHF2 919 HFE-338mcf2 CF3-CH2-O-CF2-CF3 552 HFE-338mmz1 (CF3)2CH-O-CHF2 380 HFE-338pcc13 (HG-01) HFE-347mcc3 (HFE-7000) CHF2-O-CF2-CF2-O-CHF CH3-O-CF2-CF2-CF3 575 HFE-347mcf2 CHF2-CH2-O-CF2-CF3 374 HFE-347mmy1 (CF3)2CF-O-CH3 343 HFE-347mmz1 (Sevoflurane) CH2F-O-CH(CF3) HFE-347pcf2 CHF2-CF2-O-CH2-CF3 580 HFE-356mec3 CH3-O-CF2-CHF-CF3 101 HFE-356mm1 (CF3)2CH-O-CH3 27 3
4 Chemical Formula / GWP 1 HFE-356pcc3 CH3-O-CF2-CF2-CHF2 110 HFE-356pcf2 CHF2-CH2-O-CF2-CHF2 265 HFE-356pcf3 CHF2-O-CH2-CF2-CHF2 502 HFE-365mcf3 CF3-CF2-CH2-O-CH3 11 HFE-374pc2 CHF2-CF2-O-CH2-CH3 557 HFE-449sl (HFE-7100) HFE-569sf2 (HFE-7200) HFE-43-10pccc124 (H-Galden 1040x) Fluorinated alcohols C4F9-O-CH3 297 C4F9-O-C2H5 59 CHF2-O-CF2-O-C2F4-O-CHF ,2,3,3,3-Pentafluoropropan-1-ol CF3-CF2-CH2-OH 42 Bis(trifluoromethyl)methanol (CF3)2CH-OH 195 Perfluoropolyether (PFPE) Octafluortetramethylenhydroxymethyl-group -(CF2)4CH(OH)- 73 PFPMIE Perfluoropolymethylisopropylether CF3(O-CF(CF3)CF2)n-(O-CF2)m- O-CF3 (n,m=1) 1 If not indicated otherwise GWP100 taken from: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 996 pp. 4 GWP100 from: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp
5 Table 3: Global Warming Potentials (GWP100) of HFC-mixtures / Refrigerant blends Industrial Chemical Formula / GWP 1,5 HFC-mixtures / Refrigerant blends R404A HFC-125 (CHF2-CF3): 44% HFC-134a (CH2F-CF3): 4% HFC-143a (CH3-CF3): 52% R407A HFC-32 (CH2F2): 20% HFC-125 (CHF2-CF3): 40% HFC-134a (CF3-CH2F):40% R407B HFC-32 (CH2F2): 10% HFC-125 (CHF2-CF3): 70% HFC-134a (CF3-CH2F): 20% R407C HFC-32 (CH2F2): 23% HFC-125 (CHF2-CF3): 25% HFC-134a (CH2F-CF3): 52% R407D HFC-32 (CH2F2): 15% HFC-125 (CHF2-CF3): 15% HFC-134a (CF3-CH2F): 70% R407E HFC-32 (CH2F2): 25% HFC-125 (CHF2-CF3): 15% HFC-134a (CF3-CH2F): 60% R407F HFC-32 (CH2F2): 30% HFC-125 (CHF2-CF3): 30% HFC-134a (CF3-CH2F): 40% R407G HFC-32 (CH2F2): 2,5% HFC-125 (CHF2-CF3): 2,5% HFC-134a (CF3-CH2F): 95% R410A HFC-32 (CH2F2): 50% HFC-125 (CHF2-CF3): 50% R410B HFC-32 (CH2F2): 45% HFC-125 (CHF2-CF3): 55 % R413A HFC-134a (CH2F-CF3): 88% PFC-218 (CF3-CF2-CF3): 9% R600a (CH(CH3)3): 3% R417A HFC-125 (CHF2-CF3): 46,6% HFC-134a (CH2F-CF3): 50% R600 (CH3-CH2-CH2-CH3): 3,4% R417B HFC-125 (CHF2-CF3): 79% HFC-134a (CH2F-CF3): 18,3% R600 (CH3-CH2-CH2-CH3): 2,7% R417C HFC-125 (CHF2-CF3): 19,5% HFC-134a (CH2F-CF3): 78,8% R600 (CH3-CH2-CH2-CH3): 1,7%
