SAFETY DATA SHEET PROOFEX WG BASE

Transcription

1 Revision Date 31 July 2014 Revision 4 SAFETY DATA SHEET PROOFEX WG BASE SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. PROOFEX WG BASE A UK Relevant identified uses of the substance or mixture and uses advised against Identified uses Base Component of Three Part Epoxy Flooring System 1.3. Details of the supplier of the safety data sheet Supplier FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3XN Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com 1.4. Emergency telephone number +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health Xi;R36/38. R43. N;R51/53. The product is irritating to eyes and skin. May cause sensitisation by skin contact. Environment The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Contains Labelling BISPHENOL A & F BLEND 2-ETHYL HEXYL GLYCIDYL ETHER Risk Phrases Safety Phrases Irritant Dangerous for the environment R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24/25 Avoid contact with skin and eyes. 1 / 8

2 S26 S37 S57 S60 S61 P5 PROOFEX WG BASE In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Contains epoxy constituents. See information supplied by the manufacturer Other hazards This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures BISPHENOL A & F BLEND % CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xi;R36/38. N;R51/53. R43. 2-ETHYL HEXYL GLYCIDYL ETHER 5-10% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Classification (67/548/EEC) Xi;R36/38. R43,R52/53. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Get medical attention if any discomfort continues. Inhalation Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion Remove victim immediately from source of exposure. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed 2 / 8

3 PROOFEX WG BASE General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation May cause irritation to the respiratory system. Ingestion May cause discomfort if swallowed. Skin contact Skin irritation. Eye contact Irritation of eyes and mucous membranes Indication of any immediate medical attention and special treatment needed No information available. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products Carbon monoxide (CO). Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Avoid discharge into drains, water courses or onto the ground. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. Ventilate well Reference to other sections For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Avoid forming spray/aerosol mists Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. 3 / 8

4 Storage Class Chemical storage. PROOFEX WG BASE 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Engineering measures Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours. Respiratory equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. It is recommended to use respiratory equipment with combination filter, type A2/Р2. Hand protection Use suitable protective gloves if risk of skin contact. Use protective gloves made of: Butyl rubber. Nitrile. Eye protection If risk of splashing, wear safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. DO NOT SMOKE IN WORK AREA! Skin protection Wear apron or protective clothing in case of contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Colour Straw. Odour Mild. Solubility Insoluble in water Initial boiling point and boiling > 200 range ( C) Relative density 1.14 Vapour pressure kpa 20 Flash point ( C) > Other information Not determined. SECTION 10: STABILITY AND REACTIVITY Reactivity 4 / 8

5 No specific reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Not relevant Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid Amines. Acids Strong alkalis Hazardous decomposition products When heated, vapours/gases hazardous to health may be formed. SECTION 11: TOXICOLOGICAL INFORMATION PROOFEX WG BASE Information on toxicological effects Inhalation Gas or vapour may irritate respiratory system. Ingestion May cause discomfort if swallowed. Skin contact Irritating to skin. May cause sensitisation by skin contact. Eye contact Irritating to eyes. Route of entry Skin and/or eye contact. Toxicological information on ingredients. BISPHENOL A & F BLEND (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > mg/kg Rat Respiratory or skin sensitisation: Sensitising. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Dangerous for the environment: May cause long-term adverse effects in the aquatic environment Toxicity Acute Fish Toxicity Toxic to aquatic organisms. 5 / 8

6 Ecological information on ingredients. PROOFEX WG BASE BISPHENOL A & F BLEND (CAS: ) Acute Toxicity - Fish LC50 96 hours 3.6 mg/l Leuciscus idus (Golden orfe) EC 50, 48 Hrs, Daphnia, mg/l 2.8 Acute Toxicity - Aquatic Plants EC50 96 hours 220 mg/l Persistence and degradability Degradability The product is not expected to be biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: Not relevant, due to the form of the product Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 3082 UN No. (IMDG) 3082 UN No. (ICAO) UN proper shipping name Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN) Transport hazard class(es) ADR/RID/ADN Class 9 ADR/RID/ADN Class Class 9: Miscellaneous dangerous substances and articles. ADR Label No. 9 IMDG Class 9 ICAO Class/Division 9 Transport Labels 6 / 8

7 PROOFEX WG BASE MISCELLANEOUS DANGEROUS GOODS Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group III III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant Special precautions for user EMS Emergency Action Code F-A, S-F 3Z Hazard No. (ADR) 90 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION 7 / 8

8 PROOFEX WG BASE General information The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date 31 July 2014 Revision 4 Risk Phrases In Full R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard Statements In Full H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Disclaimer The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 8 / 8

