Safety Summary. Ammonium nitrate based fertilizer 33,5 %

Transcription

1 Novomoskovskiy Azot 10 Svyazi St., Novomoskovsk, Tula Region, , Russia Safety Summary Global Product Strategy (GPS) according to the recommendations of International Council of Chemical Associations (ICCA) as the fulfillment of the obligations under the Strategic Approach to International Chemicals Management (SAICM) of United Nations (UN). Ammonium nitrate based fertilizer 33,5 % This safety summary is provided within the scope of ICCA Global Product Strategy (GPS) to provide to the general public. GPS safety summary includes explanations on the possible chemical hazards and/or exposure scenarios, as well as information on safe handling and risk management. This summary is not intended to provide technical information on emergency actions, medical information or information on treatment in case of exposure. 1. General information Producer: Novomoskovskiy Azot (NAK Azot) Address: 10 Svyazi St., Novomoskovsk, Tula Region, , Russia Tel.: +7 (48762) , ext: Fax: +7 (48762) , ext Novomoskovsk@eurochem.ru 2. Substance identification Trade name Ammonium nitrate based fertilizer 33,5 % Technical Name: Stabilized Ammonium Nitrate Fertilizer Chemical Name Not applicable CAS-No Not applicable. EC-No Not applicable. 3. Product Uses It is used in agriculture as a nitrogen fertilizer for all crops for the core, when entering seed and feed in accordance with the regulations of application depending on the type of crop, its cultivation technology, the planned harvest, taking into account agrochemical parameters of the soil. Basic technical characteristics according to TC Components Mass Max. permissible Hazard Class fraction, % concentration, mg/m 3 Ammonium nitrate 91,4 97,1 not applicable No CAS ES Dolomite CAS ES ,4 8,1 -/ 6 (on limestone) 4

2 The product is a preparation within the meaning of the REACH Regulation (1907/2006/EC). The following table contains the main constituent at the top. Chemical Name Concentration, wt. % CAS-No EC-No / Registration number Ammonium nitrate 92,8-95, / Dolomite 4-6, Water and others addition 0,5 - - Aluminium sulphate 0, Physical/Chemical Properties / XXXX Physical state Colour Odor Explosive properties Flammability Oxidizing properties Granulated White. No data available. No explosive. Non flammable No oxidizing. Molecular Weight Not applicable. Boiling point/boiling range No data available Flash Point Not applicable. The substance is a solid at room temperature Ignition temperature 380 С Autoignition temperature 385 С Vapor pressure Not applicable (testing does not appear scientifically necessary). Melting point/range 165 ± 1 С Bulk Density 1,025-1,026 g/cm3 Water solubility > 90% at 20 C Partition coefficient: n-octanol/water No data available Decomposition point/range ºC Viscosity, dynamic Not applicable. Viscosity is only relevant to liquids. The substance is a solid at room temperature. Viscosity, kinematic Not applicable. Viscosity is only relevant to liquids. The substance is a solid at room temperature. 5. Health information 5.1 DNEL (Derived No-Effect Level)/DMEL (Derived Minimal Effect Level) For workers Inhalation - acute - systemic effects, mg/m 3 : No data available Inhalation - acute - local effects, mg/m 3 : No data available Inhalation - long-term - systemic effects, mg/m 3 : Ammonium nitrate 36.7 Inhalation - long-term - local effects, mg/m 3 : No data available Dermal - acute - systemic effects, mg/kg bw day: No data available Dermal - acute - local effects, mg/kg bw day: no data available Dermal - long-term - systemic effects, mg/kg bw day: Ammonium nitrate 21.3 Page 2 of 7

3 Dermal - long-term - local effects, mg/kg bw day: No data available Oral - acute - systemic effects, mg/kg bw day: No data available Oral - acute - local effects, mg/kg bw day: No data available Oral - long-term - systemic effects, mg/kg bw day: No data available Oral - long-term - local effects, mg/kg bw day: No data available For consumers Inhalation - acute - systemic effects, mg/m 3 : No data available Inhalation - acute - local effects, mg/m 3 : No data available Inhalation - long-term - systemic effects, mg/m 3 : Ammonium nitrate 11.1 Inhalation - long-term - local effects, mg/m 3 : No data available Dermal - acute - systemic effects, mg/kg bw day: No data available Dermal - acute - local effects, mg/kg bw day: No data available Dermal - long-term - systemic effects, mg/kg bw day: Ammonium nitrate 12,8 Dermal - long-term - local effects, mg/kg bw day: No data available Oral - acute - systemic effects, mg/kg bw day: No data available Oral - acute - local effects, mg/kg bw day: No data available Oral - long-term - systemic effects, mg/kg bw day: Ammonium nitrate 12.8 Oral - long-term - local effects, mg/kg bw day: No data available 5.2 Toxicity value Acute oral toxicity LD50 (rats) mg/kg: Ammonium nitrate LD50 (rat): mg/kg Acute dermal toxicity LD50 (rats) mg/kg: Ammonium nitrate LD50 (rat): > mg/kg Acute inhalation toxicity LD50 (rats): No data available Chronic inhalation toxicity: No data available 5.3 Irritation/Corrosivity/Sensitization Irritation/corrosion (eyes/skin): May irritate eyes. Sensitization (skin/respiratory tract): No effect 5.4 CMR-effects Carcinogenisity Mutagenicity Suspected of causing cancer no effect 5.5 Specific target-organ toxicity Single exposure - No data available Repeated dose toxicity: (subacute/subchronic) Ammonium nitrate NOAEC (sub-acute; rat (male)): 185 mg/m 3 Route of application: inhalation Exposure time: 2 weeks (5 hrs/day; 5 days/week) 6. Environmental information 6.1 Predicted No Effect Concentration (PNEC) Page 3 of 7

