Building and Construction

Transcription

1 Building and Construction

2 Edem Lanzareda Business School Fire, Smoke & Toxic Fume Systems (FST) The University of Valencia built using Crestapol 1212 and Crystic Crestabond range of structural adhesives. Our diverse range of products is specifically designed to offer complete systems that meet European and Global FST standards and performance ratings. Our FST products are used in many industries including Rail, Building & Construction and Marine. Scott Bader aims to provide excellent technical support, expertise and advice to support our products. BBVA Headquarters Built using Crestapol 1212 and Crystic 75PA (IMS) resulting in energy savings. Scott Bader was established in 1921 and today we are an independent, multinational chemical company with over 650 employees worldwide. We are a common trusteeship company, which means Scott Bader is owned by all employees, and can operate with great agility and innovation for the customers and industries we serve. Today Scott Bader is a US $287 million global chemical company, with manufacturing facilities in Europe, The Middle East, India, South Africa, Saudi Arabia, Canada and South America. 2

3 Building & Construction FST Product Table Certificates Application Resin Type EU UK FR ES GER US CHINA FST Resins EN BS476-6 BS476-7 NF F NFP M Test DIN4102 ASTM E84 UL94 GB8624 B, s1, d0 Crestapol 1213A* B, s1, d0 (expected to achieve) Crystic 356PA HL DBNPG Class 1 Crystic 799PA Closed mould Ortho Class 2 Crystic 1355PA HL Ortho Class 0 Class 1 Crystic PD9359PA RTM Ortho Class 0 Class 1 FST Resin & system +GC 70PA +GC 76PA +GC LS97PA +GC 967 Crestapol 1216/ATH +GC 76PA Crystic 356PA +GC LS-96PA Crystic 356PA +GC 65PA Crystic 356PA +GC 97PA Crystic 1355PA +GC 65PA Crystic 1355PA Crystic Crystic FR1166PAK Crystic 5046PA Crystic 5046PA +GC 6004 Crystic U 1131TPA HL B, s2, d0 (Indicative) B, s2, d0 (Indicative) C, s2, d0 HL DBNPG Class 0 Class 1 F1 M1 M1 HL DBNPG Class 0 Class 1 F3 M1 HL DBNPG Class 0 Class 1 Class 1 HL Ortho V-0 HL Ortho Class 1 HL Ortho F2 M2 HL & contact moulding Ortho / DCPD HL & S Ortho F2 M1 HL & S Ortho B1 HL & S Ortho F1 M2 F1 M2 B, s1, d0 Crestapol s FST performance is achieved by the addition of aluminium trihydrate (ATH). Due to the inherently low viscosity of Crestapol Resins up to 200 phr of ATH can be incorporated to achieve a range of stringent fire, smoke and toxic fume standards (details can be found on page 7). FST performance will also be dependent on glass content and profile thickness. Please contact Scott Bader Technical Services Dept. for advice on ATH loadings for specific applications. 3

4 Building and Construction Resins & Compounds All our FST resins offer excellent FST performance that are specifically designed to meet European and Global FST standards & performance ratings. For certification please see our composite systems table on page 3. Crystic 356PA Pre-accelerated, filled polyester resin Hand lay-up Crystic 799PA Pre-accelerated, filled polyester resin Halogen and antimony free Good mould flow whilst minimising filler settlement during storage RTM Crystic 1355PA Pre-accelerated, filled, polyester resin Inexpensive & rapidly wets out reinforcement Hand lay-up Crystic Pre-filled, Ortho unsaturated polyester resin Non-accelerated, low styrene content Zero chlorine and zero nitrogen Spray and hand lay-up process Crystic U 1131TPA Pre-accelerated, filled, Ortho unsaturated polyester resin Halogen & heavy metal free Low styrene content Spray and Hand Lay-up Crystic PD9359PA Pre-accelerated, filled, polyester resin RTM Crystic 5046PA Pre-accelerated, filled, Ortho unsaturated polyester resin Hand lay-up & injection processing Crystic FR1166 PAK Pre-accelerated, filled Ortho unsaturated polyester resin Low styrene content Halogen & heavy metal free Spray and hand lay-up process 4

5 Crystic New Technology FST s and Topcoats Protecting composites from fire. Technical performance benefits of Crystic range: High level of FST Performance low surface spread of flame Superior handling Low porosity finish Easy to repair 70PA, 72PA and 73PA are available in all RAL colours *75PA Excel is available in a limited range of colours Crystic 70PA Very low smoke & very low surface spread of flame Halogen free Spray gelcoat Crystic 73PA Low smoke & low surface spread of flame Halogen free Brush gelcoat Crystic 72PA Low smoke & surface spread of flame Halogen free Spray gelcoat Crystic Topcoat 75PA Excel Excellent Fire Retardant Performance Intumescent FST Technology Spray and brush grades available In-house tests have shown that Crystic Topcoat 75PA Excel can withstand a direct flame at 700 C for over 60 minutes Spread of flame on a horizontal burn test after 5 minutes* *Samples tested using the UL94-HB test: 20mm flame is applied to the 3mm thick gelcoat sample for 30 seconds, the resulting horizontal flame spread after 5 minutes is then measured, this is repeated three times and an average is taken. % Flame spread Crystic Topcoat 75PA Excel Crystic 70PA Standard Iso Lightly Halogenated Crystic 72PA Crystic 73PA 5

