Assured Monitoring Group

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1 SOURCE EMISSIONS MONITORING RASP MINE, BROKEN HILL Assured Monitoring Group CBH RESOURCES LIMITED BROKEN HILL OPERATIONS PTY LTD Project ID R_0 DATE OF RELEASE: 25/09/2015 Unit 1, 22 Varley Street Yeerongpilly Queensland ABN:

2 Table 1: Document approval Name Position Title Signature Date Author Curtis Profke Senior Consultant Reviewer Glenn Ward Principal Scientist Approver Glenn Ward Principal Scientist Table 2: Revision register Revision Date Name Comment R_ Curtis Profke Initial release DISCLAIMER Assured Monitoring Group acts in all professional matters as a faithful advisor to the Client and exercises all reasonable skill and care in the provision of its professional services. Reports are commissioned by and prepared for the exclusive use of the Client. They are subject to and issued in accordance with the agreement between the Client and Assured Monitoring Group. Assured Monitoring Group is not responsible for any liability and accepts no responsibility whatsoever arising from the misapplication or misinterpretation by third parties of the contents of its reports. Except where expressly stated, Assured Monitoring Group does not attempt to verify the accuracy, validity or comprehensiveness of any information supplied to Assured Monitoring Group for its reports. Reports cannot be copied or reproduced in whole or part for any purpose without the prior written agreement of Assured Monitoring Group. Where site inspections, testing or fieldwork have taken place, the report is based on the information made available by the client or their nominees during the visit, visual observations and any subsequent discussions with regulatory authorities. The validity and comprehensiveness of supplied information has not been independently verified and, for the purposes of this report, it is assumed that the information provided to Assured Monitoring Group is both complete and accurate. It is further assumed that normal activities were being undertaken at the site on the day of the site visit(s), unless explicitly stated otherwise. ACCREDITED FOR COMPLIANCE TO ISO/IEC The results of the tests, calibrations and/or measurements included in this document are traceable to Australian/national standards. Accreditation ID: Project ID R_0 ii

3 EXECUTIVE SUMMARY Table 1 below shows the results summary for the emissions testing undertaken on the vent shaft and mill baghouse stacks at the Rasp Mine, Broken Hill. No licence exceedances were recorded on this occasion. Table 3: Summary of emissions Release Point Parameter Unit of Measure Vent Shaft Licence Limit Mill Baghouse Emission Point Source ID (NSW EPA) 1 2 Run ID 1 2 Licence Limit Date of testing dd-mm-yy Exhaust Velocity m/sec Average stack temperature C Moisture % Dry standard stack flow rate Nm 3 /min Carbon dioxide concentration % Oxygen concentration % Total solid particulates mg/nm TBD emission rate g/min Type 1 and Type 2 substances a mg/nm TBD emission rate g/min Oxides of nitrogen as (NO2) b mg/nm 3 < emission rate g/min < 24 Volatile organic compounds mg/nm 3 < emission rate g/min < 7.9 NOTES: Type 1 substances: Refers to the elements antimony, arsenic, cadmium, lead or mercury or any compound containing one or more of these elements. Type 2 substances: Refers to the elements of beryllium, chromium, cobalt, manganese, nickel, selenium, tin or vanadium or any compound containing one or more of these elements. Project ID R_0 iii

