DEPARTMENT OF TRANSPORTATION HAZMAT TRAINING COURSE [ 49 CFR ] ITINERARY

Transcription

1 DEPARTMENT OF TRANSPORTATION HAZMAT TRAINING COURSE [ 49 CFR ] 8:00 am - 8:15 am INTRODUCTION ITINERARY 8:15 am - 8:25 am REGULATORY OVERVIEW 8:25 am - 9:00 am HAZARDOUS MATERIAL CLASSES 9:00 am - 9:10 am BREAK 9:10 am - 9:20 am CONTAINER MARKINGS 9:20 am - 9:30 am LOADING AND UNLOADING 9:30 am - 10:00 am HAZARDOUS MATERIALS TABLES 10:00 am - 10:10 am BREAK 10:10 am - 10:45 am HAZARDOUS MATERIALS EERCISE 10:45 am - 11:40 am UNIFORM HAZARDOUS WASTE MANIFEST 11:40 am - 12:00 pm STRAIGHT BILL OF LADING 12:00 pm - 1:00 pm LUNCH 1:00 pm - 1:20 pm 704 MARKING SYSTEM 1:20 pm - 1:50 pm HAZARD COMMUNICATION 1:50 pm - 2:00 pm BREAK 2:00 pm - 2:30 pm "FIRST ON THE SCENE" VIDEO 2:30 pm - 3:00 pm EMERGENCY RESPONSE GUIDEBOOK 3:00 pm - 3:10 pm BREAK 3:10 pm - 3:40 pm PERSONAL PROTECTIVE EQUIPMENT 3:40 pm - 4:05 pm HAZARDOUS MATERIAL DEFINITIONS 4:05 pm - 4:15 pm BREAK 4:15 pm - 5:00 pm COURSE REVIEW AND FINAL TEST NOTE: Times indicate only an approximate guideline. ( LP i ) NEI

2 SUBJECT: INTRODUCTION Time of Lesson: 15 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook, Background Survey/Evaluation Objectives: To explain the training approach to the students and what is to be accomplished from this course. LESSON OUTLINE: 8:00 am I. Explain the training approach for the course A. Student Workbook B. Hazardous Material Compliance Pocketbook C. Emergency Response Guidebook D. Course Test II. Pass out and have students complete Background forms III. Review the table of contents with students 8:15 AM IMPORTANT INFORMATION! Blue text are main headings or other information that needs to be stressed. Red text is information students need to write in their workbook. NEI ( LP ii )

3 TABLE OF CONTENTS REGULATORY OVERVIEW 1 HAZARDOUS MATERIAL CLASSES 2 CONTAINER MARKINGS 5 LOADING AND UNLOADING 6 HAZARDOUS MATERIALS TABLES 7 HAZARDOUS MATERIAL EERCISE 10 UNIFORM HAZARDOUS WASTE MANIFEST 11 STRAIGHT BILL OF LADING MARKING SYSTEM 23 HAZARD COMMUNICATION 24 EMERGENCY RESPONSE GUIDEBOOK 30 PERSONAL PROTECTIVE EQUIPMENT 32 HAZARDOUS MATERIALS DEFINITIONS 34 ATTACHMENT A: UNIFORM HAZARDOUS WASTE MANIFEST 36 ATTACHMENT B: STRAIGHT BILL OF LADING 38 ATTACHMENT C: FUNCTION SPECIFIC TRAINING VERIFICATION 39 ATTACHMENT D: DRIVER TRAINING VERIFICATION 40 ATTACHMENT E: HAZMAT SECURITY AWARENESS 41

4 SUBJECT: Time of Lesson: REGULATORY OVERVIEW 10 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 1 Objectives: To give the students an understanding of the regulations that are covered in the course. LESSON OUTLINE: 8:15 am Review the following regulations with students: I. 49 CFR (1) II. 49 CFR (2): See Appendix C for a copy of the form. III. 49 CFR (3) IV. 49 CFR (4) V. 49 CFR (5) VI. 49 CFR See Appendix D for a copy of the form. 8:25 am IMPORTANT INFORMATION! NEI ( LP 1 )

5 I. 49 CFR (1): REGULATORY OVERVIEW Each hazmat employee shall receive general awareness/familiarization training designed to provide familiarity with the requirements of this subchapter, and to enable the employee to recognize and identify hazardous materials consistent with the hazard communication standards of this subchapter. II. 49 CFR (2): Each hazmat employee shall receive function-specific training concerning requirements of this subchapter, or exemptions issued under subchapter A of this chapter, which are specifically applicable to the functions the employee performs. III. 49 CFR (3): Each hazmat employee shall receive safety training concerning- ( i ) Emergency response information required by subpart G of part 172; ( ii ) Measures to protect the employee from the hazards associated with hazardous materials to which they may be exposed in the work place, including specific measures the hazmat employer has implemented to protect employees from exposure; and ( iii ) Methods and procedures for avoiding accidents, such as the proper procedures for handling packages containing hazardous materials. IV. 49 CFR (4): Security awareness training. Each hazmat employee must receive training that provides an awareness of security risks associated with hazardous materials transportation and methods designed to enhance transportation security. This training must also include a component covering how to recognize and respond to possible security threats. New hazmat employees must receive the security awareness training required by this paragraph within 90 days after employment. V. 49 CFR (5): In-depth security training. Each hazmat employee of a person required to have a security plan in accordance with subpart I of this part who handles hazardous materials covered by the plan, performs a regulated function related to the hazardous materials covered by the plan, or is responsible for implementing the plan must be trained concerning the security plan and its implementation Security training must include company security objectives, organizational security structure, specific security procedures, specific security duties and responsibilities for each employee, and specific actions to be taken by each employee in the event of a security breach. VI. 49 CFR : Drivers must be giving not only general awareness/familiarization, function-specific and safety training, but also training on the safe operation of the motor vehicle which they operate or intend to operate and the applicable requirements of the Federal Motor Carrier Safety Regulations. Driver training shall include the requirements of Sec (a) (1-6): ( 1 ) NEI

6 SUBJECT: Time of Lesson: HAZARDOUS MATERIAL CLASSES 35 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 2, Hazardous Material Compliance Pocketbook Objectives: To give the students an understanding of what hazardous substances are and the ability to identify the hazardous material involved in an emergency. LESSON OUTLINE: 8:25 am I. Ask student to give their definition of Hazardous Materials: II. Review the nine different hazard classes of chemicals: A. Class 1 (Explosives) 8:35 am B. Class 2 (Gases) C. Class 3 (Flammable & Combustible Liquids) D. Class 4 (Flammable Solids) E. Class 5 (Oxidizers & Organic Peroxides) F. Class 6 (Poisons) G. Class 7 (Radioactive Materials) H. Class 8 (Corrosives) I. Class 9 (Miscellaneous) III. Discus the D.O.T. General Warning Labeling Guidelines: BREAK 10 minutes IMPORTANT INFORMATION! Have students give examples of different classes of chemicals found in the workplace. NEI ( LP 2 )

