: ZINC CITRATE (Di- or TRIHYDRATE)

Transcription

1 Revision date: 13/06/2014 Supersedes: 11/07/2013 Version: 5.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Substance name : ZINC CITRATE (Di- or TRIHYDRATE) EC no : CAS No : REACH registration No : Formula : Zn3 (C6H5O7)2, 2 H2O / Zn3 (C6H5O7)2, 3 H2O 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Title Formulation of preparationsx (ES Ref.: 1) : Personal care products (See exposure scenario nr 1) Use descriptors SU3, SU10, PC39, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, ERC2 Full text of use descriptors: see section Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer : JOST CHEMICAL CO Lackland Saint Louis MO USA T : / F : Distributor : JOST EUROPE Rue de Perwez 108 A 5300 ANDENNE BELGIQUE T : / F : troulet@josteurope.com 1.4. Emergency telephone number Country Organisation/Company Address Emergency number UNITED KINGDOM SECTION 2: Hazards identification National Poisons Information Service (Birmingham Centre) City Hospital 2.1. Classification of the substance or mixture Dudley Road B18 7QH Birmingham Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1 Aquatic Acute 1 H400 Full text of H-phrases: see section (UK only) Classification according to Directive 67/548/EEC or 1999/45/EC N; R50 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects Very toxic to aquatic life. Not classified as flammable according to EC criteria, but may present a risk in the event of a fire. 13/06/2014 EN (English) 1/12

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS09 : Warning : H400 - Very toxic to aquatic life : P273 - Avoid release to the environment P391 - Collect spillage P501 - Dispose of contents/container to a licensed disposal company 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Name Product identifier % Classification according to Directive 67/548/EEC ZINC CITRATE (Di- or TRIHYDRATE) (Main constituent) (CAS No) (EC no) (REACH-no) ,4-100 N; R50 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] ZINC CITRATE (Di- or TRIHYDRATE) (Main constituent) (CAS No) (EC no) (REACH-no) ,4-100 Aquatic Acute 1, H400 Full text of R- and H-phrases: see section Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Move the affected person away from the contaminated area and into the fresh air. : Immediately remove contaminated clothing or footwear. Wash with plenty of water. : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum). Consult an ophthalmologist if irritation persists. : If the quantity swallowed is significant : Ask for medical advice Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Metal fume fever. Symptoms/injuries after ingestion : Vomiting. Diarrhea Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Carbon dioxide. Dry powder. Foam Special hazards arising from the substance or mixture Fire hazard : Combustible. During combustion : Toxic vapours may be released Advice for firefighters Firefighting instructions Protection during firefighting : Contain the extinguishing fluids by bunding (the product is hazardous for the environment). Use water spray or fog for cooling exposed containers. : Do not attempt to take action without suitable protective equipment. Complete protective clothing. Self-contained breathing apparatus. 13/06/2014 EN (English) 2/12

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Do not allow product to spread into the environment. Do not discharge into drains or rivers Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections For further information refer to section 13. : Sweep up or vacuum up the product. Gather the product and place it in a spare container that has been suitably labelled. : Dispose of contaminated materials in accordance with current regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Extraction to remove dust at its source. Avoid contact with skin and eyes. Avoid creating or spreading dust. : Do not drink, eat or smoke in the workplace. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products 7.3. Specific end use(s) : Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the rupture of containers or transfer systems. : Store in dry, cool, well-ventilated area. Keep container tightly closed. : Strong oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ZINC CITRATE (Di- or TRIHYDRATE) ( ) DNEL/DMEL (Workers) Acute - systemic effects, dermal Acute - systemic effects, inhalation Long-term - systemic effects, dermal Long-term - systemic effects, inhalation PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC (Sediment) PNEC sediment (freshwater) PNEC sediment (marine water) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant 0,54 mg/kg bodyweight/day 1,89 mg/m³ 0,54 mg/kg bodyweight/day 1,89 mg/m³ 7,8 µg/l (Zn) 2 µg/l (Zn) 11 mg/kg (Zn) 1,1 mg/kg (Zn) 23 mg/kg (Zn) 52 µg/l (Zn) 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Respiratory protection : Ensure good ventilation of the work station. Extraction to remove dust at its source. Eye fountain. : Protective gloves. The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN 374. Breakthrough time : refer to the recommandations of the supplier. : Safety glasses. : If dust are formed : Gas mask with filter type P1/FFP1. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid 13/06/2014 EN (English) 3/12