4 TABLE OF CONTENTS 1 INTRODUCTION METHODOLGY & EQUIPMENT SAMPLING METHODOLOGY SAMPLE LOCATION TEST EQUIPMENT QUALITY ASSURANCE & QUALITY CONTROL (QA/QC) DEFINITIONS RESULTS HISTORICAL RESULTS LIST OF TABLES TABLE 1: DOCUMENT APPROVAL... II TABLE 2: REVISION REGISTER... II TABLE 3: SUMMARY OF EMISSIONS... III TABLE 4: TEST METHODOLOGY... 2 TABLE 5: ANALYSIS NOTES... 2 TABLE 6: SAMPLE NOTES... 2 TABLE 7: SAMPLE LOCATION DETAILS VENT SHAFT... 4 TABLE 8: SAMPLE LOCATION DETAILS - MILL BAGHOUSE... 4 TABLE 9: TESTO 350XL COMBUSTION GAS ANALYSER SPECIFICATIONS... 5 TABLE 10: SAMPLING DATA QA/QC CHECKLIST... 7 TABLE 11: LABORATORY DATA QA/QC CHECKLIST... 7 TABLE 12: DEFINITIONS... 8 TABLE 13: RESULTS SUMMARY VENT SHAFT... 9 TABLE 14: RESULTS SUMMARY - VENT SHAFT, CONTINUED...10 TABLE 15: RESULTS SUMMARY - MILL BAGHOUSE...11 TABLE 16: RESULTS SUMMARY - MILL BAGHOUSE, CONTINUED TABLE 17: VENT SHAFT RESULTS 2014/ TABLE 18: MILL BAGHOUSE RESULTS 2014/ LIST OF FIGURES FIGURE 1: SAMPLE LOCATIONS... 3 FIGURE 2: FULL ISOKINETIC SAMPLING ASSEMBLY... 5 FIGURE 3: TESTO 350XL COMBUSTION GAS ANALYSER... 5 Project ID R_0 iv

5 1 INTRODUCTION Assured Monitoring Group (AMG) was commissioned by CBH Resources to monitor emissions from their vent shaft sample point and mill baghouse at the Rasp Mine facility, Broken Hill. Sampling was conducted by AMG on 2 nd September AMG was responsible for the collection and analysis of samples, unless otherwise indicated. The samples were recovered and stored in the appropriate manner until their return to the laboratory where the samples were prepared and analysed according to the appropriate methodology. This test program was conducted to: Monitor emissions from the Vent Shaft sample point Monitor emissions from the Mill bag house Project ID: R_0 1

6 2 METHODOLGY & EQUIPMENT 2.1 Sampling methodology Unless otherwise stated, the following test methods meet the requirements of NSW EPA. All sampling and analysis was conducted by AMG unless otherwise stated. The results presented in this report are related to one or more reference calibrations held by AMG. All sampling and analysis was carried in accordance to the listed requirements in Table 4. Any deviations to these methods have been documented where required. Table 4: Test methodology Emission Test Units of Measure NSW Method ID Sample notes Analytical Laboratory NATA accreditation Traverse point selection - TM-1 a 1 yes Temperature o C TM-2 Nil 1 yes Velocity m/s TM-2 Nil 1 yes Volumetric flowrate m 3 /s TM-2 Nil 1 yes Moisture content % TM-22 Nil 1 yes Carbon dioxide % TM-24 b 1 yes Oxygen % TM-25 b 1 yes Particulate Matter (PM) mg/m 3 TM-15 Nil 1 yes Carbon monoxide (CO) mg/m 3 TM-32 b 1 yes Nitrogen oxides (NOx) mg/m 3 TM-11 Nil 1 yes TVOC s (as propane) mg/m 3 TM-34 Nil 2 yes Type 1 & 2 hazardous substances (heavy metals) mg/m 3 TM-12, 13 & 14 c 2 yes Table 5: Analysis notes Analysis Note Company Accreditation ID Report Number 1 AMG Pty Ltd NATA: EnviroLab Services NATA: [R00] Table 6: Sample notes Note ID a b Comment The Mine vent shaft sampling location is not ideal for isokinetic sampling, the sample location can be considered best available as this sample location is a mine vent shaft, rather than a true stack release point. The sampling duration on the vent shaft is timed to coincide with a blast within the mine and is run for a period to time to cover the emission of any potential blast fume. Only NOx calibration gas taken to site to perform on-site calibration checks. For all other gases, analyser calibration checks were performed in laboratory conditions before and after sampling, not on-site. Project ID: R_0 2

7 2.2 Sample location Mill Baghouse release point Vent Shaft release point Figure 1: Sample locations Project ID: R_0 3