4 PNEC aqua freshwater: Ammonium nitrate 0.45 mg/l PNEC aqua - marine water: Ammonium nitrate mg/l PNEC aqua - intermittent releases: Ammonium nitrate 4.5 mg/l PNEC STP: Ammonium nitrate 18 mg/l 6.2 Toxicity value Short-term toxicity to fish LC50 (96 h, mg/l): Ammonium nitrate LC50 (Cyprinus carpio): 447 mg/l Exposure time: 48 h Toxicity to daphnia and other aquatic EC50 mg/l 555 invertebrates: Toxicity to algae: EC50 mg/l Environmental fate Phototransformation: No data available Hydrolysis: No data available Biodegradation: No data available Bioaccumulation: No data available PBT and vpvb assessment: The substance is not considered a PBT/vPvB 7. Exposure Assessment See section Recommendations on Risk Management Closed manufacturing processes (if necessary), performance forced-air or local exhaust ventilation at the work zone, use of personal protection equipment. Minimization of quantity of exposed workers. Use of special dispensers and pumps designed to prevent splashes / spills. Effective removal of contaminants. Minimization of manual phases. Avoidance of contact with contaminated tools and objects. Regular cleaning of equipment and work area. Verification of the appropriate use of risk management measures. Ensure high levels of personal hygiene. Inform consumers through labeling. 9. Classification and labelling 9.1 Classification Classification to REGULATION (EC) No 1272/2008 Oxidizing solids, Category 3 H272: May intensify fire; oxidizer Eye irritation, Category 2A H319: Causes serious eye irritation. 9.2 Labelling Labeling according to REGULATION (EC) No 1272/2008 Page 4 of 7

5 Hazard pictogram(s): Exclamation mark Flame over circle Signal word Hazard statements Prevention: Response: Warning H272: May intensify fire; oxidizer H319: Causes serious eye irritation P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P220: Keep/Store away from cloting/ metal powders/organic/combustible materials. P264: Wash hands thoroughly after handling. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P370+Р378: In case of fire: Use water for extinction. 9.3 PBT assessment The substance is not considered a PBT/vPvB. 10. Registartion information Ammonium nitrate based fertilizer 33,5 % Registration Number: Not applicable. 11. Conclusion Calculation of exposure and risk assessment was carried out on ammonium nitrate as a substance, contribute most to the product In the Product Safety Summary for risk calculations the following Exposure scenarios are used: Identifiers ES1 - M1 Titles of exposure scenarios and the related contributing scenarios Manufacture - Manufacture - Manufacture (ERC 1) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 14) Page 5 of 7

6 ES3 - IW1 ES8 - PW2 ES9 - PW3 Use at industrial site - Use at industrial site - Use at industrial site (ERC 6a) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 13) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8b) - Worker contributing scenario (PROC 11) - Worker contributing scenario (PROC 19) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8e) - Worker contributing scenario (PROC 11) - Worker contributing scenario (PROC 19) GPS safety risk calculations performed for production, processing, use and disposal of Ammonium nitrate based fertilizer 33,5 and when exposed to the consumer and the environment (in accordance with the ECHA Guidelines on Safety Assessment). The analysis shows that risks could be adequately controlled through the use of standardized technical, organizational measures, which are designed and operated by NAK Azot. 12. Contact information For more information on the matter, please contact: Novomoskovsk@eurochem.ru or visit: Date of issue 09-Sept-2016 Note For more information on first aid measures, fire fighting, prevention and elimination of accidents and emergency situations and their consequences, recycling, safe use and transportation and storage rules, refer to the Safety Data Sheet (SDS) for this chemical or chemical products. While the data and information contained herein are presented in Page 6 of 7

7 good faith and believed to be accurate at the date of printing, it is provided for your guidance only and may be revised in the future. No warranties of any kind, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made regarding the data or information provided. Further, the Company assumes no obligation or liability whatsoever resulting from use of or reliance on the data and information given. The Company makes no commitment to update or correct any information that appears on the Internet. Page 7 of 7