9 Revision Date 31 July 2014 Revision 4 SAFETY DATA SHEET PROOFEX WG FILLER SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. PROOFEX WG FILLER A UK Relevant identified uses of the substance or mixture and uses advised against Identified uses Filler component of three part of epoxy resin system 1.3. Details of the supplier of the safety data sheet Supplier FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3XN Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com 1.4. Emergency telephone number +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Xi;R37. Human health Dust may irritate the eyes and the respiratory system Label elements Labelling Irritant Risk Phrases Safety Phrases 2.3. Other hazards R37 S51 S22 Irritating to respiratory system. Use only in well-ventilated areas. Do not breathe dust. Not Classified as PBT/vPvB by current EU criteria. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 6

10 PROOFEX WG FILLER SILICA SAND % CAS-No.: EC No.: Classification (EC 1272/2008) STOT SE 3 - H335 Classification (67/548/EEC) Not classified. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and provide fresh air. Get medical attention if any discomfort continues. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation Dust may irritate throat and respiratory system and cause coughing. Skin contact Dust has an irritating effect on moist skin. Eye contact Dust or splashes from the mixture may cause permanent eye damage Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials Special hazards arising from the substance or mixture Hazardous combustion products No hazardous decomposition products Advice for firefighters Protective equipment for fire-fighters Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid inhalation of dust. Avoid contact with eyes and prolonged skin contact. Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions The product should not be dumped in nature but collected and delivered according to agreement with the local authorities. 2 / 6

11 PROOFEX WG FILLER 6.3. Methods and material for containment and cleaning up Avoid generation and spreading of dust. Collect spillage with shovel, broom or the like and reuse, if possible Reference to other sections For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid inhalation of dust and contact with skin and eyes. Observe occupational exposure limits and minimise the risk of inhalation of dust Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Unspecified storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes SILICA SAND WEL 0,1 mg/m3 WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Engineering measures Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust. Respiratory equipment Dust mask/respirator. No specific recommendation made, but protection against nuisance dust must be used when the general level exceeds 10 mg/m3. (EN 149) Hand protection Use suitable protective gloves if risk of skin contact. PVC or rubber gloves are recommended. Eye protection Wear dust resistant safety goggles where there is danger of eye contact. (conform EN 166) Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 3 / 6

12 PROOFEX WG FILLER 9.1. Information on basic physical and chemical properties Appearance Powder, dust Colour White / off-white. Odour Odourless. Solubility Insoluble in water Initial boiling point and boiling Not applicable. range ( C) Melting point ( C) Not applicable. Relative density 2.02 Flash point ( C) None Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Hazardous Polymerisation Will not polymerise Conditions to avoid No specific conditions are likely to result in a hazardous situation Incompatible materials Materials To Avoid No specific, or groups of materials are likely to react to produce a hazardous situation Hazardous decomposition products No hazardous decomposition products. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation Dust may irritate throat and respiratory system and cause coughing. Skin contact Irritating to skin. Eye contact Irritating to eyes. May cause severe irritation to eyes. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Not regarded as dangerous for the environment Toxicity Acute Fish Toxicity Not considered toxic to fish. 4 / 6

13 PROOFEX WG FILLER Persistence and degradability Degradability The product is not expected to be biodegradable Bioaccumulative potential Bioaccumulative potential Not expected to be bioaccumulative Mobility in soil Mobility: The product is not volatile but may be spread by dust-raising handling Results of PBT and vpvb assessment Not Classified as PBT/vPvB by current EU criteria Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information The material is inert and suitable for disposal at an approved solid waste disposal or landfill site Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General Road Transport Notes Rail Transport Notes Sea Transport Notes Air Transport Notes The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). Not Classified Not classified. Not classified. Not classified UN number Not applicable UN proper shipping name Not applicable Transport hazard class(es) Transport Labels No transport warning sign required Packing group Not applicable Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user 5 / 6

14 Not applicable. PROOFEX WG FILLER Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date 31 July 2014 Revision 4 Risk Phrases In Full R37 Hazard Statements In Full H335 Irritating to respiratory system. May cause respiratory irritation. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6

15 Revision Date 31 July 2014 Revision 4 SAFETY DATA SHEET PROOFEX WG HARDENER SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. PROOFEX WG HARDENER A UK Relevant identified uses of the substance or mixture and uses advised against Identified uses Hardener component of three part epoxy resin floor finish 1.3. Details of the supplier of the safety data sheet Supplier FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3XN Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com 1.4. Emergency telephone number +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health Xn;R22. C;R34. R43. R52/53. Prolonged or repeated contact with skin may cause redness, itching, irritation and eczema/chapping. The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin. Environment The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Contains Labelling TRIMETHYL HEXAMETHYLENEDIAMINE Risk Phrases Corrosive R22 R34 R43 Harmful Harmful if swallowed. Causes burns. May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 1 / 8