8 Table 7: Sample location details Vent Shaft Stack Parameter Dimensions (m) 5.0 Port size (inches) 4 Port Thread Type BSP Distance to upstream disturbance (m) 1 Distance to downstream disturbance (m) 1 Number of traverses 3 Number of points per traverse 8 Total number of traverse points 24 AS Compliance No only one port available. Table 8: Sample location details - Mill Baghouse Stack Parameter Dimensions (m) Port size (inches) 4 Port Thread Type BSP Distance to upstream disturbance (m) 5.5 Distance to downstream disturbance (m) 1.5 Number of traverses 2 Number of points per traverse 6 Total number of traverse points 12 AS Compliance Yes Project ID: R_0 4 File name: CBH Resources Sep 2015 R_0

9 2.3 Test equipment All equipment used during the course of the testing meets all relevant performance standards as required by relevant jurisdictions. The isokinetic equipment used for this project was from Apex Instruments. Figure 2: Full isokinetic sampling assembly Figure 3: Testo 350XL Combustion gas analyser Table 9: Testo 350XL Combustion gas analyser specifications Compound Range Lower Detection Limit Linearity O2 1 to 25% 0.1% +/- 0.8% of range CO 1 to 2,000ppm 1 ppm +/- 5% selected range CO2 0 to 50% 0.01% +/- 1% of range NO 1 to 3,000ppm 1 ppm +/- 5% selected range NO2 1 to 500ppm 0.5 ppm +/- 5% selected range Flow Rate ~ 0.8 liters per minute Accuracy 2% of span Span Drift Less than 2% per test Response Time 40 seconds Project ID: R_0 5 File name: CBH Resources Sep 2015 R_0

10 3 QUALITY ASSURANCE & QUALITY CONTROL (QA/QC) AMG operates within a quality system based upon the requirements of ISO Our quality system defines specific procedures and methodologies to ensure any project undertaken by AMG is conducted with the highest level of quality given the specific confines of each project The overall objective of our QA/QC procedures is to representatively sample and accurately analyse components in the gas streams and therefore report valid measurements of emission concentrations. To ensure representativeness of field work, our quality procedures target: 1. Correct sampling locations 2. Sample time 3. Frequency of samples and 4. Method selection & adherence To ensure representativeness of lab work, our quality procedures target: 1. Sample preservation 2. Chain of custody (COC) 3. Sample preparation and 4. Analytical techniques AMG maintains strict quality assurance throughout all its sampling programs, covering on-site field work and the analytical phase of our projects. Our QA program covers the calibration of all sampling and analytical apparatus where applicable and the use of spikes, replicate sample and reference standards. The test methodologies used for this project are outlined in section 2 of this document. Field test data has been recorded and calculated using direct entry into Microsoft Excel spreadsheets following the procedures of the appropriate test methods. Determination of emission concentrations has been performed using the same Microsoft Excel spreadsheets which are partially supplied as an attachment to this report. More detailed information can be supplied upon request. QA/QC checks for this project will use validation techniques and criteria appropriate to the type of data and the purpose of the measurement to approve the test report. Records of all data will be maintained. Complete chain of custody (COC) procedures has been followed to document the entire custodial history of each sample. The COC forms also served as a laboratory sheet detailing sample ID and analysis requirements. Project ID: R_0 6 File name: CBH Resources Sep 2015 R_0

11 Table 10: Sampling data QA/QC checklist Sampling Data QA/QC Checklist Use of appropriate test methods Normal operation of the process being tested Use of properly operating and calibrated test equipment Use of high purity reagents Performance of leak checks post sample (at least) Comment Yes Yes as instructed by client Yes Yes Yes Table 11: Laboratory data QA/QC checklist Laboratory Data QA/QC Checklist Use of appropriate analytical methods Use of properly operating and calibrated analytical equipment Precision and accuracy comparable to that achieved in similar projects Accurate reporting Comment Yes Yes Yes Yes Project ID: R_0 7 File name: CBH Resources Sep 2015 R_0

