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1 Encyclopedic Entry For Student natural gas For the complete encyclopedic entry with media resources, visit: Natural gas is a fossil fuel. Like other fossil fuels such as coal and oil, natural gas forms from the plants, animals, and microorganisms that lived millions of years ago. There are several different theories to explain how fossil fuels are formed. The most prevalent theory is that they form underground, under intense conditions. As plants, animals, and microorganisms decompose, they are gradually covered by layers of soil, sediment, and sometimes rock. Over millions of years, the organic matter is compressed. As the organic matter moves deeper into Earth s crust, it encounters higher and higher temperatures. The combination of compression and high temperature causes the carbon bonds in the organic matter to break down. This molecular breakdown produces thermogenic methane natural gas. Methane, probably the most abundant organic compound on Earth, is made of carbon and hydrogen (CH4). Natural gas deposits are often found near oil deposits. Deposits of natural gas close to the Earth s surface are usually dwarfed by nearby oil deposits. Deeper deposits formed at higher temperatures and under more pressure have more natural gas than oil. The deepest deposits can be made up of pure natural gas. Natural gas does not have to be formed deep underground, however. It can also be formed by tiny microorganisms called methanogens. Methanogens live in the intestines of animals (including humans) and in lowoxygen areas near the surface of the Earth. Landfills, for example, are full of decomposing matter that methanogens break down into a type of methane called biogenic methane. The process of methanogens creating natural gas (methane) is called methanogenesis. Although most biogenic methane escapes into the atmosphere, there are new technologies being created to contain and harvest this potential energy source. Thermogenic methane the natural gas formed deep beneath the Earth s surface can also escape into the atmosphere. Some of the gas is able to rise through permeable matter, such as porous rock, and eventually dissipate into the atmosphere. However, most thermogenic methane that rises toward the surface encounters geological formations that are too impermeable for it to escape. These rock formations are called sedimentary basins. Sedimentary basins trap huge reservoirs of natural gas. In order to gain access to these natural gas reservoirs, a hole (sometimes called a well) must be drilled through the rock to allow the gas to escape and be harvested. Sedimentary basins rich in natural gas are found all over the world. The deserts of Saudi Arabia, the humid tropics of Venezuela, and the freezing Arctic of the U.S. state of Alaska are all sources of natural gas. In the United States outside Alaska, basins are primarily around the states bordering the Gulf of Mexico, including Texas and Louisiana. 1 of 9

2 Recently, the northern states of North Dakota, South Dakota, and Montana have developed significant drilling facilities in sedimentary basins. Types of Natural Gas Natural gas that is economical to extract and easily accessible is considered conventional. Conventional gas is trapped in permeable material beneath impermeable rock. Natural gas found in other geological settings is not always so easy or practical to extract. This gas is called unconventional. New technologies and processes are always being developed to make this unconventional gas more accessible and economically viable. Over time, gas that was considered unconventional can become conventional. Biogas is a type of gas that is produced when organic matter decomposes without oxygen being present. This process is called anaerobic decomposition, and it takes place in landfills or where organic material such as animal waste, sewage, or industrial byproducts are decomposing. Biogas is biological matter that comes from plants or animals, which can be living or not-living. This material, such as forest residues, can be combusted to create a renewable energy source. Biogas contains less methane than natural gas, but can be refined and used as an energy source. Deep Natural Gas Deep natural gas is an unconventional gas. While most conventional gas can be found just a few thousand meters deep, deep natural gas is located in deposits at least 4,500 meters (15,000 feet) below the surface of the Earth. Drilling for deep natural gas is not always economically practical, although techniques to extract it have been developed and improved. Shale Shale gas is another type of unconventional deposit. Shale is a fine-grained, sedimentary rock that does not disintegrate in water. Some scientists say shale is so impermeable that marble is considered spongy in comparison. Thick sheets of this impermeable rock can sandwich a layer of natural gas between them. Shale gas is considered an unconventional source because of the difficult processes necessary to access it: hydraulic fracturing (also known as fracking) and horizontal drilling. Fracking is a procedure that splits open rock with a high-pressure stream of water, and then props it open with tiny grains of sand, glass, or silica. This allows gas to flow more freely out of the well. Horizontal drilling is a process of drilling straight down into the ground, then drilling sideways, or parallel, to the Earth s surface. Tight Gas Tight gas is an unconventional natural gas trapped underground in an impermeable rock formation that makes it extremely difficult to extract. Extracting gas from tight rock formations usually requires expensive and difficult methods, such as fracking and acidizing. Acidizing is similar to fracking. An acid (usually hydrochloric acid) is injected into the natural gas well. The acid dissolves the tight rock that is blocking the flow of gas. Coalbed Methane Coalbed methane is another type of unconventional natural gas. As its name implies, coalbed methane is commonly found along seams of coal that run underground. Historically, when coal was mined, the natural gas was intentionally vented out of the mine and into the atmosphere as a waste product. Today, coalbed methane is 2 of 9