6 Crestapol Resins Crestapol s FST performance is achieved by the addition of aluminium trihydrate (ATH). Due to the inherent low viscosity of Crestapol resins up to 200 phr of ATH can be incorporated to achieve a range of stringent fire, smoke and toxic fume standards. Fire performance will also be dependent on glass content and profile thickness. Please contact Scott Bader Technical Services Dept. for advice on ATH loadings for specific applications. Property Liquid properties Unit of Measurement Appearance - Crestapol 1212 fracture toughness Crestapol 1212 Clear yellowish brown 25 C 4500 sec - 1 Poise C gcm Volatile Content % 49 Stability in the 20 C Months 9 Crestapol 1212 Acrylate based Thermosetting resin Very Low viscosity Flexibility to adjust ATH & Accelerator levels Pultrusion & Close moulding applications Crestapol 1213A Compounded version of Crestapol 1212 Pre-accelerated and pre-filled with ATH Hand Lamination & Close moulding applications Crestapol 1214 Acrylate based Comparable FST performance of Crestapol 1212 Low Profile technology for aesthetically demanding applications Pultrusion grade only Crestapol 1216 Acrylate based Thermosetting resin Very Low viscosity Resin fully air cures Hand Lamination and Compression moulding 500 Crestapol VE 200 ISO UP (J/m 2 ) 6

7 FST performance in Pultrusion Fire requirement Minimum ATH loading Results French NFP M1 French NFP F0 UNE : 1990 UNE : M1 DIN S4/SR2/ST2 ASTM ASTM ASTM E Is = 10 (limit <35) Meets Federal Railroad Admin requirements for surface flammability Ds (max) = 119 Dm (1.5) = 1 Dm (4) = 4 smoke index 110, flame index 15 ISO HL2 ISO HL2 ISO &2 170 HL2 Pultrusion guidelines Typical formulation Crestapol 1212 and 1214 ATH* BYK W996 # Trigonox C Perkadox 16 (dispersed in solvent) Internal release agent 1 pbw on total resin + filler Pigment (if required) 100 pbw pbw 3-6 pbw 1 pbw 0.5 pbw 1.0 pbw 1-3 pbw 2-5 pbw Die temperature: 140 (First section unheated to prevent gellation at die entrance) Start up approx 0.2 metre/minute # Registered trademark of BYK-Chemie GmbH Perkadox and Trigonox are trademarks of Akzo Nobel Chemicals INT-PUL 341is produced by Axel Plastic Research Laboratories, Inc. Features High Reactivity Offering the potential for high line speeds compared to other typical thermosetting resins. Mechanical Performance The inherent toughness of the cured resin matrix results in profiles exhibiting excellent mechanical performance despite the presence of high levels of filler. Pigmentable 1212 is pigmentable and fully compatible with polyester pigment pastes. 7

8 Scott Bader Group Companies Leading composites innovation for over 60 years Head Office Scott Bader Company Limited Wollaston, England Tel: +44 (0) Fax: +44 (0) Scott Bader France Amiens, France Tel: Fax: info_distribution@scottbader.fr Scott Bader Spain Barcelona, Spain Tel: Fax: diazs@scottbader.es Scott Bader Germany Weiden, Germany Tel: Fax: composites@scottbader.de Scott Bader Ireland Dublin, Ireland Tel: Fax: composites@scottbader.ie Scott Bader Scandinavia AB Falkenberg, Sweden Tel: Fax: composites@scottbader.se SB Eastern Europe s.r.o Mimon II, Czech Republic Tel: +420 (0) Fax: +420 (0) miro@sbee.cz Scott Bader Croatia Zagreb, Croatia Tel: Fax: info@scottbader.hr Scott Bader North America Stow, OH, USA Tel: Fax: info@scottbader-na.com NovaScott Especialidades Químicas Ltda Civit II, Serra, ES Brazil Tel: info@novascott.com.br Scott Bader South Africa Hammarsdale, South Africa Tel: Fax: composites@scottbader.co.za Scott Bader Middle East Limited Dubai, United Arab Emirates Tel: Fax: info@scottbader.ae Scott Bader Asia Pacific Shanghai, China Tel: +86 (21) Fax: +86 (21) info@scottbader.cn Satyen Scott Bader Pvt. Ltd Mumbai, India Tel: Fax: info@satyenpolymers.com All information correct at time of printing. Issue 1