Avonley Road SE14 5ER London

Transcription

1 Date of issue:11/11/2015 Revision date:11/11/2015 : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Article number : Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Function or use category : Professional use. Consumer use : Lubricants and additives Uses advised against 1.3. Details of the supplier of the safety data sheet 1.4. Emergency telephone number Country Organization/Company Address Emergency number Comment Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Avonley Road SE14 5ER London Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified 2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display EUH phrases : EUH208 - Contains Calcium long chain alkaryl sulfonate. May produce an allergic reaction Security closing plug for children. Tactile warning 2.3. Other hazards SECTION 3: Composition/Information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Zinkalkyl dithiofosfaat (CAS No) (EC no) (REACH-no) Full text of H-phrases: see section Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general special measures required. 11/18/2015 EN (English US) 1/6

2 First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Assure fresh air breathing. Call a poison center or a doctor if you feel unwell. irritant effect. : Immediately rinse with water for a prolonged period while holding the eyelids wide open. : Do NOT induce vomiting. Get immediate medical advice/attention Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed If swallowed or in case of vomiting, danger of entering the lungs. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Dry chemical. Foam. Water. : Do not use a heavy water stream Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : High temperature may liberate toxic gases Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders Protective equipment : Wear proper protective equipment Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections No dangerous substances are released. See Headings 7 and 8. See Heading 13. : Soak up with absorbent material (for example sand, sawdust, neutral absorbent granule, silica gel). Take up large spills with pump or vacuum. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Use adequate ventilation to keep oil mist below applicable standard Conditions for safe storage, including any incompatibilities Storage conditions : Store in a dry, cool place. Keep container tightly closed. Packaging materials : Keep only in original container Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA - ACGIH ACGIH STEL (mg/m³) 10 mg/m³ (OSHA PEL: 5 mg/m3) 8.2. Exposure controls Personal protective equipment : Gloves. 11/18/2015 EN (English US) 2/6

3 Hand protection Eye protection Skin and body protection Respiratory protection : Wear suitable gloves tested to EN374. Gloves material: Nitrile. PVC gloves. neoprene/butyl rubber. Refer to manufacturer's information. Penetration time of glove material: 240 min : Use eye protection to EN 166, designed to protect against liquid splashes : Wear suitable protective clothing t required. Other information : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) : Liquid : clear. : characteristic. Melting point : -36 C (ASTM D97) Freezing point Boiling point Flash point : > 215 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density Solubility Log Pow : 0.87 g/cm³ (20 C) : Practically not miscible. Organic solvent:0.0% Viscosity, kinematic : 57.2 mm²/s (ASTM D445) 40 C C: 9.7 mm2/s (ASTM D445) Viscosity, dynamic Explosive properties Oxidizing properties Explosion limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability To avoid thermal decomposition, do not overheat Possibility of hazardous reactions Strong oxidizers Conditions to avoid Incompatible materials Hazardous decomposition products No hazardous decomposition products known. : Product is not explosive. Not self-igniting. 11/18/2015 EN (English US) 3/6

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard > 2000 mg/kg > 2000 mg/kg irritant effect. irritant effect. sensitization responses were observed : This product contains mineral oils which are considered to be severely refined and not considered. Carcinogenic under IARC It was demonstrated by the IP 346 test all oils in this product contain less than 3% extractables. Viscosity, kinematic 57.2 mm²/s (ASTM D445) 40 C C: 9.7 mm2/s (ASTM D445) Other information : The product is not subject to classification. According to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product on the basis of our experience and the information provided to us will not cause adverse health effects. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Almost not biodegradable Bioaccumulative potential Mobility in soil Ecology - soil Prevent entry to sewers and public waters Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations EURLW code SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Prevent entry to sewers and public waters. Dispose in a safe manner in accordance with local/national regulations. : * - mineral-based non-chlorinated engine, gear and lubricating oils UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) 11/18/2015 EN (English US) 4/6

5 Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 4) 11/18/2015 EN (English US) 5/6

6 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands Waterbezwaarlijkheid SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : 11 - Weinig schadelijk voor in het water levende organismen : Zinkalkyl dithiofosfaat is listed : Zinkalkyl dithiofosfaat is listed ne of the components are listed ne of the components are listed ne of the components are listed : Emergency management guidelines for the storage of flammable liquids must be followed Chemical safety assessment No SECTION 16: Other information Abbreviations and acronyms: Abbreviations and acronyms: RID: Regulations Concerning the International Transport of Dangerous Goods by Rail ICAO: International Civil Aviation Organization ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Full text of H- and EUH-phrases: Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 Eye Dam. 1 Serious eye damage/eye irritation Category 1 Skin Irrit. 2 Skin corrosion/irritation Category 2 H315 H318 H411 EUH208 Causes skin irritation Causes serious eye damage Toxic to aquatic life with long lasting effects Contains. May produce an allergic reaction SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 11/18/2015 EN (English US) 6/6