3 collected and is a popular energy source. Gas in Geopressurized Zones Another source of unconventional natural gas is geopressurized zones. Geopressurized zones form 3,000-7,600 meters (10,000-25,000 feet) below the Earth s surface. These zones form when layers of clay rapidly accumulate and compact on top of material that is more porous, such as sand or silt. Because the natural gas is forced out of the compressed clay, it is deposited under very high pressure into the sand, silt, or other absorbent material below. Geopressurized zones are very difficult to mine, but they may contain a very high amount of natural gas. In the United States, most geopressurized zones have been found in the Gulf Coast region. Methane Hydrates Methane hydrates are another type of unconventional natural gas. Methane hydrates were discovered only recently in ocean sediments and permafrost areas of the Arctic. Methane hydrates form at low temperatures (around 0 C, or 32 F) and under high pressure. When environmental conditions change, methane hydrates are released into the atmosphere. The United States Geological Survey (USGS) estimates that methane hydrates could contain twice the amount of carbon than all of the coal, oil, and conventional natural gas in the world, combined. In ocean sediments, methane hydrates form on the continental slope as bacteria and other microorganisms sink to the ocean floor and decompose in the silt. Methane, trapped within the sediments, has the ability to cement the loose sediments into place and keep the continental shelf stable. However, if the water becomes warmer, the methane hydrates break down. This causes causes underwater landslides, and releases natural gas. In permafrost ecosystems, methane hydrates form as bodies of water freeze and water molecules create individual cages around each methane molecule. The gas, trapped in a frozen lattice of water, is contained at a much higher density than it would be in its gaseous state. As the ice cages thaw, the methane escapes. Global warming, the current period of climate change, influences the release of methane hydrates from both permafrost and ocean sediment layers. There is a vast amount of potential energy stored in methane hydrates. However, because they are such fragile geological formations capable of breaking down and disrupting the environmental conditions around them methods for extracting them are developed with extreme caution. Drilling and Transportation Natural gas is measured in normal cubic meters or standard cubic feet. In 2009, the United States Energy Information Administration (EIA) estimated that the world s proven natural gas reserves are around 6,289 trillion cubic feet (tcf). Most of the reserves are in the Middle East, with 2,686 tcf in 2011, or 40 percent of total world reserves. Russia has the second-highest amount of proven reserves, with 1,680 tcf in The United States contains just over 4 percent of the world s natural gas reserves. < According to the EIA, total world consumption of dry natural gas in 2010 was 112,920 billion cubic feet (bcf). That year, the United States consumed a little more than 24,000 bcf, the most of any nation. 3 of 9