12 4 DEFINITIONS The following terms and abbreviations may be used in this report: Table 12: Definitions Symbol Definition < The analytes tested for was not detected; the value stated is the reportable limit of detection Am 3 AS BH o C CARB dscm FH f/ml g kg m m 3 mbar mg min ml mmh2o Mole N/A ng NATO NIOSH Nm 3 NMI NM VOC NR OSHA ou PCDD PCDF PM ppb ppm sec Sm 3 STP TO TWA USEPA Gas volume in cubic metres at measured conditions Australian Standard Back half of sample train (filter holder and impingers) (referred to during sample recovery) Degrees Celsius California Air Resources Board methods dry standard cubic meters Front half of sample train (probe and filter holder) (referred to during sample recovery) Fibres per millilitre Grams Kilograms Metres actual gas volume in cubic metres as measured Millibars Milligrams (10-3 grams) Minute Millilitres Millimetres of water SI unit that measures the amount of substance Not applicable Nanograms (10-9 grams) North Atlantic Treaty Organisation National institute for occupational safety and health (USA) Gas volume in dry cubic metres at standard temperature and pressure (0 C and kpa) National Measurement Institute Non methane volatile organic compound Not required on this occasion Occupational Safety and Health Act Odour unit Polychlorinated dibenzo-p-dioxin Polychlorinated dibenzofuran Particulate matter Parts per billion Parts per million Second Gas volume in dry cubic metres at standard temperature and pressure (0 C and kpa) and corrected to a standardised value (e.g. 15% O2) Standard temperature and pressure (0 C and kpa) USEPA air toxics method Time weighted average United States Environmental Protection Authority Project ID: R_0 8 File name: CBH Resources Sep 2015 R_0

13 5 RESULTS Table 13: Results summary Vent Shaft Historical Data & Hardware Information - Manual Sample Source Data Stack SDS version Client 0 CBH Resources Site 0 Rasp Mine Sample Point 0 Vent Shaft Reference Method 0 USEPA M29 - Metals - ISOKINETIC Test Parameters 0 PM & Metals Process conditions 0 Development blast Run Start Date dd-mm-yy 0 Wednesday, September 02, 2015 Project ID Run ID 0-1 Run Start Time Ti hh:mm 0 18:40:00 Run Stop Time Tf hh:mm 0 19:56:00 Positioning compliance check with AS Non-ideal Flow & temperature compliance check with AS YES Traverse pt factors; up, down, total & trav pts 0 1.2, 1.15, 1.38, 42 Console Serial Number 0 SN174 Meter Calibration Factor (Y) Orifice Coefficient (DH@) Pitot Tube Coefficient (Cp) Actual Nozzle Diameter (Dna) mm Stack Test Data Initial Meter Volume (Vm)i m Final Meter Volume (Vm)f m Actual Sampling Time (Q) minutes 0 72 Average Meter Temperature (tm)avg oc Average Stack Temperature (ts)avg oc Barometric Pressure (Pb) mb Stack Static Pressure (Pstatic) mm H2O Absolute Stack Pressure (Ps) mb Sample Volumes Actual Meter Volume (Vm) m Standard Meter Volume (Vm)std Nm Moisture Content Data Impingers 1-3 Water Volume Gain (Vn) ml Impinger 4 Silica Gel Weight Gain (Wn) g Total Water Volume Collected (Vlc) ml Water vapour concentration (Bws(calc)) % Stack Gas Density Analysis Data Carbon Dioxide Percentage (%CO2) % Oxygen Percentage (%O2) % Carbon Monoxide Percentage (%CO) % Nitrogen Percentage (%N2) % Dry Gas Molecular Weight (Md) kg/nm Dry Gas Molecular Weight (Md) g/g-mole Wet Stack Gas Molecular Weight (Ms) g/g-mole Volumetric Flow Rate Data (at Sample Plane) Average Stack Gas Velocity (vs) m/sec Stack Diameter Ds m Stack Cross-Sectional Area (As) m Upstream distance (from disturbance) B m Downstream distance (from disturbance) A m Actual Stack Flow Rate (Qaw) m3/min 0 12,828 Wet Standard Stack Flow Rate (Qsw) Nm3/min-wet 0 11,869 Dry Standard Stack Flow Rate (Qsd) Nm3/min-dry 0 11,588 Percent of Isokinetic Rate (I) % Project ID: R_0 9

