Joogi-, põhja-, pinna-, mere-, heitja reovesi, sademed Drinking, ground, surface and seawater, effluent, waste water, precipitation

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1 LISA 1 OÜ Eesti Keskkonnauuringute Keskuse akrediteerimistunnistusele L008 of Estonian Environmental Research Centre LLC 1. Akrediteerimisulatus on: Accreditation scope is: 1.1. Keskkonna analüüsid Environmental analyses Materials or products tested / tested Fotomeetria Photometry 1.1 Ammooniumioon (NH 4 + ) Ammonium ion 1.2 Nitritioon (NO - 2 ) ja nitraatioon (NO - 3 ) ning nende summa (pidevvooluanalüsaatoriga) Nitrite ion and nitrate ion and the sum of both by flow analysis method 1.3 Üldlämmastik (N üld) (oksüdeerimine peroksodisulfaadiga) Total nitrogen (N tot) (digestion with peroxodisulfate) 1.4 Sulfaatioon (SO 2-4 ) Sulfate ion 1.5 Ortofosfaatioon (PO 4 3- ) Ortophosphate ion 1.6 Üldfosfor (P üld) Total phosphorus (P tot) 1.7 Üldfosfor (P üld) Total phosphorus (P tot) 1.8 Üldraud (Fe) Total iron 1.9 Kahevalentne raud (Fe 2+ ) Iron (II), sademed sea, effluent, waste, precipitation sea, effluent, waste Põhja-, pinna- ja merevesi, sademed Ground, surface and sea, precipitation Põhja-, pinna-, heit- ja Ground and surface, effluent and waste sea, effluent, waste Põhja-, pinna-, heit- ja Ground, surface, effluent, and waste Joogi, põhja-, pinna-, heit- ja effluent, waste Joogi- ja põhjavesi Drinking and ground SFS AOAC sec sec 7 STJV26B SFS 3028 STJV28

2 Leht/Page 2/ Hägusus Turbidity 1.11 Tsüaniid (CN - ) Cyanide Gravimeetria 1.12 Kuivjääk, Dry residue Lahustunud aine kuivjääk Total dissolved solids Kuivaine (KA), niiskus Dry matter, moisture 1.13 Põletusjääk, orgaaniline aine Ignition residue, organic matter 1.14 Hõljuvaine Suspended solids Materials or products tested / tested Joogi-, põhja- ja pinnavesi waste, effluent Gravimetric determinations, leostis 2 effluent, waste, eluate 2 Joogi-, põhja-, pinna-, heit-, effluent, waste Põhja-, pinna-, mere-, heit- ja Ground, surface, sea and waste EVS EN ISO 7027 ISO , Sec 2 SFS 3008 STJ V8 EVS-EN STJ V8 SFS 3008 EVS-EN STJ V8 EVS-EN Värvus Colour Füüsikalis keemilised katsed Physical Chemical tests Joogi-, põhja- ja pinnavesi Drinking, ground and surface 7887 sec D Tiitrimeetria 1.16 Kaltsiumioon (Ca 2+ ) Calcium ion 1.17 Üldkaredus Total hardness 1.18 Kloriidioon (Cl - ) (Mohr i meetod) Chloride ion (Mohr method) 1.19 Leelisus Alkalinity Titrimetric determination Drinking, ground surface, Joogi-, põhja- ja pinnavesi, sademed precipitation ISO 6058 ISO 6059 ISO

3 Leht/Page 3/ Keemiline (dikromaatne) hapnikutarve (KHT Cr) Chemical oxygen demand (COD Cr) 1.21 Keemiline (permanganaatne) hapnikutarve e. oksüdeeritavus (KHT Mn) Permanganate index (COD Mn) 1.22 Üldlämmastik (N üld) (modifitseeritud Kjeldahl meetod) Total nitrogen (N tot) (modified Kjeldahl method) 1.23 Üldlämmastik (N üld) (modifitseeritud Kjeldahl) Total nitrogen (N tot) (modified Kjeldahl method) 1.24 ph ph 1.25 ph ph Elektrokeemilised määramised 1.26 Elektrijuhtivus Electrical conductivity 1.27 Biokeemiline hapnikutarve (BHT n) Biochemical oxygen demand (BOD n) 1.28 Üldkaredus (arvutuslik) Total hardness (calculated) 1.29 Naftasaadused (süsivesinikud C 10-C 40) Hydrocarbon oil index, oil products Materials or products tested / tested Põhja-, pinna-, mere-, heit- ja Ground, surface and sea, Joogi-, põhja- ja pinnavesi Heit- ja Effluent and waste ISO 6060 SFS 3036 SFS 5505 ISO Electrochemical determinations Joogi-, põhja-, pinna-, mere, heit- ja ISO 10523, sademed Drinking, ground, surface, sea and waste, precipitation Joogi-, põhja-, pinna-, mere, heit- ja, sademed Drinking, ground, surface sea,, precipitation Põhja-, pinna- ja merevesi Ground, surface and sea Heit- ja Effluent and waste Arvutuslik Calculated Joogi-, põhja-, pinna-, mere-, heit ja, sademed Drinking, ground, surface, sea and waste, precipitation Gaasikromatograafia Joogivesi, põhjavesi, merevesi, pinnavesi, heit- ja Drinking, ground, surface, sea, effluent and waste Pinna- ja põhjavesi 1 Surface and ground 1 jäätmed waste ISO STJV72 EVS-EN ISO EVS-EN ISO EVS-EN STJV3 lisa 1 Gas chromatography ISO STJU62A