4 Natural gas is most commonly extracted by drilling vertically from the Earth s surface. From a single vertical drill, the well is limited to the gas reserves it encounters. Hydraulic fracturing, horizontal drilling, and acidizing are processes to expand the amount of gas that a well can access, and thus increase its productivity. However, these practices can have negative environmental consequences. Hydraulic fracturing, or fracking, is a process that splits open rock formations with high-pressure streams of water, chemicals, and sand. The sand props open the rocks, which allows gas to escape and be stored or transported. However, fracking requires huge quantities of water, which can radically reduce an area s water table and negatively impact aquatic habitats. The process produces highly toxic and frequently radioactive wastewater that, if mismanaged, can leak and contaminate underground water sources used for drinking, hygiene, and industrial and agricultural use. In addition, fracking can cause micro-earthquakes. Most of these temblors are far too tiny to be felt on the surface, but some geologists and environmentalists warn that the quakes may cause structural damage to buildings or underground networks of pipes and cables. Due to these negative environmental effects, fracking has been criticized and banned in some areas. In other areas, fracking is a lucrative economic opportunity and providing a reliable source of energy. Horizontal drilling is a way of increasing the area of a well without creating multiple expensive and environmentally sensitive drilling sites. After drilling straight down from the Earth s surface, drilling can be directed to go sideways horizontally. This broadens the well s productivity without requiring multiple drilling sites on the surface. Acidizing is a process of dissolving acidic components and inserting them into the natural gas well, which dissolves rock that may be blocking the flow of gas. After natural gas is extracted, it is most frequently transported through pipelines that can be from 2 to 60 inches in diameter. The continental United States has more than 210 pipeline systems that are made up of 490,850 kilometers (305,000 miles) of transmission pipelines that transfer gas to all 48 states. This system requires more than 1,400 compressor stations to ensure that the gas continues on its path, 400 underground storage facilities, 11,000 locations to deliver the gas, and 5,000 locations to receive the gas. Natural gas can also be cooled to about -162 C (-260 F) and converted into liquified natural gas, or LNG. In liquid form, natural gas takes up only 1/600 of the volume of its gaseous state. It can easily be stored and transported places that do not have pipelines. LNG is tranported by a specialized insulated tanker, which keeps the LNG at its boiling point. If any of the LNG vaporizes, it is vented out of the storage area and used to power the transport vessel. The United States imports LNG from other countries, including Trinidad and Tobago and Qatar. However, the U.S. is currently increasing its domestic LNG production. Consuming Natural Gas Although natural gas takes millions of years to develop, its energy has only been harnessed during the past few thousand years. Around 500 BCE, Chinese engineers made use of natural gas seeping out of the Earth by building bamboo pipelines. These pipes transported gas to heat water. In the late 1700s, British companies provided natural gas to light streetlamps and homes. 4 of 9

5 Today, natural gas is used in countless ways for industrial, commercial, residential, and transportation purposes. The United States Department of Energy (DOE) estimates that natural gas can be up to 68 percent less expensive than electricity. In residential homes, the most popular use for natural gas is heating and cooking. It is used to power home appliances such as stoves, air conditioners, space heaters, outdoor lights, garage heaters, and clothes dryers. Natural gas is also used on a larger scale. In commercial settings, such as restaurants and shopping malls, it is an extremely efficient and economical way to power water heaters, space heaters, dryers, and stoves. Natural gas is used to heat, cool, and cook in industrial settings, as well. However, it is also used in a variety of processes such as waste treatment, food processing, and refining metals, stone, clay, and petroleum. Natural gas can also be used as an alternative fuel for cars, buses, trucks, and other vehicles. Currently, there are more than 5 million natural gas vehicles (NGV) worldwide, and more than 150,000 in the United States. Although NGVs initially cost more than gas-powered vehicles, they are cheaper to re-fuel and are the cleanestrunning vehicles in the world. Gasoline- and diesel-powered vehicles emit harmful and toxic substances including arsenic, nickel, and nitrogen oxides. In contrast, NGVs may emit minute amounts of propane or butane, but release 70 percent less carbon monoxide into the atmosphere. Using the new technology of fuel cells, the energy from natural gas is also used to generate electricity. Instead of burning natural gas for energy, fuel cells generate electricity with electrochemical reactions. These reactions produce water, heat, and electricity without any other byproducts or emissions. Scientists are still researching this method of producing electricity in order to affordably apply it to electric products. Natural Gas and the Environment Natural gas usually needs to be processed before it can be used. When it is extracted, natural gas can contain a variety of elements and compounds other than methane. Water, ethane, butane, propane, pentanes, hydrogen sulphide, carbon dioxide, water vapor, and occasionally helium and nitrogen may be present in a natural gas well. In order to be used for energy, the methane is processed and separated from the other components. The gas that is used for energy in our homes is almost pure methane. Like other fossil fuels, natural gas can be burned for energy. In fact, it is the cleanest-burning fuel, meaning it releases very few byproducts. When fossil fuels are burned, they can release (or emit) different elements, compounds, and solid particles. Coal and oil are fossil fuels with very complex molecular formations, and contain a high amount of carbon, nitrogen, and sulfur. When they are burned, they release high amounts of harmful emissions, including nitrogen oxides, sulfur dioxide, and particles that drift into the atmosphere and contribute to air pollution. In contrast, the methane in natural gas has a simple molecular make-up: CH4. When it is burned, it emits only carbon dioxide and water vapor. Humans exhale the same two components when we breathe. Carbon dioxide and water vapor, along with other gases such as ozone and nitrous oxide, are known as greenhouse gases. The increasing amounts of greenhouse gases in the atmosphere are linked to global warming and could have disastrous environmental consequences. Although burning natural gas still emits greenhouse gases, it emits almost 30 percent less CO2 than oil, and 45 5 of 9

