Safety Data Sheet. according to Regulation (EC) No 1907/2006. SYMPROfluid universal

Transcription

1 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Special denture cleaner for use in a denture cleaning appliance with needles. Details of the supplier of the safety data sheet Company name: Street: Place: Untere Giesswiesen 2 D Hilzingen Telephone: Telefax: info@renfert.com Contact person: Frau Andris Telephone: Internet: Emergency telephone: Vergiftungs-Zentrale Freiburg SECTION 2: Hazards identification Classification of the substance or mixture Label elements Indications of danger : Irritant R-phrases: Irritating to eyes, respiratory system and skin. Danger symbols: Xi - Irritant Xi - Irritant R phrases 36/37/38 Irritating to eyes, respiratory system and skin. S phrases 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 24/25 Avoid contact with skin and eyes. SECTION 3: Composition/information on ingredients Mixtures Chemical characterization Acid cleaning agent

2 Page 2 of 7 Hazardous components EC No Index No REACH No X Classification GHS classification methanesulphonic acid C R34 Skin Corr. 1B; H314 hydrochloric acid... % C, Xi R34-37 Skin Corr. 1B, STOT SE 3; H314 H335 Fettalkohol, ethoxyliert Xi R38 Quantity < 5 % < 10 % < 5 % (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether Xi R Eye Irrit. 2; H319 Full text of R- and H-phrases: see section 16. < 5 % SECTION 4: First aid measures Description of first aid measures General information Take off immediately all contaminated clothing. After inhalation Provide fresh air. After contact with skin After contact with skin, wash immediately with plenty of water and soap. In case of skin irritation, seek medical treatment. After contact with eyes In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. After ingestion Rinse mouth immediately and drink large quantities of water. Do not induce vomiting. Immediately get medical attention. Most important symptoms and effects, both acute and delayed No symptoms known up to now. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media The product itself is not combustible. Extinguishing materials should be selected according to the surrounding area. Special hazards arising from the substance or mixture Can be released in case of fire: Hydrogen chloride (HCl). Sulfur oxides.

3 Page 3 of 7 Advice for firefighters In case of fire: Wear self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Provide adequate ventilation. Environmental precautions Do not empty into drains or the aquatic environment. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed containers for disposal. SECTION 7: Handling and storage Precautions for safe handling Advice on safe handling Handle and open container with care. Wear personal protection equipment. Avoid contact with skin and eyes. Advice on protection against fire and explosion No special fire protection measures are necessary. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep only in the original container in a cool, well-ventilated place. Keep container tightly closed. Advice on storage compatibility Do not store together with: Alkalis (alkalis). Further information on storage conditions Keep away from food, drink and animal feedingstuffs. SECTION 8: Exposure controls/personal protection Control parameters Exposure limits (EH40) ml/m³ mg/m³ F/ml Category Origin (2-Butoxyethoxy)ethanol TWA (8 h) WEL Exposure controls Occupational exposure controls refer to chapter 7. No further action is necessary. Protective and hygiene measures Take off immediately all contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with skin and eyes. Respiratory protection Provide adequate ventilation STEL (15 min) WEL

4 Page 4 of 7 Respiratory protection required in case of: aerosol or mist generation. Hand protection Tested protective gloves are to be worn: CR (polychloroprenes, Chloroprene rubber). Butyl rubber. FKM (fluororubber). In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. Eye protection Tightly sealed safety glasses. Environmental exposure controls Do not empty into drains or the aquatic environment. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state: Colour: Odour: liquid colourless fruity ph-value (at 20 C): < 1 Test method Changes in the physical state Boiling point: Flash point: Explosive properties not explosive. Density (at 20 C): Water solubility: Viscosity / dynamic: 100 C not applicable 1,02-1,06 g/cm³ complete miscible product has not been tested. SECTION 10: Stability and reactivity Reactivity Chemical stability No special measures are necessary. No special measures are necessary. Possibility of hazardous reactions Reacts with : Alkalis (alkalis). Corrosive to metals. Conditions to avoid Thermal decomposition can lead to the escape of irritating gases and vapours. Incompatible materials Reactions with metals, with evolution of hydrogen. Hazardous decomposition products No hazardous decomposition products known. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity There are no data available on the preparation/mixture itself.

5 Page 5 of 7 Exposure routes Method Dose Species Source methanesulphonic acid oral LD mg/kg Ratte dermal LD mg/kg (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether oral LD mg/kg Kaninchen Rat dermal LD mg/kg Rabbit Irritation and corrosivity Irritant effect on the skin: irritant. Irritant effect on the eye: irritant. Sensitising effects no danger of sensitization. Empirical data on effects on humans Irritating to eyes, respiratory system and skin. Further information product has not been tested. The statement is derived form the properties of the components. SECTION 12: Ecological information Toxicity There are no data available on the preparation/mixture itself. Aquatic toxicity Method Dose h Species Source hydrochloric acid... % Acute fish toxicity LC mg/l 96 Leuciscus idus 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether Acute algae toxicity ErC50 > 100 mg/l Scenedesmus sp. Acute crustacea toxicity EC50 > 100 mg/l 48 Daphnia magna Persistence and degradability The surfactants contained in the product are biodegradable according to the requirements of the Detergent Directive 648/2004/EC. Bioaccumulative potential Partition coefficient n-octanol/water Log Pow (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether 0,56 (25 C) Mobility in soil No information available. Results of PBT and vpvb assessment The components in this formulation do not meet the criteria for classification as PBT or vpvb. Other adverse effects Product is acid. The product needs to apply neutralizing agents before draining to wastewater treatment plants.

6 Page 6 of 7 Further information 1 Do not empty into drains or the aquatic environment. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Remove according to the regulations. Product is acid. The product needs to apply neutralizing agents before draining to wastewater treatment plants. Waste disposal number of waste from residues/unused products MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately collected fractions (except 15 01); detergents containing dangerous substances Classified as hazardous waste. Contaminated packaging Handle contaminated packaging in the same way as the substance itself. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine transport UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine pollutant: Air transport UN/ID number: UN proper shipping name: Transport hazard class(es): Packing group: 3264 ÄTZENDER SAURER ANORGANISCHER FLÜSSIGER STOFF, N.A.G. (Salzsäure und Methansulfonsäure Mischung) 8 III 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Alkylsulphonic acid and hydrochloric acid mixture) 8 III no 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Alkylsulphonic acid and hydrochloric acid mixture) 8 III SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information Additional information Labelling for contents according to regulation (EC) No 648/2004, annex 7: < 5% non-ionic surfactants, perfumes National regulatory information

7 Page 7 of 7 Water contaminating class (D): 1 - slightly water contaminating Additional information M 004 Reizende Stoffe / Ätzende Stoffe (BGI 595) SECTION 16: Other information Full text of R-phrases referred to under sections 2 and 3 34 Causes burns. 36 Irritating to eyes. 36/37/38 Irritating to eyes, respiratory system and skin. 37 Irritating to respiratory system. 38 Irritating to skin. Full text of H-Statements referred to under sections 2 and 3 H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. Reserved for industrial and professional use. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)