6 Chemical Formula / GWP 1,5 R419A HFC-125 (CHF2-CF3): 77% HFC-134a (CF3-CH2F): 19% RE170 (CH3-O-CH3): 4 % R419B HFC-125 (CHF2-CF3): 48,5% HFC-134a (CF3-CH2F): 48% RE170 (CH3-O-CH3): 3,5% R421A HFC-125 (CHF2-CF3): 58% HFC-134a (CF3-CH2F): 42% R421B HFC-125 (CHF2-CF3): 85% HFC-134a (CF3-CH2F): 15% R422A HFC-125 (CHF2-CF3): 85,1% HFC-134a (CF3-CH2F): 11,5% R600a (CH(CH3)3): 3,4% R422B HFC-125 (CHF2-CF3): 55% HFC-134a (CF3-CH2F): 42% R600a (CH(CH3)3): 3% R422C HFC-125 (CHF2-CF3): 82% HFC-134a (CF3-CH2F): 15% R600a (CH(CH3)3): 3% R422D HFC-125 (CHF2CF3): 65,1% HFC-134a (CF3-CH2F): 31,5% R600a (CH(CH3)3): 3,4% R422E HFC-125 (CHF2CF3): 58% HFC-134a (CF3-CH2F): 39,3% R600a (CH(CH3)3): 2,7% R423A HFC-134a (CF3-CH2F): 52,5% HFC-227ea (CF3-CHF-CF3): 47,5% R424A HFC-125 (CHF2-CF3): 50,5% HFC-134a (CF3-CH2F): 47% R600 (CH3-CH2-CH2-CH3): 1% R600a (CH(CH3)3): 0,9% R601a (CH3CH(CH3)CH2CH3): 0,6% R425A HFC-32 (CH2F2): 18,5% HFC-134a (CF3-CH2F): 69,5% HFC-227ea (CF3-CHF-CF3): 12% R426A HFC-125 (CHF2-CF3): 5,1% HFC-134a (CF3-CH2F): 93% R600 (CH3-CH2-CH2-CH3): 1,3% R601a (CH3CH(CH3)CH2CH3): 0,6% R427A HFC-32 (CH2F2): 15% HFC-125 (CHF2-CF3): 25% HFC-134a (CF3-CH2F): 50% HFC-143a (CH3-CF3): 10%
7 Chemical Formula / GWP 1,5 R428A HFC-125 (CHF2-CF3): 77,5% HFC-143a (CH3-CF3): 20% R290 (CH3-CH2-CH3): 0,6% R600a (CH(CH3)3): 1,9% R429A HFC-152a (CHF2-CH3): 10% RE170 (CH3-O-CH3): 60% R600a (CH(CH3)3): 30% R430A HFC-152a (CHF2-CH3): 76% R600a (CH(CH3)3): 24% R431A HFC-152a (CHF2-CH3): 29% R290 (CH3-CH2-CH3): 71% R434A HFC-125 (CHF2-CF3): 63,2% HFC-134a (CF3-CH2F): 16% HFC-143a (CH3-CF3): 18% R600a (CH(CH3)3): 2,8% R435A HFC-152a (CHF2-CH3): 20% RE170 (CH3-O-CH3): 80% R437A HFC-125 (CHF2-CF3): 19,5% HFC-134a (CF3-CH2F): 78,5% R600 (CH3-CH2-CH2-CH3): 1,4% R601 (CH3-CH2-CH2-CH2-CH3) : 0,6% R438A HFC-32 (CH2F2): 8,5% HFC-125 (CHF2-CF3): 45% HFC-134a (CF3-CH2F): 44,2% R600 (CH3-CH2-CH2-CH3): 1,7% R601a (CH3CH(CH3)CH2CH3): 0,6% R439A HFC-32 (CH2F2): 50% HFC-125 (CHF2-CF3): 47% R600a (CH(CH3)3): 3% R440A HFC-134a (CF3-CH2F): 1,6% HFC-152a (CHF2-CH3): 97,8% R290 (CH3-CH2-CH3): 0,6% R442A HFC-32 (CH2F2): 31% HFC-125 (CHF2-CF3): 31% HFC-134a (CF3-CH2F): 30% HFC-152a (CHF2-CH3): 3% HFC-227ea (CF3-CHF-CF3): 5% R444A HFC-32 (CH2F2): 12% HFC-152a (CHF2-CH3): 5% HFC-1234ze (CHF=CH-CF3): 83% R444B HFC-32 (CH2F2): 41,5% HFC-152a (CHF2-CH3): 10% HFC-1234ze (CHF=CH-CF3): 48,5%
8 Chemical Formula / GWP 1,5 R445A HFC-134a (CF3-CH2F): 9% HFC-1234ze (CHF=CH-CF3): 85% R744 (CO2): 6% R446A HFC-32 (CH2F2): 68% HFC-1234ze (CHF=CH-CF3): 29% R600 (CH3-CH2-CH2-CH3): 3% R447A HFC-32 (CH2F2): 68% HFC-125 (CHF2-CF3): 3,5% HFC-1234ze (CHF=CH-CF3): 28,5% R448A HFC-32 (CH2F2): 26% HFC-125 (CHF2-CF3): 26% HFC-134a (CF3-CH2F): 21% HFC-1234yf (CH2=CF-CF3): 20% HFC-1234ze (CHF=CH-CF3): 7% R449A HFC-32 (CH2F2): 24,3% HFC-125 (CHF2-CF3): 24,7% HFC-134a (CF3-CH2F): 25,7% HFC-1234yf (CH2=CF-CF3): 25,3% R449B HFC-32 (CH2F2): 25,2% HFC-125 (CHF2-CF3): 24,3% HFC-134a (CF3-CH2F): 27,3% HFC-1234yf (CH2=CF-CF3): 23,2% R449C HFC-32 (CH2F2): 20% HFC-125 (CHF2-CF3): 20% HFC-134a (CF3-CH2F): 29% HFC-1234yf (CH2=CF-CF3): 31% R450A HFC-134a (CF3-CH2F): 42% HFC-1234ze (CHF=CH-CF3): 58% R451A HFC-134a (CF3-CH2F): 10,2% HFC-1234yf (CH2=CF-CF3): 89,8% R451B HFC-134a (CF3-CH2F): 11,2% HFC-1234yf (CH2=CF-CF3): 88,8% R452A HFC-32 (CH2F2): 11% HFC-125 (CHF2-CF3): 59% HFC-1234yf (CH2=CF-CF3): 30% R452B HFC-32 (CH2F2): 67% HFC-125 (CHF2-CF3): 7% HFC-1234yf (CH2=CF-CF3): 26% R452C HFC-32 (CH2F2): 12,5% HFC-125 (CHF2-CF3): 61% HFC-1234yf (CH2=CF-CF3): 26,5%
9 Chemical Formula / GWP 1,5 R453A HFC-32 (CH2F2): 20% HFC-125 (CHF2-CF3): 20% HFC-134a (CF3-CH2F): 53,8% HFC-227ea (CF3-CHF-CF3): 5% R600 (CH3-CH2-CH2-CH3): 0,6% R601a (CH3CH(CH3)CH2CH3): 0,6% R454A HFC-32 (CH2F2): 35% HFC-1234yf (CH2=CF-CF3): 65% R454B HFC-32 (CH2F2): 68,9% HFC-1234yf (CH2=CF-CF3): 31,1% R454C HFC-32 (CH2F2): 21,5% HFC-1234yf (CH2=CF-CF3): 78,5% R455A HFC-32 (CH2F2): 21,5% HFC-1234yf (CH2=CF-CF3): 75,5% R744 (CO2): 3% R456A HFC-32 (CH2F2): 6% HFC-134a (CF3-CH2F): 45% HFC-1234ze (CHF=CH-CF3): 49% R457A HFC-32 (CH2F2): 18% HFC-152a (CHF2-CH3): 12% HFC-1234yf (CH2=CF-CF3): 70% R507A HFC-125 (CHF2-CF3): 50% HFC-143a (CH3-CF3): 50% R508A HFC-23 (CHF3): 39% PFC-116 (C2F6): 61% R508B HFC-23 (CHF3): 46% PFC-116 (C2F6): 54% R511A HFC-152a (CHF2-CH3): 5% R290 (CH3-CH2-CH3): 95% R512A HFC-134a (CF3-CH2F): 5% HFC-152a (CHF2-CH3): 95% R513A HFC-134a (CF3-CH2F): 44% HFC-1234yf (CH2=CF-CF3): 56% R513B HFC-134a (CF3-CH2F): 41,5% HFC-1234yf (CH2=CF-CF3): 58,5% R514A HFC-1336mzz (CF3-CH=CH-CF3): 74,7% R1130 (CHCl=CHCl): 25,3% R515A HFC-227ea (CF3-CHF-CF3): 12% HFC-1234ze (CHF=CH-CF3): 88% Isceon MO89 HFC-125 (CF3-CHF2): 86% PFC-218 (CF3-CF2-CF3): 9% R290 (CH3-CH2-CH3): 5%
10 Table 4: Global Warming Potentials (GWP100) of halogen free substances Industrial Chemical Formula / GWP 1 Halogen free substances Methane CH4 25 R170 Ethane CH3-CH3 6 R290 Propane CH3-CH2-CH3 3 R600 n-butane CH3-CH2-CH2-CH3 4 R600a i-butane (Isobutane) (CH3)2-CH-CH3 3 R601 n-pentane CH3-CH2-CH2-CH2-CH3 5 5 R601a i-pentane (Isopentane) (CH3)2-CH-CH2-CH3 5 5 RE170 Dimethyl ether (DME) CH3-O-CH3 1 R610 Diethyl ether CH3-CH2-O-CH2-CH3 4 R611 Methyl formate HCOOCH3 25 R702 Hydrogen H2 6 R717 Ammonia NH3 0 R718 Water H2O 0 R723 Dimethyl ether/ammonia - Blend R717 (NH3): 60% RE170 (CH3-O-CH3): 40% R744 Carbon dioxide CO2 1 R1150 Ethene (Ethylene) CH2=CH2 4 R1270 Propene (Propylene) CH2=CH-CH3 2 1 If not indicated otherwise GWP100 taken from: Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 996 pp. 5 Standard value based on GWP100 of other hydrocarbons. 1 Contact: Umweltbundesamt (German Environment Agency) PO box Dessau-Roßlau Germany Phone: info@umweltbundesamt.de As at: May
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