6 percent less CO2 than coal. Safety As with any extractive activity, drilling for natural gas can lead to leaks. If the drill hits an unexpected high-pressure pocket of natural gas, or the well is damaged or ruptures, the leak can be immediately hazardous. Because natural gas dissapates so quickly into the air, it does not always cause an explosion or burn. However, the leaks are an environmental hazard that also leak mud and oil into the surrounding areas. If hydraulic fracturing was used to expand a well, the chemicals from that process can contaminate local aquatic habitats and drinking water with highly radioactive materials. The uncontained methane released in the air can also force people to temporary evacuate the area. Leaks can also occur slowly over time. Until the 1950s, cast iron was a popular choice for distribution pipelines, but it allows a high amount of natural gas to escape. The cast iron pipes become leaky after years of freeze-thaw cycles, heavy overhead traffic, and strains from the naturally shifting soil. Methane leaks from these distribution pipelines make up more than 30 percent of the methane emmissions in the U.S. natural gas distribution sector. Today, pipelines are made out of a variety of metals and plastics to reduce leakage. VOCABULARY Term Part of Speech Definition acidizing process of injecting acid into a natural gas well to dissolve the rock and free the gas. anaerobic decomposition process by which microbes such as bacteria decompose organic material in the absence of oxygen. Arctic region at Earth's extreme north, encompassed by the Arctic Circle. arsenic chemical element with the symbol As. atmosphere layers of gases surrounding a planet or other celestial body. bacteria plural (singular: bacterium) single-celled organisms found in every ecosystem on Earth. biogas fuel produced by bacteria helping to decompose organic material, such as plants and sewage. biogenic adjective resulting from the activity of living organisms. butane hydrocarbon gas used as fuel. byproduct substance that is created by the production of another material. carbon bond chemical bond (covalent, single) made up of two electrons shared between two carbon atoms. carbon monoxide toxic gas. cast iron iron alloy containing so much carbon that it cannot be wrought (shaped) but must be cast into shape. climate change gradual changes in all the interconnected weather elements on our planet. 6 of 9

7 coal dark, solid fossil fuel mined from the earth. coalbed methane natural gas extracted from coal seams. Also called coal mine methane. combust verb to burn. compact verb to pack tightly together. compress verb to press together in a small space. contaminate verb to poison or make hazardous. continental slope conventional gas the sometimes-steep descent of a continental shelf to the ocean floor. natural gas (methane) trapped in permeable material beneath impermeable rock. crust rocky outermost layer of Earth or other planet. decompose verb to decay or break down. deep natural gas unconventional gas found in pockets at least 4,500 meters (15,000 feet) below the surface of the Earth. diesel oil or other fuel used in diesel engines, emitting a low, constant temperature. disintegrate verb to fall apart and disappear. dissipate verb to scatter and disappear. earthquake the sudden shaking of Earth's crust caused by the release of energy along fault lines or from volcanic activity. ecosystem community and interactions of living and nonliving things in an area. electricity set of physical phenomena associated with the presence and flow of electric charge. fossil fuel coal, oil, or natural gas. Fossil fuels formed from the remains of ancient plants and animals. fracking process usually used to extract oil and natural gas in which fractures in the Earth's surface are opened and widened by injecting water, chemicals, and sand at high pressure. Also called hydraulic fracturing. fuel cell device that produces an electric current by combining a fuel, usually hydrogen, with oxygen. geologist person who studies the physical formations of the Earth. geopressurized zone natural underground formations that are under unusually high pressure for their depth, 3,000-7,600 meters (10,000-25,000 feet) below the Earth's surface. global warming increase in the average temperature of the Earth's air and oceans. greenhouse gas gas in the atmosphere, such as carbon dioxide and ozone, that absorbs solar heat reflected by the surface of the Earth, warming the atmosphere. humid adjective air containing a large amount of water vapor. 7 of 9