16 Safety Phrases 2.3. Other hazards S25 S26 S36/37/39 S45 S60 PROOFEX WG HARDENER Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). This material and its container must be disposed of as hazardous waste. Not Classified as PBT/vPvB by current EU criteria. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures TRIMETHYL HEXAMETHYLENEDIAMINE % CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Classification (67/548/EEC) Xn;R22. C;R34. R43,R52/53. PARA TOLUENE SULPHONIC ACID MONO HYDRATE 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 STOT SE 3 - H335 Classification (67/548/EEC) Xi;R36/37/38. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention immediately! Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Ingestion May cause chemical burns in mouth and throat. 2 / 8

17 PROOFEX WG HARDENER Skin contact May cause serious chemical burns to the skin. May cause sensitization by skin contact. Eye contact Eye contact may cause serious and potentially irreversible injuries Indication of any immediate medical attention and special treatment needed No specific first aid measures noted. Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not allow ANY environmental contamination Methods and material for containment and cleaning up DO NOT TOUCH SPILLED MATERIAL! Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer Reference to other sections For personal protection, see section 8. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Avoid inhalation of vapours/spray and contact with skin and eyes Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Corrosive storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 3 / 8

18 PROOFEX WG HARDENER 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Process conditions Provide eyewash, quick drench. Engineering measures Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours. Respiratory equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. It is recommended to use respiratory equipment with combination filter, type A2/Р2. Hand protection Use suitable protective gloves if risk of skin contact. Polyvinyl chloride (PVC). Nitrile. Viton rubber (fluor rubber). Eye protection If risk of splashing, wear safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. Skin protection Wear apron or protective clothing in case of splashes. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Clear Odour Amine. Ammonia. Solubility Immiscible with water Initial boiling point and boiling > 230 C range ( C) Relative density Vapour pressure kpa 20 ph-value, Conc. Solution 1.1 mixture Flash point ( C) 110 C Auto Ignition Temperature ( C) 350 C 9.2. Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Acids. Alkalis. Oxidising materials. 4 / 8

19 PROOFEX WG HARDENER Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Not known. Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid Strong oxidising substances. Strong acids Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation Harmful by inhalation. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Ingestion Harmful if swallowed. May cause burns in mucous membranes, throat, oesophagus and stomach. Skin contact Causes burns. Harmful in contact with skin. May cause sensitisation by skin contact. Eye contact Causes burns. Risk of serious damage to eyes. Health Warnings This substance is corrosive. Route of entry Inhalation. Ingestion. Skin and/or eye contact. Target Organs No specific target organs noted Toxicological information on ingredients. TRIMETHYL HEXAMETHYLENEDIAMINE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 910 mg/kg Rat Respiratory or skin sensitisation: Sensitising. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment Toxicity 5 / 8

20 Acute Fish Toxicity Ecotoxic to fish/daphnia/algae PROOFEX WG HARDENER Ecological information on ingredients. Acute Toxicity - Fish LC50 48 hours 174 mg/l Leuciscus idus (Golden orfe) Acute Toxicity - Aquatic Invertebrates EC50 24 hours 31.5 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EC50 72 hours 29.5 mg/l Scenedesmus subspicatus Acute Toxicity - Microorganisms EC10 16 hours 72 mg/l Pseudomonas putida Persistence and degradability Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: The product is insoluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not relevant SECTION 13: DISPOSAL CONSIDERATIONS General information TRIMETHYL HEXAMETHYLENEDIAMINE (CAS: ) When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Incinerate in suitable combustion chamber. Note that fully cured material is not considered as hazardous waste. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 2327 UN No. (IMDG) 2327 UN No. (ICAO) UN proper shipping name Proper Shipping Name Proper Shipping Name TRIMETHYLHEXAMETHYLENE DIAMINE TRIMETHYLHEXAMETHYLENEDIAMINES Transport hazard class(es) ADR/RID/ADN Class 8 ADR/RID/ADN Class Class 8: Corrosive substances. 6 / 8

21 ADR Label No. 8 PROOFEX WG HARDENER IMDG Class 8 ICAO Class/Division 8 Transport Labels CORROSIVE Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group III III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS Emergency Action Code F-A, S-B 2X Hazard No. (ADR) 80 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not relevant SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Water hazard classification Water hazard class 2 (German Regulation) (Self Assessment): hazardous for water Chemical Safety Assessment No chemical safety assessment has been carried out. 7 / 8

22 PROOFEX WG HARDENER SECTION 16: OTHER INFORMATION General information The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date 31 July 2014 Revision 4 Risk Phrases In Full R34 Causes burns. R22 Harmful if swallowed. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitisation by skin contact. Hazard Statements In Full H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. Disclaimer The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 8 / 8