7 I. DEFINITION 171.8: HAZARDOUS MATERIAL CLASSES Hazardous Materials: A SUBSTANCE OR MATERIAL WHICH HAS BEEN DETERMINED TO BE CAPABLE OF POSING AN UNREASONABLE RISK TO HEALTH, SAFETY, AND PROPERTY WHEN TRANSPORTED IN COMMERCE AND WHICH HAS BEEN SO DESIGNATED. II. HAZARD MATERIAL CLASSES: Hazardous material shipments are recognizable by entries and the shipper's certification on shipping papers, hazardous material warning labels and markings on the packages. Hazardous materials are grouped into nine categories identified by the United Nations Hazard Class Number System, including: A. C las s 1 (e x p lo s iv e s ) 4 9 C F R D iv id e d in t o s ix d iv is io n s : 1. D iv is io n 1.1 : EPLOSIVES THAT HAVE A MASS EPLOSION HAZARD. E: DYNAMITE, BLACK POWDER. 2. Division 1.2: EPLOSIVES THAT HAVE A PROJECTION HAZARD. E: AERIAL FLARES, DETONATING CORDS. 3. Division 1.3: EPLOSIVES THAT HAVE A FIRE, AND EITHER MINOR BLAST OR PROJECTION HAZARD OR BOTH. E: LIQUID FUELED ROCKET MOTORS. 4. Division 1.4: EPLOSIVE DEVICES THAT PRESENT A MINOR BLAST HAZARD E: LINE THROWING ROCKETS OR PRACTICE AMMUNITION. 5. Division 1.5: VERY INSENSITIVE EPLOSIVES. E: AMMONIUM NITRATE-FUEL OIL MITURES. 6. Division 1.6: ETREMELY INSENSITIVE ARTICLES WHICH DO NOT HAVE A MASS EPLOSION HAZARD. E: NOT OTHERWISE SPECIFIED ( 2 ) NEI

8 SUBJECT: HAZARDOUS MATERIAL CLASSES CONT. Objectives: To give the students an understanding of what hazardous substances are and the ability to identify the hazardous material involved in an emergency. LESSON OUTLINE: I. Ask student to give their definition of Hazardous Materials: II. Review the nine different classes of chemicals: A. Class 1 (Explosives) 8:35 am B. Class 2 (Gases) C. Class 3 (Flammable & Combustible Liquids) D. Class 4 (Flammable Solids) E. Class 5 (Oxidizers & Organic Peroxides) 8:45 am F. Class 6 (Poisons) G. Class 7 (Radioactive Materials) H. Class 8 (Corrosives) I. Class 9 (Miscellaneous) III. Discus D.O.T. General Warning Labeling Guidelines: BREAK 10 minutes IMPORTANT INFORMATION! The following is from the new OSHA CFR (a)(19) and is repeated in : Flammable liquid means any liquid having a flashpoint at or below F (93 C). Flammable liquids are divided into four categories as follows: Category 1, Category 2, Category 3 and Category 4. NEI ( LP 3 )

9 B. Class 2 (gases) 49 CFR Three Divisions: 1. Division 2.1: GASES THAT ARE FLAMMABLE. E: PROPANE OR METHYL CHLORIDE. 2. Division 2.2: GASES THAT ARE NON-FLAMMABLE AND COMPRESSED. E: CARBON DIOIDE OR COMPRESSED NITROGEN. 3. Division 2.3: GASES THAT ARE POISONOUS. E: PHOSPHINE C. Class 3 (flammable and combustible liquids) 49 CFR : 1. Flammable Liquid: SUBSTANCE THAT HAS A FLASH POINT OF NOT MORE THAN F. (DOT DEFINITION) E: GASOLINE 2. Combustible Liquid: SUBSTANCE THAT HAS A FLASH POINT ABOVE F AND BELOW F. (DOT DEFINITION) E: FUEL OIL D. Class 4 (flammable solids) 49 CFR Three Divisions: 1. Division 4.1: SOLIDS THAT ARE FLAMMABLE. E: SULFUR. 2. Division 4.2: MATERIALS THAT ARE SPONTANEOUSLY COMBUSTIBLE. E: CARBON, ACTIVATED. 3. Division 4.3: MATERIAL THAT IS DANGEROUS WHEN WET. E: LITHIUM. E. Class 5 (oxidizers and organic peroxides) 49 CFR Two Divisions: 1. Division 5.1: MATERIALS THAT ARE OIDIZERS. E: HYDROGEN PEROIDE. ( 3 ) NEI

10 SUBJECT: HAZARDOUS MATERIAL CLASSES CONT. Objectives: To give the students an understanding of what hazardous substances are and the ability to identify the hazardous material involved in an emergency. LESSON OUTLINE: I. Ask student to give their definition of Hazardous Materials: II. Review the nine different classes of chemicals: A. Class 1 (Explosives) B. Class 2 (Gases) C. Class 3 (Flammable & Combustible Liquids) D. Class 4 (Flammable Solids) E. Class 5 (Oxidizers & Organic Peroxides) 8:45 am F. Class 6 (Poisons) G. Class 7 (Radioactive Materials) H. Class 8 (Corrosives) I. Class 9 (Miscellaneous) II. Discus D.O.T. General Warning Labeling Guidelines: 9:00 am BREAK 10 minutes 9:10 am IMPORTANT INFORMATION! NEI ( LP 4 )

