Innovative. and Sustainable. Coating Solutions. 3M Dyneon PTFE Dispersions 3M Dyneon PFA, FEP and THV Fluoroplastic Dispersions 3M Dyneon PFA Powder

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1 3M Dyneon PTFE Dispersions 3M Dyneon PFA, FEP and THV Fluoroplastic Dispersions 3M Dyneon PFA Powder Innovative and Sustainable Coating Solutions a 3M company

2 When the going gets tough The right raw materials for highest demands and you need a high performance material with low friction, high durability, excellent thermal properties and chemical inertness, Dyneon is your perfect partner. For more than 10 years Dyneon, as a technology leader, sets a benchmark for the development, sustainable processing and servicing of high performance fluoropolymers. As a 3M company, Dyneon is a global player and supplier for major industries like automotive, chemical processing, consumer products, construction, electrical/electronic engineering, and semiconductor manufacturing. The unique properties of PTFE (polytetrafluoroethylene) have made it an indispensable material for modern industry. PTFE offers exceptional characteristics like a nearly universal chemical resistance, a very wide service temperature range from -200 C to +260 C (-328 F to +500 F) combined with a high flame resistance and excellent dielectric properties. Even more, PTFE Dispersions show no embrittlement or aging and due to their ultra-smooth surfaces they reduce the total cost of ownership of equipment. With continuous research and development, Dyneon improves in an ongoing process the properties of its PTFE Dispersions, PFA, FEP and THV Fluoroplastic (FP) Dispersions and PFA Powders. As an innovation leader for the process technology used in manufacturing fluoropolymers, Dyneon reaffirms its commitment to the customers and the environment. The Dyneon Vision To be the most innovative and differentiated provider of fluoropolymers, additives and related products to customers seeking custom solutions for applications requiring multi-faceted performance in harsh chemical and thermal environments. 2

3 Leading the way with sustainable production The environmental, economic, and social dimensions of sustainability have inspired Dyneon researchers to produce fluoropolymers without the use of PFOA. They succeeded in developing a new emulsifier for fluoropolymer production. This emulsifier exhibits a significantly improved Environmental, Health and Safety profile, whilst maintaining the properties of well established fluoropolymer products to their full extent. Dyneon was therefore able to comply with the U.S. Environmental Protection Agency s Voluntary PFOA Stewardship Program s goals seven years ahead of time. We believe creating and maintaining sustainable technology in chemical manufacturing processes to be a cornerstone for sustaining today s society. Dyneon supports this basic approach with the most advanced process technology. Our containment technology removes and recovers the new emulsifier from process off-gas and waste water, minimizes the release into the environment, and recycles the emulsifier into the manufacturing process. Our Product Stewardship Strategy Dyneon replaced PFOA in the manufacture of its entire product portfolio with the new emulsifier at the end of 2008, seven years earlier than required Dyneon has a sophisticated system in place for the recapture and re-use of the new emulsifier in our processes Dyneon operates an advanced system to minimize the release of the new emulsifier into the environment Dyneon has made its emulsifier containment technology available to others through license Building Blocks (Monomers) Products (Fluoropolymers) Polymerisation aid Recovery & Recycling of new emulsifier from off gas and waste water State-of-the-art technology 3

4 PTFE and FP Dispersions with improved properties for innovative metal coating solutions: PTFE Dispersion TF 5050Z Our best product for formulation systems. Unique property is the bimodal particle size distribution for additional improved high corrosion resistance substrate bonding and glossier surfaces of coated articles with food contact. Higher packing density with bimodal particle-size distribution. The variable sized particles form a more tightly packed particle arrangement and thus produce a denser coating film. Bimodal particle-size distribution Using Fluoropolymer Dispersions in the formulation of coating systems with bimodal particle size distribution will enable: improved film formation far fewer pores better gloss better adhesion higher resistance To achieve an optimum performance, we recommend a size ratio (small to larger particles) of 0,3-0,6 in your coating system. PTFE Dispersion TF 5070GZ The small particle size of TF 5070GZ permits the formulation of coating systems with bimodal particle size distribution. This, combined with the low molecular weight of the polymer, can improve packing density in the coating, reduce the initial sintering temperature and result in superior oil and scratch resistance. It can also enhance the slide performance and result in glossier surfaces for coated articles with food contact. Fluoroplastic PFA 6910GZ The nano particle size of PFA 6910GZ makes it a unique product which allows for formulating coating systems with bimodal particle size distribution. Bimodal distribution of particle sizes improves the packing density, which closes the finest pores of the substrate or coating. 4