14 Table 14: Results summary - Vent Shaft, continued Particulate Matter (PM) Concentration Total Mass of Particulates (mn) g Stack PM Concentration (cs) mg/nm Particulate Emission Rate (E) g/min Particulate Uncertainty Calculation Uncertainty expressed at 95%CI (U) % 0 Non ideal. Uncertainty expressed at 95%CI (U) mg/nm3 0 Cannot quote Instrumental Analyser - Historical Data & Hardware Information Analyser serial number, make & model value 0 SN437 Analyser Run Start Time Ti hh:mm 0 18:39:25 Analyser Run Stop Time Tf hh:mm 0 19:45:25 Analyser Total Sampling Time (Q) hh:min 0 1:06 Instrumental Analyser Raw Data Averages Average Oxides of Nitrogen (USEPA Method 7E - instrumental analyser) Average Carbon Monoxide (USEPA Method 10 - instrumental analyser) Oxides of Nitrogen (NOx) ppm < 1.00 Carbon Monoxide (CO) ppm 1.18 Nitrogen Oxides (NOx as NO2) (Conc) mg/nm3 < 2.05 Nitrogen Oxides (NOx as NO2) (E) g/min < 23.8 Carbon Monoxide (CO) (Conc) mg/nm Carbon Monoxide (CO) (E) g/min 17.1 Heavy Metals (USEPA Method 29) Antimony µg/nm3 < 4.90 Arsenic µg/nm3 < 4.90 Barium µg/nm Beryllium µg/nm3 < Cadmium µg/nm Chromium µg/nm3 < 2.94 Cobalt µg/nm3 < Copper µg/nm3 < 3.7 Lead µg/nm3 27 Manganese µg/nm3 0.9 Nickel µg/nm Phosphorus µg/nm3 < 184 Selenium µg/nm3 < 4.90 Silver µg/nm3 < 3.67 Thallium µg/nm3 < 18.4 Tin µg/nm3 < 12.2 Vanadium µg/nm3 < 6.12 Zinc µg/nm3 65 Mercury µg/nm3 < Total Heavy metals (excluding LOD values mg/nm OTHER ANALYTES TVOC (Conc) mg/nm3 < TVOC emission rate (E) g/min < 7.89 Project ID: R_0 10

15 Table 15: Results summary - Mill Baghouse Historical Data & Hardware Information - Manual Sample Source Data Stack SDS version Client 0 CBH Resources Site 0 Rasp Mine Sample Point 0 Mill Baghouse Reference Method 0 USEPA M29 - Metals - ISOKINETIC Test Parameters 0 PM & Metals Process conditions 0 See additional documents Run Start Date dd-mm-yy 0 Wednesday, September 02, 2015 Project ID Run ID 0-3 Run Start Time Ti hh:mm 0 14:00:00 Run Stop Time Tf hh:mm 0 15:27:00 Positioning compliance check with AS Ideal Flow & temperature compliance check with AS YES Traverse pt factors; up, down, total & trav pts 0 1, 1, 1, 12 Console Serial Number 0 SN174 Meter Calibration Factor (Y) Orifice Coefficient (DH@) Pitot Tube Coefficient (Cp) Actual Nozzle Diameter (Dna) mm Stack Test Data Initial Meter Volume (Vm)i m Final Meter Volume (Vm)f m Actual Sampling Time (Q) minutes 0 84 Average Meter Temperature (tm)avg oc Average Stack Temperature (ts)avg oc Barometric Pressure (Pb) mb Stack Static Pressure (Pstatic) mm H2O Absolute Stack Pressure (Ps) mb Sample Volumes Actual Meter Volume (Vm) m Standard Meter Volume (Vm)std Nm Moisture Content Data Impingers 1-3 Water Volume Gain (Vn) ml Impinger 4 Silica Gel Weight Gain (Wn) g Total Water Volume Collected (Vlc) ml Water vapour concentration (Bws(calc)) % Stack Gas Density Analysis Data Carbon Dioxide Percentage (%CO2) % Oxygen Percentage (%O2) % Carbon Monoxide Percentage (%CO) % Nitrogen Percentage (%N2) % Dry Gas Molecular Weight (Md) kg/nm Dry Gas Molecular Weight (Md) g/g-mole Wet Stack Gas Molecular Weight (Ms) g/g-mole Volumetric Flow Rate Data (at Sample Plane) Average Stack Gas Velocity (vs) m/sec Stack Diameter Ds m Stack Cross-Sectional Area (As) m Upstream distance (from disturbance) B m Downstream distance (from disturbance) A m Actual Stack Flow Rate (Qaw) m3/min Wet Standard Stack Flow Rate (Qsw) Nm3/min-wet Dry Standard Stack Flow Rate (Qsd) Nm3/min-dry Percent of Isokinetic Rate (I) % Project ID: R_0 11