8 hydraulic fracturing hydrochloric acid process usually used to extract oil and natural gas in which fractures in the Earth's surface are opened and widened by injecting water, chemicals, and sand at high pressure. Also called fracking. (HCl) strong, poisonous solution of hydrogen chloride in water. Also called muriatic acid. hygiene science and methods of keeping clean and healthy. intestine tubular system in the human digestive system, which regulates elimination of waste products from the body. landfill site where garbage is layered with dirt and other absorbing material to prevent contamination of the surrounding land or water. landslide the fall of rocks, soil, and other materials from a mountain, hill, or slope. LNG (liquified natural gas) natural gas that has been cooled and liquified for ease in storage and transportation. lucrative adjective profitable or money-making. methane chemical compound that is the basic ingredient of natural gas. methane hydrate unconventional natural gas made of a lattice of frozen water, which forms a "cage" around molecules of methane. methanogen microbe (Archaea), living in the intestinces of some animals and in low-oxygen areas of the Earth, able to create natural gas (methane). methanogenesis process by which microbes create natural gas (methane). Also called biomethanation. Middle East region of southwest Asia and northeast Africa. minute adjective very small amount. natural gas type of fossil fuel made up mostly of the gas methane. oil fossil fuel formed from the remains of marine plants and animals. Also known as petroleum or crude oil. organic adjective composed of living or once-living material. ozone form of oxygen that absorbs ultraviolet radiation. permafrost permanently frozen layer of the Earth's surface. permeable adjective allowing liquid and gases to pass through. prevalent adjective common or widespread. propane hydrocarbon gas used as fuel. radioactive waste renewable energy byproduct of nuclear fission that emits a type of heat, or radiation, that can damage the tissue of living organisms. energy obtained from sources that are virtually inexhaustible and replenish naturally over small time scales relative to the human life span. sediment solid material transported and deposited by water, ice, and wind. sedimentary basin depression in the Earth's surface that has slowly been filled with layers of sand, rock, and other debris (sediment). 8 of 9

9 sedimentary rock rock formed from fragments of other rocks or the remains of plants or animals. sewage liquid and solid waste material from homes and businesses. shale type of sedimentary rock. silica chemical compound (SiO2) that makes up most of the Earth's rocks. silt small sediment particles. temblor earthquake. thermogenic adjective producing heat through natural processes. tight gas unconventional gas trapped in impermeable rock formations. toxic adjective poisonous. tropics region generally located between the Tropic of Cancer (23 1/2 degrees north of the Equator) and the Tropic of Capricorn (23 1/2 degrees south of the Equator). unconventional gas natural gas found in geological formations that make it difficult and expensive to extract. USGS (United States Geological Survey) primary source for science about the Earth, its natural and living resources, natural hazards, and the environment. viable adjective capable of growing and sustaining itself. water table underground area where the Earth's surface is saturated with water. Also called water level. FOR FURTHER EXPLORATION Articles & Profiles EIA Energy Kids: Natural Gas National Geographic News: Natural Gas Stirs Hope and Fear in Pennsylvania Interactives Federal Energy Regulatory Commission: Projects Near You Worksheets & Handouts National Energy Technology Laboratory: Shale Gas Websites U.S. Environmental Protection Agency: Clean Energy Natural Gas National Geographic Society. All rights reserved. 9 of 9

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