11 III. 2. Division 5.2: MATERIALS THAT ARE ORGANIC PEROIDE. E: BENZOYL PEROIDE. F. Class 6 (toxics) 49 CFR Two Divisions: 1. Division 6.1: MATERIALS THAT ARE TOIC. E: HYDROGEN CYANIDE, ANHYDROUS. 2. Division 6.2: MATERIALS THAT ARE AN INFECTIOUS SUBSTANCE. E: REGULATED MEDICAL WASTE. G. Class 7 (radioactive material) Subpart I: MATERIAL HAVING A SPECIFIC RADIOACTIVE ACTIVITY GREATER THAN MICROCURIES. E: PLUTONIUM H. Class 8 (corrosives) 49 CFR : MATERIALS THAT CAUSE VISIBLE DESTRUCTION OR IRREVERSIBLE ALTERATION TO HUMAN SKIN OR CORROSION TO STEEL. E: HYDROCHLORIC ACID I. Class 9 (miscellaneous) 49 CFR : MATERIAL WHICH IS A HAZARD, BUT WHICH IS NOT IN ANY OTHER CLASS. E: FORMALDEHYDE DOT GENERAL GUIDELINES FOR WARNING LABELS: Labels can help you identify a hazardous materials shipment and the hazard(s) present. A driver should not accept the shipment unless the required labels are affixed to the packages. A. SHIPPER MUST FURNISH AND ATTACH APPROPRIATE LABEL TO EACH PACKAGE OF HAZARDOUS MATERIAL OFFERED FOR SHIPMENT. B. IF MATERIAL IN A PACKAGE HAS MORE THAN ONE HAZARD CLASSIFICATION THE PACKAGE MUST BE LABELED FOR EACH HAZARD. C. IF MORE THAN ONE LABEL IS INDICATED, THE FIRST ONE LISTED IS THE PRIMARY LABEL. D. RADIOACTIVE MATERIAL REQUIRING LABELING, MUST BE LABELED ON TWO OPPOSITE SIDES OF THE PACKAGE. ( 4 ) NEI

12 SUBJECT: Time of Lesson: CONTAINER MARKINGS 10 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 5 Objectives: To provide students with the information on what type of information can be obtained from the markings that are are on containers. LESSON OUTLINE: 9:10 am I. Explain how to use the markings on containers to help in identifying the material 9:20 am IMPORTANT INFORMATION! NEI ( LP 5 )

13 I. MARKINGS: CONTAINER MARKINGS Package markings by manufactures are significantly different. The following is an example of the amount of information that can be obtained from the manufacturer's marking on the package. U N 1A1/Y1.4/150/83 USA/VL824/1mm USA/RB/10-85RL "1" means a drum "2" means a wooden barrel "3" means a jerrican "4" means a box "5" means a bag "6" means a composite packaging "7" means a pressure receptacles "1" indicates a non-removable head drum "2" indicates a removable head drum "1A1" "A" "B" "C" "D" "F" "G" "H" "L" "M" "N" "P" means steel means aluminum means natural wood means plywood means reconstituted wood means fiberboard means plastic means textile means paper, multi-wall means metal means glass, porcelain or stoneware "" "Y" "Z" "Y1.4" packaging meeting Packing Group I, II and III tests. packaging meeting Packing Group II and III tests. packaging meeting Packing Group III tests. "1.4" is the specific gravity of the material for which the packaging was tested. "150" "83" "USA" "VL824" "1mm" "USA" "RB" "10-85" "R" "L" the test pressure in kpa rounded to the nearest 10 the year of manufacture the country of manufacture the code of the manufacture the minimum thickness of material for metal or plastic drums or jerricans intended for reuse or reconditioning as single containers the country where reconditioning was performed the symbol of the reconditioner the month and year of reconditioning the drum was reconditioned the package successfully passed the leakproofness test ( 5 ) NEI

14 SUBJECT: LOADING AND UNLOADING Time of Lesson: 10 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 6 Objectives: To give the students an understanding of the rules and requirements for loading & unloading hazardous substances. LESSON OUTLINE: 9:20 am Discuss the loading and unloading rules for all Hazardous Materials Shipments as required under 49 CFR :30 am IMPORTANT INFORMATION! NEI ( LP 6 )

15 LOADING AND UNLOADING There are some regulations for the safe and secure loading and unloading of hazardous materials shipments which apply to all hazardous commodities shipments. A. All classes of hazardous materials must be secured against movement in the vehicle. Tanks, barrels, drums, cylinders or other packaging not permanently attached. B. No hazardous materials may be transported in or on any pole trailer. Pole Trailer: Means any motor vehicle which is designed to be drawn by another motor vehicle and attached to the towing motor vehicle by means of a "reach" or "pole" or by being "boomed" or otherwise secured to the towing motor vehicle, for transporting long or irregularly shaped loads such as poles, pipes, or structural members, which generally are capable of sustaining themselves as beams between the supporting connections. C. No smoking while loading or unloading hazardous materials. No person may smoke or carry any lighted smoking material on or within 25 feet of vehicle. D. Keep fire away while loading or unloading hazardous materials. Further, care should be taken to keep all fire sources away from the vehicle. E. Vehicle handbrake must be set while loading or unloading hazardous materials. All precautions should be taken to prevent movement of the vehicle. F. No tools should be used that could damage any package or container. G. Brace containers to prevent relative motion to the vehicle. Containers with valves or other similar fittings must be loaded so that there is minimum likelihood of any damage to them during transportation. H. Shall be no tampering with container or it's contents between point of origin and destination. I. Cargo tank must be attended by a qualified person at all times while being loaded. The person who is responsible for loading the cargo is also responsible for seeing that the vehicle is attended. J. Bonding must first be done to the vehicle to be filled, then to the container from which the flammable liquid will be loaded. Attachment must be done in this order. K. No motor carrier may accept for transportation or transport any goods classed as "Forbidden" in the Hazardous Materials Table. Carrier personnel are also responsible for rejecting packages of hazardous materials which show signs of leakage or other damage. ( 6 ) NEI

16 SUBJECT: Time of Lesson: HAZARDOUS MATERIALS TABLES 30 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 7, Hazardous Material Compliance Pocketbook Objectives: To show students how to use the Hazardous Materials Tables that are found in 49 CFR. LESSON OUTLINE: 9:30 am I. Explain how to use the Segregation Table for hazardous materials to students (d) II. Explain what each symbol in the Segregation Table means 9:40 am III. Discuss with the student the exception for the Compatibility Table and how to use it (f) IV. Give instruction on what each symbol in the table represents V. Discuss with the students the Hazardous Material Table and what information can be obtained from it BREAK 10 minutes IMPORTANT INFORMATION! Have the student use the hazardous Materials Compliance Pocketbook NEI ( LP 7 )

