Silver Braze 35, 60Sn10, 56, 45T, 38, 40, 45, 65, 30, 25Sn2, 50, 54, 70, 92.5, 72a, 72, 85, Pure Silver (Solids) Safety Data Sheet

Transcription

1 Silver Braze 35, 60Sn10, 56, 45T, 38, 40, 45, 65, 30, 25Sn2, 50, 54, 70, 92.5, 72a, 72, 85, Pure Silver (Solids) Date of issue:11/30/2015 Revision date: : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Silver Braze 35, 60Sn10, 56, 45T, 38, 40, 45, 65, 30, 25Sn2, 50, 54, 70, 92.5, 72a, 72, 85, Pure Silver (Solids) Type of product : Alloy 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture Function or use category : Professional use : For professional use only : Brazing : Welding, cutting, heating and brazing Uses advised against 1.3. Details of the supplier of the safety data sheet The Prince & Izant Companies Plaza Drive Cleveland, Ohio - USA T F support@princeizant.com Emergency telephone number Emergency number : (CHEMTREC) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Child-resistant fastening Tactile warning 2.3. Other hazards Adverse physicochemical, human health and environmental effects Other hazards not contributing to the classification : To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. ne under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 12/14/2015 EN (English) 1/6

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Silver substance with a Community workplace exposure limit Full text of H-statements: see section 16 (CAS No) (EC no) >= 20 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. Get medical advice/attention. : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. t expected to present a significant ingestion hazard under anticipated conditions of normal use. If large quantities are ingested, seek medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause respiratory irritation. : Repeated or prolonged contact may cause slight irritation to the skin. : Dust from this product may cause eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity in case of fire Hazardous decomposition products in case of fire t expected to present a significant ingestion hazard under anticipated conditions of normal use. : Dry powder. Use extinguishing media appropriate for surrounding fire. : The product is not flammable. : Product is not explosive. t known. : Toxic fumes may be released Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting special measures required. : Use extinguishing media appropriate for surrounding fire. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Avoid release to the environment For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Wear suitable protective clothing, gloves and eye or face protection. : Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe dust, fume. : Do not attempt to take action without suitable protective equipment. Wear suitable protective clothing, gloves and eye or face protection. For further information refer to section 8: "Exposure controls/personal protection". Avoid contact with skin and eyes. Do not breathe Dust, Fumes. : Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Collect spillage. 12/14/2015 EN (English) 2/6

3 Methods for cleaning up Other information : Place in a suitable container for disposal in accordance with the waste regulations (see Section 13). : Dispose of in accordance with relevant local regulations Reference to other sections For further information refer to section 8: "Exposure controls/personal protection". For disposal of solid materials or residues refer to section 13 : "Disposal considerations". SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Always wash hands after handling the product. Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible materials Storage area Packaging materials 7.3. Specific end use(s) Other hot work operations with metals. : Ensure adequate ventilation, especially in confined areas. : Store in a well-ventilated place. Keep cool. : Acetylene, ammonia, ammonium nitrate, aqua regia, dioxane, ethylene oxide, chlorine trifluoride, halogens, hydrogen peroxide, hydrazine, hydrazine, mononitrate, hydrazoic acid, hydroxylamine, hydrogen sulfide, performic acid, phosphorus, selenium, sulfur, titanium plus potassium chlorate. Bromates, chlorates and iodates of alkali and alkali earth metals. : Store in a well-ventilated place. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Silver ( ) EU Local name Silver, metallic EU IOELV TWA (mg/m³) 0.1 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Ensure good ventilation of the work station. : Gloves. Protective goggles. Face shield. Protective clothing. : Wear suitable protective clothing : Protective gloves : Wear tight fitting safety glasses or face shield : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Silver-gray alloy. Metallic wire, rod, strip. Colour : Silver. Odour : odourless. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point 12/14/2015 EN (English) 3/6

4 Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits n flammable : insoluble in water. : Product is not explosive. : Oxidising solids Not applicable Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Acetylene, ammonia, ammonium nitrate, aqua regia, dioxane, ethylene oxide, chlorine trifluoride, halogens, hydrogen peroxide, hydrazine, hydrazine, mononitrate, hydrazoic acid, hydroxylamine, hydrogen sulfide, performic acid, phosphorus, selenium, sulfur, titanium plus potassium chlorate. Bromates, chlorates and iodates of alkali and alkali earth metals Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Contact dermatitis may result from direct exposure to the skin. Long-term exposure to brazing fume, gasses, or dust may contribute to pulmonary irritation or pneumoconiosis. 12/14/2015 EN (English) 4/6

5 SECTION 12: Ecological information Toxicity Ecology - general Ecology - water : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. : The product does not have any known adverse effect on the tested aquatic organisms Persistence and degradability Silver Braze 35, 60Sn10, 56, 45T, 38, 40, 45, 65, 30, 25Sn2, 50, 54, 70, Persistence and degradability The product is not biodegradable Bioaccumulative potential Silver Braze 35, 60Sn10, 56, 45T, 38, 40, 45, 65, 30, 25Sn2, 50, 54, 70, Bioaccumulative potential Not established Mobility in soil Silver Braze 35, 60Sn10, 56, 45T, 38, 40, 45, 65, 30, 25Sn2, 50, 54, 70, Ecology - soil Not established Results of PBT and vpvb assessment Other adverse effects Other adverse effects Additional information ne known. : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) 12/14/2015 EN (English) 5/6

6 Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/14/2015 EN (English) 6/6