4 Colour Odour Odour threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : white. : odourless. : Not applicable : 295 C (Decomposes) : Not applicable : Not applicable : Not applicable : Non flammable : Water: Very slightly soluble : Not applicable : Not explosive. : Non oxidizing material according to EC criteria Other information SECTION 10: Stability and reactivity Reactivity To our knowledge, the product does not present any particular risk, under normal conditions of use Chemical stability Stable at ambient temperature and under normal conditions of use Possibility of hazardous reactions None to our knowledge Conditions to avoid None to our knowledge Incompatible materials Strong oxidizing agents Hazardous decomposition products On combustion or on thermal decomposition (pyrolysis) releases : Carbon oxydes (CO, CO2). Zinc oxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ZINC CITRATE (Di- or TRIHYDRATE) ( ) LD50 oral rat > 2000 mg/kg (OECD 401) LD50 dermal rat > 2000 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity (Results obtained on a similar product) ph: Not applicable (Results obtained on a similar product) ph: Not applicable (Results obtained on a similar product) (Results obtained on a similar product) 13/06/2014 EN (English) 4/12

5 Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard (Results obtained on a similar product) : Not classified (Not applicable) SECTION 12: Ecological information Toxicity Ecology - general : No information available on this specific product, however by analogy, the product is considered to be: Very toxic to aquatic life. ZINC CITRATE (Di- or TRIHYDRATE) ( ) LC50 fishes 0,136 mg/l/96h (Zinc) EC50 Daphnia 1535 mg/l/96h (Daphnia magna) (Citric acid) EC50 other aquatic organisms 0,068 mg/l (Daphnia magna / zinc) LC50 fish 440 mg/l/96h (Citric acid) NOEC (acute) 0,005 mg/l/72h (Scenedesmus quadricauda, algae / zinc) Persistence and degradability ZINC CITRATE (Di- or TRIHYDRATE) ( ) Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment ZINC CITRATE (Di- or TRIHYDRATE) ( ) Results of PBT assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Additional information SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN Readily biodegradable. (Results obtained on a similar product). The product does not meet the PBT and vpvb classification criteria : Dispose of in accordance with relevant local regulations. : The user's attention is drawn to the possible existence of specific european, national or local regulations regarding disposal. ADR IMDG IATA UN number UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc citrate (dior trihydrate)) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc citrate (dior trihydrate)) Transport hazard class(es) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc citrate (dior trihydrate)) Packing group III III III Environmental hazards Dangerous for the environment : Yes Dangerous for the environment : Yes Marine pollutant : Yes Dangerous for the environment : Yes 13/06/2014 EN (English) 5/12

6 14.6. Special precautions for user Overland transport Classification code (ADR) : M7 Special provision (ADR) : 274, 335, 601 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5kg : E1 : P002, IBC08, LP02, R001 : PP12, B3 : MP10 : T1, BK1, BK2 : TP33 : SGAV, LGBV : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Bulk (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) : V13 : VV1 : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) EAC code : E : 2Z Transport by sea Special provision (IMDG) : 274, 335, 966, 967 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 Packing provisions (IMDG) : PP12 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1, BK1, BK2, BK3 Tank special provisions (IMDG) : TP33 Stowage category (IMDG) : A MFAG-No : Air transport PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y956 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 956 PCA max net quantity (IATA) : 400kg CAO packing instructions (IATA) : 956 CAO max net quantity (IATA) : 400kg Special provision (IATA) : A97, A158, A179 ERG code (IATA) : 9L Inland waterway transport Not applicable Rail transport Not applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable 13/06/2014 EN (English) 6/12

7 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions National regulations Chemical safety assessment For this substance a chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: This sheet was updated (refer to the date at the top of this page). This sheet has been revised completely (changes were not marked). Data sources Other information : CSR (Chemical safety report). Joint Research Center (JRC). IUCLID. : Safety data sheet established by : LISAM SERVICES - TELEGIS 17, Rue de la Couture F PASSEL Safety Made Easy with Full text of R-, H- and EUH-phrases: Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Very toxic to aquatic life R50 N ERC2 PC39 PROC2 PROC3 PROC4 PROC5 PROC8a PROC8b PROC9 SU10 SU3 Very toxic to aquatic organisms Dangerous for the environment Formulation of preparations Cosmetics, personal care products Use in closed, continuous process with occasional controlled exposure Use in closed batch process (synthesis or formulation) Use in batch and other process (synthesis) where opportunity for exposure arises Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Formulation [mixing] of preparations and/or re-packaging (excluding alloys) Industrial uses: Uses of substances as such or in preparations at industrial sites SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 13/06/2014 EN (English) 7/12