17 HAZARDOUS MATERIALS TABLES I. SEGREGATION TABLE (d): The Hazardous Materials Regulations contain Segregation requirements which indicate which hazardous materials may not be loaded, transported or stored together, except as provided in the following Table: Class or Division Notes gas Zone A 2.3 gas Zone B liquids PGI ZoneA 7 8 liquids only Explosives Explosives Explosives Very insensitive explosives Extremely insensitive explosives Flammable gases Non-toxic, nonflammable gases Poisonous gas Zone A Poisonous gas Zone B Flammable liquids Flammable solids Spontaneously combustible materials Dangerous when wet materials Oxidizers Organic peroxides Poisonous liquids PG 1 Zone A Radioactive materials Corrosive liquids 1.1 and A A A * * * * * * * * * * * * * * * O O O O O O O * * * * * * * * * * O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O II. SEGREGATION SYMBOLS (e): A. = That these materials may not be loaded, transported, or stored together in the same transport vehicle or storage facility during the course of transportation. B. O = That these materials may not be loaded, transported, or stored together in the same transport vehicle or storage facility during the course of transportation unless separated in a manner that commingling of hazardous materials would not occur. C. * = That segregation among different Class 1 (explosive) materials is governed by the compatibility table. D. = That no restrictions apply. F. A = That, notwithstanding the requirements of the letter "", ammonium nitrate (UN 1942 and Ammonium nitrate fertilizer may be loaded or stored with Division 1.1 (class A explosive) or Division 1.5 (blasting agents) materials. ( 7 ) NEI

18 SUBJECT: HAZARDOUS MATERIALS TABLES CONT. Objectives: To show students how to use the Hazardous Materials Tables that are found in 49 CFR. LESSON OUTLINE: 9:40 am I. Explain how to use the Segregation Table for hazardous materials to students (d) II. Explain what each symbol in the Segregation Table means III. Discuss with the student the exception for the Compatibility Table and how to use it (f) IV. Give instruction on what each symbol in the table represents 9:50 am V. Discuss with the students the Hazardous Material Table and what information can be obtained from it BREAK 10 minutes IMPORTANT INFORMATION! Have the student use the hazardous Materials Compliance Pocketbook NEI ( LP 8 )

19 III. COMPATIBILITY TABLE (f): Class 1 (explosive) materials shall not be be loaded, transported, or stored together, except as provided in this section and in accordance with the following Table: Compatibility Group A B C D E F G H J K L N S A B C D E F G H J K L N S (4) 4/ /5 (4) 2 2 4/ /5 4/ /5 4/5 4/5 4/ /5 4/5 4/5 4/5 4/5 4/5 4/5 4/5 4/5 4/5 4/5 IV. COMPATIBILITY TABLE INSTRUCTIONS (g): A. = That no restrictions apply. B. = That explosives of different compatibility groups may not be carried on the same transport vehicle. C. The numbers in the table mean the following: 1 = means an explosive from compatibility group L shall only be carried on the same transport vehicle with an identical explosive. 2 = means any combination of explosives from compatibility groups C, D, or E is assigned to compatibility group E. 3 = means any combination of explosives from compatibility groups C, D, or E with those in compatibility group N is assigned to compatibility group D. 4 = means (g) when transporting detonators. 5 = means Division 1.4S fireworks may not be loaded on the same transport vehicle with Division 1.1 or 1.2 (Class A explosive) materials. 6 = means explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of compatibility groups C, D and E, provided no explosive substance are carried in the same vehicle. ( 8 ) NEI

20 SUBJECT: HAZARDOUS MATERIALS TABLES CONT. Objectives: To show students how to use the Hazardous Materials Tables that are found in 49 CFR. LESSON OUTLINE: I. Explain how to use the Segregation Table for hazardous materials to students (d) II. III. Explain what each symbol in the Segregation Table means Discuss with the student the exception for the Compatibility Table and how to use it (f) IV. Give instruction on what each symbol in the table represents 9:50 am V. Discuss with the students the Hazardous Material Table and what information can be obtained from it :00 am 10:10 am BREAK 10 minutes IMPORTANT INFORMATION! Have the student use the hazardous Materials Compliance Pocketbook NEI ( LP 9 )

21 V. HAZARDOUS MATERIALS TABLE : The Hazardous Materials Table identifies the requirements that apply to each shipment of a hazardous material. The table will help you identify: Column 1 - Symbols: Five symbols showing special conditions placed on hazardous materials: "+" = Fixes proper shipping name, hazard class and packing group without regard to whether the material meets the class, packing group or any other hazard class. "A" = Applies to materials offered or intended for transportation by aircraft unless the material is a hazardous substance or a hazardous waste. "D" = Identifies proper shipping names for describing materials for domestic transportation may be inappropriate for international transportation. "I" = Identifies proper shipping names for describing materials in international transportation. "W" = Applies to materials offered or intended for transportation be vessel unless the material is a hazardous substance or a hazardous waste. Column 2 - Hazardous Material Descriptions: Proper shipping name Column 3 - Hazard Class or Division: In accordance with Definitions Column 4 - Identification Number: UN = Can Ship International Column 5 - Packing Group: NA = Only Ship North America The degree of danger presented by the material: I = Great, II = Medium, III = Minor Column 6 - Labels: Codes for hazard warning labels required for a package Column 7 - Special Provisions: See for meaning and requirements Column 8 - Placard Column: (not part of the Table) Quick indication of the placard required for shipping description Symbols (1) Hazardous materials descriptions and proper shipping names (2) Hazard class or Division (3) Identification Numbers (4) PG (5) Label codes (6) Special provisions (7) Placards Consult regulations (Part 172, Subpart F) *Placard any quantity Accellerene, See p-nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc. Acetal Acetaldehydre A Acetaldehydre ammonia Acetaldehydre oxime UN1088 UN1089 UN1841 UN2332 II I III III 3 IB2, T4, TP A3, B16, T11 TP2, TP7 IB8, 1P6 B1, IB3, T4, TP1 FLAMMABLE FLAMMABLE CLASS 9 FLAMMABLE ( 9 ) NEI

22 SUBJECT: HAZARDOUS MATERIAL EERCISE Time of Lesson: 35 minute Exercise Instructor Training Aids: PowerPoint Program Students Materials: Workbook, Hazardous Material Compliance Pocketbook Objectives: To show students how to use the Hazardous Material Tables LESSON OUTLINE: 10:10 am I. Have students complete the exercise. II. Review the exercise with students 10:45 am IMPORTANT INFORMATION! NEI ( LP 10 )