16 Table 16: Results Summary - Mill baghouse, continued Particulate Matter (PM) Concentration Total Mass of Particulates (mn) g Stack PM Concentration (cs) mg/nm Particulate Emission Rate (E) g/min Particulate Uncertainty Calculation Uncertainty expressed at 95%CI (U) % Uncertainty expressed at 95%CI (U) mg/nm Instrumental Analyser - Historical Data & Hardware Information Analyser serial number, make & model value Analyser Run Start Time Ti hh:mm Analyser Run Stop Time Tf hh:mm Analyser Total Sampling Time (Q) hh:min Instrumental Analyser Raw Data Averages Average Oxides of Nitrogen (USEPA Method 7E - instrumental analyser) Oxides of Nitrogen (NOx) ppm Carbon Monoxide (CO) ppm Nitrogen Oxides (NOx as NO2) (Conc) mg/nm3 Nitrogen Oxides (NOx as NO2) (E) g/min Average Carbon Monoxide (USEPA Method 10 - instrumental analyser) Carbon Monoxide (CO) (Conc) mg/nm3 Carbon Monoxide (CO) (E) g/min Heavy Metals (USEPA Method 29) Antimony µg/nm3 < 4.21 Arsenic µg/nm3 < 4.21 Barium µg/nm3 < 4.34 Beryllium µg/nm3 < Cadmium µg/nm Chromium µg/nm3 < 2.51 Cobalt µg/nm3 < Copper µg/nm3 < 4.34 Lead µg/nm Manganese µg/nm Nickel µg/nm3 < 0.47 Phosphorus µg/nm3 < 158 Selenium µg/nm3 < 4.21 Silver µg/nm3 < 3.15 Thallium µg/nm3 < 15.8 Tin µg/nm3 < Vanadium µg/nm3 < 5.26 Zinc µg/nm Mercury µg/nm3 < Total Heavy metals (excluding LOD values mg/nm OTHER ANALYTES TVOC (Conc) mg/nm3 TVOC emission rate (E) g/min Project ID: R_0 12

17 6 HISTORICAL RESULTS Table 17: Vent Shaft results 2014/2015 Release Point Parameter Unit of Measure Licence Limit Emission Point Source ID (NSW EPA) 1 Vent Shaft Release Point Round Date of testing dd-mm-yy Exhaust Velocity m/sec Average stack temperature C Moisture % Dry standard stack flow rate Nm 3 /min Carbon dioxide concentration % Oxygen concentration % Total solid particulates mg/nm emission rate g/min Type 1 and Type 2 substances a mg/nm emission rate g/min Oxides of nitrogen as (NO2) b mg/nm < emission rate g/min < 24 Volatile organic compounds mg/nm 3 < 1.28 < 0.72 < 0.67 < emission rate g/min < 14.9 < 8.5 < 8.0 < 7.9 The results from sampling conducted on the vent shaft release point during this round is consistent with historical data and can be considered in the average range. All parameters were recorded well below the licence limit. Project ID: R_0 13

18 Table 18: Mill Baghouse results 2014/2015 Release Point Parameter Unit of Measure Licence Limit Emission Point Source ID (NSW EPA) 2 Mill Baghouse Release Point Round Date of testing dd-mm-yy Exhaust Velocity m/sec Average stack temperature C Moisture % Dry standard stack flow rate Nm 3 /min Carbon dioxide concentration % Oxygen concentration % Total solid particulates mg/nm TBD emission rate g/min Type 1 and Type 2 substances a mg/nm TBD emission rate g/min The sampling conducted on the mill baghouse release point from this round shows reasonably consistent results for all measured parameters. There is currently no permit limit specified from this release point, however when results are compared with the mine vent shaft limit (1mg/Nm3) all results are less than half of this value. Project ID: R_0 14

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