8 Annex to the 1. Exposure scenario 1 Formulation of preparations ES Ref.: 1 ES Type: Worker Version: 1 Revision date: 01/07/2013 Use descriptors Processes, tasks, activities covered PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9 PC39 SU3, SU10 ERC2 2. and risk management measures Contributing scenario controlling worker exposure (PROC2) PROC2 Use in closed, continuous process with occasional controlled exposure Solid, high dustiness Frequency and duration of use Exposure duration > 4 h/day Exposed skin surface (cm²) : 480 (two hands, face side only) Contributing scenario controlling worker exposure (PROC3) PROC3 Use in closed batch process (synthesis or formulation) Solid, high dustiness Frequency and duration of use Exposure duration > 4 h/day Exposed skin surface (cm²) : 480 (two hands, face side only) 13/06/2014 EN (English) 8/12

9 2.1.3 Contributing scenario controlling worker exposure (PROC4) PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises Solid, high dustiness Frequency and duration of use Exposure duration 1-4 h/day Exposed skin surface (cm²) : 480 (two hands, face side only) Contributing scenario controlling worker exposure (PROC5) PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact), Solid in solution Solid, high dustiness, Solid, low dustiness Frequency and duration of use Exposure duration 1-4 h/day Exposed skin surface (cm²) : 480 (two hands, face side only) Contributing scenario controlling worker exposure (PROC8a) PROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities Solid, high dustiness 13/06/2014 EN (English) 9/12

10 Frequency and duration of use Exposure duration 15min- 1 h/day Exposed skin surface (cm²) : 960 (two hands) Contributing scenario controlling worker exposure (PROC8b) PROC8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities Solid, high dustiness Frequency and duration of use Exposure duration 15min- 1 h/day Exposed skin surface (cm²) : 480 (two hands, face side only) Contributing scenario controlling worker exposure (PROC9) PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Solid, high dustiness Frequency and duration of use Exposure duration 15min- 1 h/day Exposed skin surface (cm²) : 480 (two hands, face side only) 13/06/2014 EN (English) 10/12

11 X X X X X X X ZINC CITRATE (Di- or TRIHYDRATE) 2.2 Contributing scenario controlling environmental exposure (ERC2) ERC2 Formulation of preparations Volatility Low volatility Amounts used Maximum daily site tonnage (kg/day): (Zn) 140 Annual site tonnage (tonnes/year): (Zn) 42 Other given operational conditions affecting Release fraction to wastewater (ERC2) 0,02 environmental exposure Release fraction to wastewater (TGD IV,2,A) 0,0009 Release fraction to air from process Negligible. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Conditions and measures related to municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste 3. Exposure estimation and reference to its source 3.1. Health Information for contributing exposure scenario Removal of solids in settling tanks Size of the STP : 2000 m³/day (by default) Reprocess or burn in an approved incinerator Controlled application to agricultural soil Dermal uptake of solid citrates is expected to be negligible and is not considered,dermal uptake factor of 0.02 applied for the liquid formulation Long-term - systemic effects DNEL Contributing Scenario PROC2 PROC3 PROC4 PROC5 PROC8a PROC8b PROC9 Inhalation: 1,89 mg/m³ Dermal: 0,54 mg/kg bodyweight/day inhalation exposure mg/m³ RCR dermal exposure mg/kg bodyweight/day RCR Sum RCR Assessment method 0,1 0, ,053 Inhalation: Used ECETOC TRA 0,1 0, ,053 Inhalation: Used ECETOC TRA 1,5 0, ,794 Inhalation: Used ECETOC TRA 1,5 (solid) 0,03 (liquid) 0,794 0, ,016 (liquid) 0 0,030 0, Inhalation: Used ECETOC TRA Dermal: Used ECETOC TRA 1 0, ,529 Inhalation: Used ECETOC TRA 0,5 0, ,265 Inhalation: Used ECETOC TRA 0,4 0, ,212 Inhalation: Used ECETOC TRA 3.2. Environment Environmental exposure Unit Exposure estimation PNEC RCR Assessment method Freshwater µg/l 0,217 7,8 0,028 Used EUSES Marine water µg/l 0, ,013 Used EUSES Freshwater sediment mg/kg 5, ,472 Used EUSES Marine water sediment mg/kg 0,632 1,1 0,575 Used EUSES Sewage treatment plant µg/l ,673 Used EUSES Soil mg/kg 1, ,05 Used EUSES 13/06/2014 EN (English) 11/12

12 4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the ES 4.1. Health Guidance - Health 4.2. Environment Guidance - Environment No additional risk management measures, besides those that are mentioned above, are needed to guarantee safe use for workers. No additional risk management measures, besides those that are mentioned above, are needed to guarantee safe use for environment. 13/06/2014 EN (English) 12/12