23 HAZARDOUS MATERIAL EERCISE Using your Hazard Materials Compliance Pocketbook complete the following chart. Material Hazard Class Label Substitution Name(s) ID# RQ Pounds Zinc cyanide 6.1 POISON UN LBS Allyl alcohol 6.1 POISON ( I. H. ) UN LBS Fuel oil, (no 1) 3 FLAMMABLE LIQUID NA-1993 NONE Benzene 3 FLAMMABLE LIQUID UN LBS Lead azide (dry) F O R B I D D E N Spent sulfuric acid 8 CORROSIVE UN-1832 NONE Hydrogen iodide 2.3 POISON GAS UN-2197 NONE Krypton, compressed 2.2 NON-FLAMMABLE GAS UN-1056 NONE White asbestos 9 CLASS 9 UN-2590 NONE Cord, Igniter 1.4G EPLOSIVE 1.4G UN-0066 NONE Lead acetate 6.1 POISON UN LBS Lead nitrate 5.1 OIDIZER UN LBS Mercury 8 CORROSIVE UN LBS Ethyl oxalate 6.1 POISON UN-2525 NONE Diesel fuel 3 NONE NA-1993 NONE Acetone 3 FLAMMABLE LIQUID UN LBS Amyl Acetate 3 FLAMMABLE LIQUID UN LBS Phosgene 2.3 POISON GAS UN LBS Silver Nitrate 5.1 OIDIZER UN LBS ylenes 3 FLAMMABLE LIQUID UN LBS Gasoline 3 FLAMMABLE LIQUID UN-1203 NONE ( 10 ) NEI

24 SUBJECT: Time of Lesson: UNIFORM HAZARDOUS WASTE MANIFEST 55 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 11 Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 10:45 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 10:50 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! It might be a good ideal to have one from your company available. NEI ( LP 11 )

25 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172: UNIFORM HAZARDOUS WASTE MANIFEST AND INSTRUCTIONS (EPA FORM ): On September 5, 2006 EPA revised the Uniform Hazardous Waste Manifest used to track hazardous waste from a generator s site to the site of its disposition. The new Uniform Hazardous Waste Manifest must be used for all hazardous waste shipments. The Uniform Hazardous Waste Manifest, (form and, if necessary, the continuation sheet form A), is a form prepared by all generators who transport, or offer for transport, hazardous waste for off-site treatment, recycling, storage, or disposal. Currently, the manifest is a paper document containing 6 copies of a single form. When completed, it contains information on the type and quantity of the waste being transported, instructions for handling the waste, and signature lines for all parties involved in the disposal process. The manifest is required by both Department of Transportation and EPA. Each party that handles the waste signs the manifest and retains a copy for themselves. This ensures critical accountability in the transportation and disposal processes. Once the waste reaches its destination, the receiving facility returns a signed copy of the manifest to the generator, confirming that the waste has been received by the designated facility. Handlers of waste (generators, or treatment, storage or disposal facilities) must obtain the new forms from any source that has been approved by the EPA Manifest Registry to print and distribute the form. The Uniform Manifest contains 6 copies. ALL COPIES MUST BE LEGIBLE. This form is designed for use on a 12 pitch (elite) typewriter; a firm ball point pen may also be used only if you press down HARD. The 6 copies must be distributed in the following way: ORIGINAL: DESTINATION STATE COPY -- The TSDF will mail to the destination state where the waste was sent (if required). ADEQ does not require the submission of this copy to the state. COPY 2: GENERATOR STATE COPY-- TSDF mails to appropriate state agency (if required). ADEQ does not require the submission of this copy to the state. COPY 3: GENERATOR COPY-- TSDF mails back to the generator completed manifest. COPY 4: TSDF COPY-- TSDF keeps this copy for his records. COPY 5: TRANSPORTER COPY-- The transporter keeps for his records. COPY 6: GENERATOR INITIAL COPY-- The generator keeps once transporter signs off and takes waste. A sample Uniform Hazardous Waste Manifest is located in Appendix A in the back of your student workbook. ( 11 ) NEI

26 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 10:50 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 10:55 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! It might be a good ideal to have one from your company available. NEI ( LP 12 )

27 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172: BR GENERATORS SECTION Item 1. Generator s U.S. EPA Identification Number Enter the generator s U.S. EPA twelve digit identification number, or the State generator identification number if the generator site does not have an EPA identification number. Item 2. Page 1 of Enter the total number of pages used to complete this Manifest (i.e., the first page (EPA Form ) plus the number of Continuation Sheets (EPA Form A), if any). Item 3. Emergency Response Phone Number Enter a phone number for which emergency response information can be obtained in the event of an incident during transportation. The emergency response phone number must: 1. Be the number of the generator or the number of an agency or organization who is capable of and accepts responsibility for providing detailed information about the shipment; 2. Reach a phone that is monitored 24 hours a day at all times the waste is in transportation (including transportation related storage); and 3. Reach someone who is either knowledgeable of the hazardous waste being shipped and has comprehensive emergency response and spill 262 App. I cleanup/incident mitigation information for the material being shipped or has immediate access to a person who has that knowledge and information about the shipment. Note: Emergency Response phone number information should only be entered in Item 3 when there is one phone number that applies to all the waste materials described in Item 9b. If a situation (e.g., consolidated shipments) arises where more than one Emergency Response phone number applies to the various wastes listed on the manifest, the phone numbers associated with each specific material should be entered after its description in Item 9b. Item 4. Manifest Tracking Number This unique tracking number must be pre-printed on the manifest by the forms printer. ( 12 ) NEI

28 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 10:55 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:00 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 13 )

29 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): YZ COMPANY, INC MY STREET ANYTOWN, USA ( 123 ) WE CARRY IT CORP IF THEY CAN'T WE CAN, INC WE HAVE IT NOW, LLC WAY OFF STREET YOUR TOWN, USA GENERATORS (212) SECTION GENERATORS SECTION Item 5. Generator s Mailing Address, Phone Number and Site Address Enter the name of the generator, the mailing address to which the completed manifest signed by the designated facility should be mailed, and the generator s telephone number. Note, the telephone number (including area code) should be the normal business number for the generator, or the number where the generator or his authorized agent may be reached to provide instructions in the event the designated and/or alternate (if any) facility rejects some or all of the shipment. Also enter the physical site address from which the shipment originates only if this address is different than the mailing address. Item 6. Transporter 1 Company Name, and U.S. EPA ID Number Enter the company name and U.S. EPA ID number of the first transporter who will transport the waste. Vehicle or driver information may not be entered here. Item 7. Transporter 2 Company Name and U.S. EPA ID Number If applicable, enter the company name and U.S. EPA ID number of the second transporter who will transport the waste. Vehicle or driver information may not be entered here. If more than two transporters are needed, use a Continuation Sheet(s) (EPA Form A). Item 8. Designated Facility Name, Site Address, and U.S. EPA ID Number Enter the company name and site address of the facility designated to receive the waste listed on this manifest. Also enter the facility s phone number and the U.S. EPA twelve digit identification number of the facility. ( 13 ) NEI

30 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:00 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:05 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 14 )