5 PTFE Dispersion TF 5035Z Benchmark for non-stick coating systems. Unique property of this formulation grade is the extremely high stability in metal coating systems vs. shear and solvents, combined with excellent good coating results in terms of resistance, film build and non-stick properties. Fluoroplastic FEP 6300GZ The main unique property of FEP 6300GZ is to increase coating performance in metal coating systems. Recommended basically for cook- and bakeware applications, used at lower temperatures. Monomodal particle-size distribution 3M TM Dyneon Fluoroplastic PFA 6900GZ Our most important additive for non-stick coating formulations. Using PFA 6900GZ can improve corrosion resistance, substrate bonding, gloss and non-stick properties. Recommended for any non-stick coating application. Fluoroplastic PFA 6503AEPCZ PFA 6503AEPCZ is a fluoroplastic powder for electrostatic powder coating applications and is designed for thin film applications. 5

6 PTFE and FP Dispersions with improved properties for cloth coating in industry and architecture: PTFE Dispersion TF 5060GZ The unique characteristic of TF 5060GZ is its wetting performance and inherent film formation thickness. Because of its excellent re-wetting properties, we recommend the use as a top coat dispersion. PTFE Dispersion TF 5041Z TF 5041Z is recommended for use as an intermediate coat for coating on heavy weight glass cloth fabrics used e.g. in architectural applications. Because of the incorporated filler system and the increased viscosity, pick up during the coating process is dramatically improved. Fluoroplastic PFA 6900GZ PFA 6900GZ is ideal for sealing fabric surfaces and, used as a top coat, enables weldability of fabrics in cloth coating applications. Fluoroplastic FEP 6300GZ Much like PFA 6900GZ, FEP 6300GZ is a dispersion ideally used for sealing fabric surfaces in cloth coating applications. When used as a top coat it enables weldability of the fabric. Fluoroplastic THV 340Z The distinctive feature of THV 340Z is its very low melting point compared to other fluoropolymers. This is an advantage in the coating of PTFE fabrics and woven or non woven materials with a lower melting point, e.g. Polyester. PTFE and FP Dispersions with improved properties for impregnation purposes: PTFE Dispersion TF 5032Z The 30 % smaller particles of TF 5032Z, compared to other PTFE dispersions, allow for improved penetration into textile structures like felts, yarns and fabrics. Best applied in impregnation and protection of substrates and controlling air passage in filter systems. PTFE Dispersion TF 5060GZ The main advantage of TF 5060GZ is its wetting performance and inherent film formation thickness. PTFE Dispersion TF 5033Z As a specialty PTFE dispersion TF 5033Z makes it comparatively easy to initiate and control the coagulation step in aqueous compounding processes of fluoropolymers for the machining and automotive industry, e.g. in self lubrification and slide bearing applications. 6

