: Bonide Ant, Roach and Spider Killer(Aerosol)

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product code : 4461 : Bonide Ant, Roach and Spider Killer(Aerosol) 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Insecticide 1.3. Details of the supplier of the safety data sheet Bonide Products, Inc Sutliff Road Oriskany, NY T (315) Emergency telephone number Emergency number : CHEMTREC - 1 (800) and/or 1 (703) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 4 H Label elements GHS-US labeling Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Warning : H227 - Combustible liquid : P210 - Keep away from open flames. - No smoking P280 - Wear chemical resistant gloves/eye protection/long sleeves, long pants, full footwear P370+P378 - In case of fire: Use carbon Dioxide, Dry Chemical, Foam, or Water for extinction P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents/container to in accordance with local/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients Mixture Name Product identifier % Classification (GHS-US) S-bioallethrin (CAS No) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Deltamethrin (CAS No) Acute Tox. 3 (Oral), H301 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the person to rest. If you feel unwell, seek medical advice. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Consult a doctor/medical service if you feel unwell. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Revision date: 02/16/2016 EN (English US) Page 1

2 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : NOTE FOR PHYSICIAN: This product is a synthetic Pyrethroid pesticide. If ingested and vomiting has not occured, emesis should be induced with supervision. Keep patient's head below hips to prevent aspiration. If symptoms such as loss of gag reflex, convulsions or unconsciousness occur before emesis, gastric lavage using a cuffed endotracheal tube should be considered. Do not administer milk, cream or other substances containing vegetable to animal fats. These only enhance absorption of lipophilic substances. If localized parestesia develops, the site should be throughly washed with soap and water. Cold cream can be applied to deminish effect. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Explosion hazard : Combustible liquid. : May form flammable/explosive vapor-air mixture Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Handle empty containers with care because residual vapors are flammable. Keep away from sparks/open flames/hot surfaces. - No smoking. : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Proper grounding procedures to avoid static electricity should be followed. : Keep container closed when not in use. : Strong bases. strong acids. : Sources of ignition. Heat sources. Revision date: 02/16/2016 EN (English US) 2/6

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear approved mask. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Off white Liquid Aerosol. Color : White. Odor : Soapy detergent, faint oily like. Odor threshold ph : 5.6 Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point : 168 F Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Density : g/l Solubility : Emulsifies in water. Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. Revision date: 02/16/2016 EN (English US) 3/6

4 10.5. Incompatible materials Strong oxidizing agents and acids Hazardous decomposition products May release flammable gases. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms 430 mg/kg (Rat) mg/kg (Rat) 1545 mg/kg (Rabbit) 128 mg/kg (Rat) ph: 5.6 ph: Not Classifiable : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 LC50 other aquatic organisms 1 LC50 fish 2 TLM fish 1 Threshold limit other aquatic organisms 1 LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) mg/l (96 h; Gammarus sp.) mg/l (96 h; Lepomis macrochirus) < mg/l (96 h; Lepomis macrochirus) mg/l (96 h; Gammarus sp.) mg/l 48 h; Salmo gairdneri (Oncorhynchus mykiss) mg/l (24 h; Daphnia magna; Locomotor effect) mg/l (48 h; Gambusia affinis) mg/l (48 h; Daphnia magna; Locomotor effect) Persistence and degradability Bonide Ant, Roach and Spider Killer(Aerosol) Persistence and degradability Persistence and degradability ThOD 2.54 g O²/g substance Revision date: 02/16/2016 EN (English US) 4/6

5 Persistence and degradability Bioaccumulative potential Bonide Ant, Roach and Spider Killer(Aerosol) Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential No bioaccumulation data available Mobility in soil Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Additional information Ecology - waste materials SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information Other information SECTION 15: Regulatory information : Dispose in a safe manner in accordance with local/national regulations. : Handle empty containers with care because residual vapors are flammable. : Avoid release to the environment. : No supplementary information available. This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if swallowed US Federal regulations International regulations US State regulations U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Flam. Liq. 4 Flammable liquids Category H227 Combustible liquid H301 Toxic if swallowed H302 Harmful if swallowed H312 Harmful in contact with skin Revision date: 02/16/2016 EN (English US) 5/6

6 H332 Harmful if inhaled H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects SDS US (GHS HazCom 2012) - Pesticides This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product Revision date: 02/16/2016 EN (English US) 6/6