31 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): AMYL ACETATES UN DM GENERATORS SECTION Item 9. U.S. DOT Description (Including Proper Shipping Name, Hazard Class or Division, Identification Number, and Packing Group) Item 9a. If the wastes identified in Item 9b consist of both hazardous and nonhazardous materials, then identify the hazardous materials by entering an in this Item next to the corresponding hazardous material identified in Item 9b. Item 9b. Enter the U.S. DOT Proper Shipping Name, Hazard Class or Division, Identification Number (UN/NA) and Packing Group for each waste as identified in 49 CFR 172. Include technical name(s) and reportable quantity references, if applicable. NOTE: If additional space is needed for waste descriptions, enter these additional descriptions in Item 27 on the Continuation Sheet (EPA Form A). Also, if more than one Emergency Response phone number applies to the various wastes described in either Item 9b or Item 27, enter applicable Emergency Response phone numbers immediately following the shipping descriptions for those Items. Item 10. Containers (Number and Type) Enter the number of containers for each waste and the appropriate abbreviation from Table I (below) for the type of container. TABLE I. TYPES OF CONTAINERS BA = Burlap, cloth, paper, or plastic bags DT = Dump truck CF = Fiber or plastic boxes, cartons, cases DW = Wooden drums, barrels, kegs CM = Metal boxes, cartons, cases (including roll-offs) HG = Hopper or gondola cars CW = Wooden boxes, cartons, cases TC = Tank cars CY = Cylinders TP = Portable tanks DF = Fiberboard or plastic drums, barrels, kegs TT = Cargo tanks (tank trucks) DM = Metal drums, barrels, kegs ( 14 ) NEI

32 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:05 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:10 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 15 )

33 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): AMYL ACETATES UN DM G GENERATORS SECTION Item 11. Total Quantity Enter, in designated boxes, the total quantity of waste. Round partial units to the nearest whole unit, and do not enter decimals or fractions. To the extent practical, report quantities using appropriate units of measure that will allow you to report quantities with precision. Waste quantities entered should be based on actual measurements or reasonably accurate estimates of actual quantities shipped. Container capacities are generally not acceptable as estimates. Item 12. Units of Measure (Weight/Volume) Enter, in designated boxes, the appropriate abbreviation from Table II (below) for the unit of measure. TABLE II. UNITS OF MEASURE G = Gallons (liquids only) N = Cubic Meters K = Kilograms P = Pounds L = Liters (liquids only) T = Tons (2000 pounds) M = Metric Tons (1000 kilograms) Y = Cubic Yards Note: Tons, Metric Tons, Cubic Meters, and Cubic Yards should only be reported in connection with very large bulk shipments, such as rail cars, tank trucks, or barges. Item 13. Waste Codes Enter up to six federal and state waste codes to describe each waste stream identified in Item 9b. State waste codes that are not redundant with federal codes must be entered here, in addition to the federal waste codes which are most representative of the properties of the waste. ( 15 ) NEI

34 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:10 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:15 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 16 )

35 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): FOR AN EMERGENCY INVOLVING THIS SUBSTANCE, CALL CHEMTREC AT GENERATORS SECTION Item 14. Special Handling Instructions and Additional Information 1. Generators may enter any special handling or shipment-specific information necessary for the proper management or tracking of the materials under the generator s or other handler s business processes, such as waste profile numbers, container codes, bar codes, or response guide numbers. Generators also may use this space to enter additional descriptive information about their shipped materials, such as chemical names, constituent percentages, physical state, or specific gravity of wastes identified with volume units in Item This space may be used to record limited types of federally required information for which there is no specific space provided on the manifest, including any alternate facility designations; the manifest tracking number of the original manifest for rejected wastes and residues that are re-shipped under a second manifest; and the specification of PCB waste descriptions and PCB out-of-service dates required under 40 CFR Generators, however, cannot be required to enter information in this space to meet state regulatory requirements. ( 16 ) NEI

36 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:15 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:20 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 17 )

37 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): JOHN J. JOHNSON John J. Johnson GENERATORS SECTION Item 15. Generator s/offeror s Certifications 1. The generator must read, sign, and date the waste minimization certification statement. In signing the waste minimization certification statement, those generators who have not been exempted by statute or regulation from the duty to make a waste minimization certification under section 3002(b) of RCRA are also certifying that they have complied with the waste minimization requirements. The Generator s Certification also contains the required attestation that the shipment has been properly prepared and is in proper condition for transportation (the shipper s certification). The content of the shipper s certification statement is as follows: I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified, packaged, marked, and labeled/placarded, and are in all respects in proper condition for transport by highway according to applicable international and national governmental regulations. If export shipment and I am the Primary Exporter, I certify that the contents of this consignment conform to the terms of the attached EPA Acknowledgment of Consent. When a party other than the generator prepares the shipment for transportation, this party may also sign the shipper s certification statement as the offeror of the shipment. 2. Generator or Offeror personnel may preprint the words, On behalf of in the signature block or may hand write this statement in the signature block prior to signing the generator/offeror certification, to indicate that the individual signs as the employee or agent of the named principal. Note: All of the above information except the handwritten signature required in Item 15 may be pre-printed. ( 17 ) NEI

38 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:20 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:25 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 18 )

39 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): INTERNATIONAL SHIPMENT SECTION Item 16. International Shipments For export shipments, the primary exporter must check the export box, and enter the point of exit (city and state) from the United States. For import shipments, the importer must check the import box and enter the point of entry (city and state) into the United States. For exports, the transporter must sign and date the manifest to indicate the day the shipment left the United States. Transporters of hazardous waste shipments must deliver a copy of the manifest to the U.S. Customs when importing or exporting the waste across U.S. borders. JIMMY L. LOW Jimmy L. Low TRANSPORTERS SECTION Item 17. Transporters Acknowledgments of Receipt Enter the name of the person accepting the waste on behalf of the first transporter. That person must acknowledge acceptance of the waste described on the manifest by signing and entering the date of receipt. Only one signature per transportation company is required. Signatures are not required to track the movement of wastes in and out of transfer facilities, unless there is a change of custody between transporters. If applicable, enter the name of the person accepting the waste on behalf of the second transporter. That person must acknowledge acceptance of the waste described on the manifest by signing and entering the date of receipt. NOTE: Transporters carrying imports or exports of hazardous waste may also have responsibilities to enter information in the International Shipments Block. See above instructions for Item 16. ( 18 ) NEI

40 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:25 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:30 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 19 )