4 Leht/Page 4/9 Materials or products tested / tested Gaasikromatograafia-massispektromeetria Gas Chromatography Massspectrometry 1.30 Kloororgaanilised pestitsiidid, Joogi-, põhja-, pinna-, mere-, heit- STJU63 fosfor-orgaanilised ja, sademed pestitsiidid, karbamaadid, Drinking, ground, surface, and uuread, püretroidid, sea,, polüklooritud bifenüülid precipitation (PCB), klorobenseenid, polüaromaatsed ühendid STJU63a (PAH) jäätmed Organochlorine pesticides, organophosphorous waste pesticides, carbamates, STJU67 ureas, pyretroids, polychlorinated biphenyls (PCB), chlorobenzenes and polyaromatic hydrocarbons (PAH) toodud lisas A annex A 1.31 Lenduvad orgaanilised ühendid (LOÜ) Volatile organic compounds toodud lisas B annex B 1.32 Polütsüklilised aromaatsed süsivesinikud (PAH) Polycyclic aromatic hydrocarbons (PAH) toodud lisas C annex C 1.33 Klorofenoolid Chlorofenols toodud lisas G annex G Drinking, ground, surface, sea, jäätmed waste Joogi-, põhja- pinna-, mere-, heit- ja Drinking, ground, surface, sea, jäätmed waste Drinking, ground, surface, sea, jäätmed waste ISO ISO ISO ISO EVS-EN EVS-EN ISO 14154

5 Leht/Page 5/ Ftalaadid Phthalates toodud lisas H annex H 1.35 Nikotiin Nicotine Materials or products tested / tested Drinking, ground, surface, sea, Pinnas, setted, reoveesetted Soil, sediments, sewage sludge E-sigarettide täitevedelik tubakatooted, nikotiini sisaldavad tooted E-cigarette liquid filling tobacco products, nicotine-containing products EVS-EN CEN/TS STJU95a STJU90 ISO 1.36 Naftasaaduste identifitseerimine ning oletatava reostaja kindlakstegemine Oil spill identification and determination of potential spiller tert-oktüülfenool 4-n-nonüülfenool 4-nonüülfenooli isomeeride summa 4-tert-octylphenol 4-n-nonylphenol sum of 4-nonylphenol isomers 1.38 Tinaorgaanika (katioonid) Organotin Tributüültina (TBT) Tributyltin Dibutüültina (DBT) Dibutyltin Monobutüültina (MBT) Monobutyltin Tetrabutüültina (TTBT) Tetrabutyltin Trifenüültina (TphT) Triphenyltin Monooktüültina (MOT) Monooctyltin Dioktüültina (DOT) Dioctyltin Tritsükloheksüültina (TcyT) Tricyclohexyltin Naftasaadused ja naftasaadustega reostunud objektid Oil products and objects contaminated with oil products sea, effluent, waste Pinnas, setted, reoveesetted Soil, sediments, sewage sludge sea, Pinnas, setted, jäätmed Soil, sediments, waste CEN/TR ISO CEN/TS STJU98a STJU89 STJU89a STJU89b

6 Leht/Page 6/ Pestitsiidid Pesticides toodud lisas F annex F Materials or products tested / tested Vedelikkromatograafia-massispektromeetria Liquid Chromatography Massspectrometry Joogi-, põhja- pinna- ja merevesi STJU92 Heitvesi, sademed Waste, precipitation Pinnas, setted Soil, sediments STJU92A STJU97 STJU97A 1.40 Diklofenak Diclofenac 1.41 Glüfosaat ja AMPA Glyphosate and AMPA 1.42 PFOS, Perfluorooktaansulfoonhape Perfluorooctanesulfonate PFNA, Perfluorononaanhape Perfluorononaoic acid PFOA, Perfluorooktaanhape Perfluorooctanoid acid PFUA, Perfluoroundekaanhape Perfluoroundecanoic acid PFBA, Perfluorobutaanhape Heptafluorobuytric acid PFDoA, Perfluorododekaanhape Perfluorododecanoic acid PFHxA, Perfluoro-nheksaanhape Perfluoro-n-hexanoic acid PFDA, Perfluorodekaanhape Perfluorodecanoic acid Joogi-, põhja- pinna- ja merevesi Heitvesi, sademed Waste, precipitation Pinnas, setted Soil, sediments Joogi-, põhja- pinna- ja merevesi Heitvesi, sademed Waste, precipitation Pinnas, setted Soil, sediments Joogi-, põhja- pinna- ja merevesi Heitvesi, sademed Waste, precipitation Pinnas, setted, kala ja muu veeelustik Soil, sediments, fish and aquatic organisms STJU92 STJU92A STJU97 STJU93 STJU93B STJU93A STJU93B STJU96