7 Property (average values) Method Unit PFA 6900GZ 1) PFA 6910GZ 1) FEP 6300GZ 1) THV 340Z 1) Solid content DIN EN ISO % Emulsifier non-ionic non-ionic non-ionic ionic Emulsifier content Dyneon internal % 7, Viscosity DIN EN ISO 3219 mpas ph value DIN ISO 976 > 9 > 9 > 9 > 9 Density DIN g/cm 3 1,4 1,4 1,4 1,4 Particle size DIN ISO nm Property (average values) Test method Unit TF 5032Z TF 5035Z TF 5050Z TF 5033Z 1) Solid content DIN EN ISO % Emulsifier non-ionic non-ionic non-ionic ionic Emulsifier content DIN EN ISO % 6, Viscosity DIN EN ISO 3219 mpas n.a. ph value DIN ISO 976 > 9 > 9 > 9 > 9 Density DIN g/cm 3 1,5 1,5 1,5 1,1 Particle size DIN ISO nm Property (average values) Test method Unit TF 5041Z TF 5060GZ 1) TF 5070GZ 1) Solid content DIN EN ISO % Emulsifier non-ionic non-ionic non-ionic Emulsifier content DIN EN ISO % 8 8 2) 8 2) Viscosity DIN EN ISO 3219 mpas ph value DIN ISO 976 > 9 > 9 > 9 Density DIN g/cm 3 / 1,5 1,4 Particle size DIN ISO nm / Property Test method Unit PFA 6503AEPCZ Melting point ASTM D 4591 C ( F) 308 (586) MFI (372 C/5kg) ASTM D 1238 g/10min 3 Bulk density DIN g/l 800 Particle size µ 30 1) Grades made without the use of APEO (Alkyl Phenyl Ethoxylates) 2) measured with internal method 7

8 a 3M company Our Worldwide Commitment To Quality Indicative of our commitment, most Dyneon design, development, production and service facilities have achieved global quality management certification. Production facilities have also received certification for their environmental management system. Please see the Dyneon website ( for the most up-to-date certification details. Important Notice: All information set forth herein is based on our present state of knowledge and is intended to provide general notes regarding products and their uses. It should not therefore be construed as a guarantee of specific properties of the products described or their suitability for a particular application. Because conditions of product use are outside Dyneon s control and vary widely, user must evaluate and determine whether a Dyneon product will be suitable for user s intended application before using it. The quality of our products is warranted under our General Terms and Conditions of Sale as now are or hereafter may be in force. Technical information, test data, and advice provided by Dyneon personnel are based on information and tests we believe are reliable and are intended for persons with knowledge and technical skills sufficient to analyze test types and conditions, and to handle and use raw polymers and related compounding ingredients. No license under any Dyneon or third party intellectual rights is granted or implied by virtue of this information. General recommendations on health and safety in processing, on work hygiene and on measures to be taken in the event of accident are detailed in our material safety data sheets. You will find further notes on the safe handling of fluoropolymers in the brochure Guide for the safe handling of Fluoropolymers Resins by PlasticsEurope, Box 3, B-1160 Brussels, Tel. +32 (2) The present edition replaces all previous versions. Please make sure and inquire if in doubt whether you have the latest edition. The Product Portfolio: PTFE, TFM PTFE, PTFE Compounds, TFM PTFE Compounds PFA, ETFE, FEP, THV, HTE, PVDF Fluoroplastics Fluoroelastomers Low Temperature Fluoroelastomers Perfluoroelastomers Dyneon is a 3M company. Dyneon 2011 All rights reserved Dyneon, TFM and Dynamar are trademarks of 3M Company. Printed in Germany Issue: January Polymer Additives Melt Modifier 3M TM Dynamar TM Polymer Additives 3M TM Dynamar TM Rubber Additives Monomers Dyneon Customer Service Europe Phone: Fax: Italy Phone: Fax: USA Phone: Fax: Industrieparkstraße 1 D Burgkirchen Germany Phone: Fax: Carl-Schurz-Straße 1 D Neuss Germany Phone: 1) Fax: Dyneon B.V. Werk Kerkrade Tunnelweg 95 NL-6468 EJ Kerkrade The Netherlands Phone: Fax: Succursale France Boulevard de l Oise, Tour 3M F Cergy Pontoise Cedex France Phone: Fax: Sede Secondaria Italia Via Norberto Bobbio, 21 Strada Rivoltana Km 4 I Pioltello (MI) Italy Phone: Fax: UK Branch Office 3M Centre Cain Road Bracknell Berkshire RG12 8HT United Kingdom Phone: M Company* rd Street North Oakdale, MN USA Phone: Fax: Sumitomo 3M Limited* 33-1 Tamagawadai 2-Chome Setagaya-ku, Tokyo 158 Japan Phone: Fax: M China Limited* 10/F, New Town Mansion 55 Lou Shan Guan Road Shanghai P.R.C. Phone: Fax: *a licensed processor and distributor of Dyneon Products