41 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): N/A OWNERS AND OPERATORS OF TREATMENT, STORAGE, AND DISPOSAL FACILITIES Item 18. Discrepancy Item 18a. Discrepancy Indication Space 1. The authorized representative of the designated (or alternate) facility s owner or operator must note in this space any discrepancies between the waste described on the Manifest and the waste actually received at the facility. Manifest discrepancies are: (1) significant differences (as defined by (b) and (b)) between the quantity or type of hazardous waste designated on the manifest or shipping paper, and the quantity and type of hazardous waste a facility actually receives, (2) rejected wastes, which may be a full or partial shipment of hazardous waste that the TSDF cannot accept, or (3) container residues, which are residues that exceed the quantity limits for empty containers set forth in 261.7(b). 2. For rejected loads and residues ( (d), (e), and (f), or (d), (e), or (f)), check the appropriate box if the shipment is a rejected load (i.e., rejected by the designated and/ or alternate facility and is sent to an alternate facility or returned to the generator) or a regulated residue that cannot be removed from a container. Enter the reason for the rejection or the inability to remove the residue and a description of the waste. Also, reference the manifest tracking number for any additional manifests being used to track the rejected waste or residue shipment on the original manifest. Indicate the original manifest tracking number in Item 14, the Special Handling Block and Additional Information Block of the additional manifests. 3. Owners or operators of facilities located in unauthorized States (i.e., states in which the U.S. EPA administers the hazardous waste management program) who cannot resolve significant differences in quantity or type within 15 days of receiving the waste must submit to their EPA Regional Administrator a letter with a copy of the Manifest at issue describing the discrepancy and attempts to reconcile it ( (c) and (c)). 4. Owners or operators of facilities located in authorized States (i.e., those States that have received authorization from the U.S. EPA to administer the hazardous waste management program) should contact their State agency for information on where to report discrepancies involving significant differences to state officials. ( 19 ) NEI

42 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:30 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:35 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 20 )

43 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): N/A OWNERS AND OPERATORS OF TREATMENT, STORAGE, AND DISPOSAL FACILITIES Item 18. Discrepancy Item 18b. Alternate Facility (or Generator) for Receipt of Full Load Rejections: Enter the name, address, phone number, and EPA Identification Number of the Alternate Facility which the rejecting TSDF has designated, after consulting with the generator, to receive a fully rejected waste shipment. In the event that a fully rejected shipment is being returned to the generator, the rejecting TSDF may enter the generator s site information in this space. This field is not to be used to forward partially rejected loads or residue waste shipments. Item 18c. Alternate Facility (or Generator)Signature.: The authorized representative of the alternate facility (or the generator in the event of a returned shipment) must sign and date this field of the form to acknowledge receipt of the fully rejected wastes or residues identified by the initial TSDF. Item 19. Hazardous Waste Report Management Method Codes: Enter the most appropriate Hazardous Waste Report Management Method code for each waste listed in Item 9. The Hazardous Waste Report Management Method code is to be entered by the first treatment, storage, or disposal facility (TSDF) that receives the waste and is the code that best describes the way in which the waste is to be managed when received by the TSDF. Note: See the following website for more information on the codes used: ( 20 ) NEI

44 SUBJECT: UNIFORM HAZARDOUS WASTE MANIFEST CONT. Objectives: To show students how to fill out and read the Uniform Hazardous Waste Manifest required in 49 CFR 172. LESSON OUTLINE: 11:35 am I. Explain to the student what type of information can found on the Uniform Hazardous Waste Manifest and how to fill one out. 11:40 am Attachment A on page 36 & 37 is a sample form IMPORTANT INFORMATION! NEI ( LP 21 )

45 UNIFORM HAZARDOUS WASTE MANIFEST I. INSTRUCTIONS FOR APPENDI TO PART 172 (CONT.): JANE S. DOE Jane S. Doe OWNERS AND OPERATORS OF TREATMENT, STORAGE, AND DISPOSAL FACILITIES Item 20. Designated Facility Owner or Operator Certification of Receipt (Except As Noted in Item 18a): Enter the name of the person receiving the waste on behalf of the owner or operator of the facility. That person must acknowledge receipt or rejection of the waste described on the Manifest by signing and entering the date of receipt or rejection where indicated. Since the Facility Certification acknowledges receipt of the waste except as noted in the Discrepancy Space in Item 18a, the certification should be signed for both waste receipt and waste rejection, with the rejection being noted and described in the space provided in Item 18a. Fully rejected wastes may be forwarded or returned using Item 18b after consultation with the generator. Enter the name of the person accepting the waste on behalf of the owner or operator of the alternate facility or the original generator. That person must acknowledge receipt or rejection of the waste described on the Manifest by signing and entering the date they received or rejected the waste in Item 18c. Partially rejected wastes and residues must be re-shipped under a new manifest, to be initiated and signed by the rejecting TSDF as offeror of the shipment. ( 21 ) NEI

46 SUBJECT: STRAIGHT BILL OF LADING Time of Lesson: 20 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 22 Objectives: To show students how to find hazardous material information form the shipping papers that are carried on the transport vehicle LESSON OUTLINE: 11:40 am I. Explain to the student what type of information can found on the Straight Bill Of Lading and how to read and understand one. Attachment B on page 35 is a complete form 12:00 pm LUNCH 60 minutes 1:00 pm IMPORTANT INFORMATION! It might be a good ideal to have one from your company available. NEI ( LP 22 )

47 STRAIGHT BILL OF LADING Whenever a hazardous material is transported, its description must appear on the shipping paper. The description must adhere to these requirements. (See Appendix B for a Full Sample Form) 1. If a hazardous material and a non-hazardous material are described on the same shipping paper, the hazardous material must be: A. Listed First B. Shown In A Contrasting Color ( Highlighted On Multi-Page Or A Reproduced Form ) C. Identified With An "" Or "RQ" Before The Proper Shipping Name In The Column Marked "HM". 2. The required shipping description on a shipping paper must be legible and printed in English. 3. Unless otherwise permitted, the required shipping description may not contain any code or abbreviation. 4. Unless otherwise permitted, additional information must be placed after the basic description required. 5. If more than one page is required, the first page must indicate such, (for example, Page 1 of 4). 6. Shipping paper must contain an emergency response telephone number. 7. Shipping paper must contain shipper's certification. WE CARRY IT CORP. PH: ( 111 ) DUMPIT ROAD WASTETOWN, USA AMYL ACETATES - DM 3 UN1104 III 95 gal 2 The shipping description of a hazardous material on the shipping paper must include: 1. The proper shipping name prescribed for the material in column 2 of the table; 2. The hazard class or division prescribed for the material as shown in column 3 of the table; 3. The identification number prescribed for the material as shown in column 4 of the table; 4. The packing group in Roman numerals, as designated for the hazardous material in Column 5 of the Table. 5. Except for empty packaging, the total quantity, including the unit of measurement, of the hazardous material covered by the description (e.g., "800 lbs", "55 gal.", "3629 kg", or "208 L"). ( 22 ) NEI