7 Leht/Page 7/9 Materials or products tested / tested Ioonkromatograafia Ion-exchange chromatography 1.43 Lahustunud kloriid-, nitraat-, Joogi-, põhja-, pinna- ja merevesi, sulfaat ja fluoriid Dissolved chloride, nitrate, sulphate and fluoride sademed (s.h võra- ja tüvevesi) Drinking, ground, surface, and sea, precipitation Lahustunud naatrium, ammoonium, kaalium, kaltsium ja magneesium Dissolved sodium, ammonium, potassium, calcium and magnesium Joogi-, põhja-, pinna-, ja merevesi, sademed (s.h võra- ja tüvevesi) Drinking, ground, surface, and sea, precipitation EVS-EN Aatomabsorptsioonspektromeetria leegimeetod Atomic absorption spectrometry atomization in flame 1.45 Mg (magneesium) Ca (kaltsium), sademed 7980 STJM/U83 Drinking, ground, surface, effluent and waste, precipitation, soil STJM/U83 Leek-emissioon spektromeetria Flame-emission spectrometry 1.46 Na (naatrium) K (kaaliumi), sademed Drinking, ground, surface, effluent and waste, precipitation, soil ISO STJM/U85 STJM/U85 AAS-külmauru meetod AAS cold vapour method 1.47 Hg (elavhõbe) Heit- ja, leostis Waste, eluate STJM/U84-1 Joogi-, põhja-, pinna- ja merevesi, sademed, mullavesi 17852, precipitation, soil STJM/U84-2 STJM/U84-2 Induktiivsidestusega plasma aatomemissioonspektromeetria Inductively coupled plasma atomic emission spectrometry (ICP-OES) ISO

8 Leht/Page 8/ Elemendid (metallid) Elements (metals) toodud lisas D annex D Materials or products tested / tested, sademed, mullavesi, leostis 2 Drinking, ground, surface, sea, effluent and waste, precipitation, soil, eluate EVS-EN STJM/U91 STJM/U91 Induktiivsidestusega plasma mass-spektromeetria Inductively coupled plasma mass spectrometry 1.49 Elemendid (metallid) Elements (metals) Joogi-, põhja-, pinna-, mere-, heitvesi, sademed, mullavesi toodud lisas E Drinking, ground, surface, sea and STJM/U94 waste, precipitation, soil Analysis parameters are listed in annex E STJM/U94 Soli, sediments, sewage sludge, ISO STJM/U94 Proovivõtt Sampling 1.50 Proovivõtt Keskkonnaproovid, jäätmed STJP7 Sampling Environmental samples, waste 1.51 Proovivõtt Sampling Pinnas Soil Vesi, reoveesetted, setted Water, sewage sludge, sediments ISO (1 5) ISO 5667-(1; 3 6, 9 13, 15, 19) 1.52 Proovivõtt Sampling Kalad Fish ISO Elektrokeemilised määramised mõõtmised proovivõtul Electrochemical determinations in-situ measurements 1.53 ph Vesi ISO ph Water 1.54 Elektrijuhtivus Vesi EVS-EN Electrical conductivity Water 1.55 Lahustunud hapnik Dissolved oxygen Vesi Water 5814 Füüsikalised katsed Physical tests 1.56 Vooluhulk (hetkeline) Vesi ISO 748 Flow rate (instant) Water 1.57 Vooluhulk (pidev) Flow rate (permanent) Vesi Water STJV74

9 Leht/Page 9/9 1 - määramispiir 2 liitri proovi ekstraheerimisel Limit of quantification for extraction of 2 L of sample 2 - Leostuskatse tehakse vastavalt standardile Leostiste korral vastab lahuse määramispiirile 1 mg/l vastava tahke materjali määramispiir 10 mg/kg KA. Leaching test according to the standard Limit of quantification value 1 mg/l for eluates corresponds to 10 mg/kg KA for solid. 3 - Tahkete proovide analüüsitulemuste ühik KA tähendab uuritava aine sisaldust kuivaines. Kuivaine määratakse metoodika EVS-EN alusel. The unit of test results for solid samples in the form of KA stands for concentration in the dry matter. Dry matter is determined according to EVS-EN Katsetamist teostav struktuuriüksus: Keskkonna- ja analüütilise keemia osakond Part of legal entity that provides testing: Environmental and Analytical Chemistry Department Tegevuskohtade aadressid: Marja 4d, Tallinn Addresses of locations: 3. Labor on akrediteeritud standardi /IEC 17025:2006 nõuete suhtes Laboratory is accredited against the requirements of standard /IEC 17025:2006 Märkus: käesolev lisa asendab välja antud lisa seoses akrediteerimisulatuse laiendamisega. te: this annex replaces annex issued on due to extension of the accreditation scope. Kristiina Saarniit EAK juhataja Director of EAK Maia Valm Peaassessor Lead Assessor Tallinn,

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