48 SUBJECT: 704 MARKING SYSTEM Time of Lesson: 20 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 23, 704 Marking System Wallet Card Objectives: To give the students an understanding of how to recognize the presence of hazardous substances in an emergency situation. LESSON OUTLINE: 1:00 pm I. Discuss how the 704 Marking System works II. Have the students give the answers for the exercise 1:20 pm IMPORTANT INFORMATION! Give the 704 marking system wallet cards to the students. NEI ( LP 23 )

49 704 MARKING SYSTEM NFPA 704, Standard System for the Identification of the Hazards of Materials for Emergency Response, was developed as a manual by the Sectional Committee on Classification, Labeling and Properties of Flammable Liquids of the NFPA Committee on Flammable Liquids starting in Its first adoption as a guide occurred in 1961, with regular revisions being adopted through In 1990 it became an NFPA standard, and extensive quantitative health hazard rating criteria were introduced. The purpose of the standard, as originally conceived, is to safeguard the lives of those individuals who respond to emergencies occurring in an industrial plant or storage location, or other location where relatively large quantities of chemicals are used, and where the hazards of materials are not readily apparent. I. HAZARDS: A. HEALTH B. FLAMMABILITY C. REACTIVITY D. SPECIAL NOTES II. COLORS: A. BLUE B. RED C. YELLOW D. WHITE III. NUMBERS: A. 4 = ETREME B. 3 = HIGH C. 2 = MODERATE D. 1 = SLIGHT E. 0 = LEAST IV. SPECIAL NOTES: A. W = REACTIVE WITH WATER B. OY = OIDIZING AGENT C. COR = CORROSIVE MATERIAL D. ALK = ALKALI E. ACID = ACIDIC MATERIAL V. EERCISE: List the most serious hazard for each substance shown W 1 A. FLAMMABILITY B. WATER REACTIVE ( 23 ) NEI

50 SUBJECT: HAZARD COMMUNICATION Time of Lesson: 30 minutes Instructor Training Aids: PowerPoint Program Student Materials: Workbook Page 24, Company Safety Data Sheet's Objectives: To explain the importance of the Hazard Communication standard and the requirements that are stated in it. To give the students an understanding of how to use SDS's to aid in identifying and realizing the need for additional support when in contact with Hazardous Materials. LESSON OUTLINE: 1:20 pm I. Explain to students the purpose of the standard 1:30 pm II. Explain the two types of hazards presented by a chemical III. IV. Explain to students the items excluded from the standard Discuss the Safety Data Sheets requirements & elements V. Explain the requirements for Container Labels BREAK 10 minutes Show "First On The Scene" Video 30 Minutes IMPORTANT INFORMATION! NEI ( LP 24 )

51 HAZARD COMMUNICATION I. PURPOSE OF 29 CFR IS TO: A. ENSURE THAT THE HAZARDS OF ALL CHEMICALS PRODUCED OR IMPORTED HAVE BEEN CLASSIFIED; B. ENSURE THAT THE INFORMATION CONCERNING THEIR HAZARDS ARE TRANSMITTED TO BOTH EMPLOYEE'S AND EMPLOYER'S; C. ENSURE EMPLOYERS ADDRESS FIVE MAJOR AREAS: 1. HAZARD CLASSIFICATION (d) The employer should evaluate all chemical products that are used by employees in carrying out their responsibilities to determine if those products are hazardous. 2. WRITTEN HAZARD COMMUNICATION PROGRAM (e) This requirement of the standard is for the company to provide information concerning the location and availability of the company's written hazard communication program. The hazard communication program should include a list of all hazardous chemicals present in the workplace. 3. CONTAINER LABELING (f) If a hazard evaluation reveals a potential for a health or physical hazard, an appropriate warning label must appear on or be attached to the container. 4. SAFETY DATA SHEET USE (g) This is a document describing the results of the health and physical hazard evaluation the manufacturer of the product has performed. A company must have an SDS for each chemical in the workplace. HazCom Training Program 5. EMPLOYEE TRAINING AND INFORMATION (h) This requirement of the standard helps to ensure your health and safety while working with hazardous materials. (f) "Labels and other forms of warning. (g) "Material safety data sheets. (h) "Employee information and training." ( 24 ) NEI

52 SUBJECT: HAZARD COMMUNICATION CONT. Objectives: To explain the importance of the Hazard Communication standard and the requirements that are stated in it. To give the students an understanding of how to use SDS's to aid in identifying and realizing the need for additional support when in contact with Hazardous Materials. LESSON OUTLINE: I. Explain to students the purpose of the standard 1:30 pm II. Explain the two types of hazards presented by a chemical III. Explain to students the items excluded from the standard 1:40 pm IV. Discuss the Safety Data Sheets requirements & elements V. Explain the requirements for Container Labels BREAK 10 minutes Show "First On The Scene" Video 30 Minutes IMPORTANT INFORMATION! NEI ( LP 25 )

53 II. PRIMARY CHEMICAL HAZARDS: The current HCS has specific criteria for each health and physical hazard, along with detailed instructions for hazard evaluation and determinations as to whether mixtures or substances are covered. A. "Health hazard" means a chemical which is classified as posing one of the following hazardous effects: acute toxicity (any route of exposure); skin corrosion or irritation; serious eye damage or eye irritation; respiratory or skin sensitization; germ cell mutagenicity; carcinogenicity; reproductive toxicity; specific target organ toxicity (single or repeated exposure); or aspiration hazard. The criteria for determining whether a chemical is classified as a health hazard are detailed in Appendix A to Health Hazard Criteria. B. "Physical hazard" means a chemical that is classified as posing one of the following hazardous effects: explosive; flammable (gases, aerosols, liquids, or solids); oxidizer (liquid, solid or gas); self-reactive; pyrophoric (liquid or solid); self-heating; organic peroxide; corrosive to metal; gas under pressure; or in contact with water emits flammable gas. See Appendix B to Physical Hazard Criteria. III. ECLUDED FROM THE STANDARD 29 CFR (b)(6): The following items are excluded from this standard; however, they may be regulated under a different regulation: A. HAZARDOUS WASTE REGULATED BY THE EPA ( (b)(6)(i)-(ii) ) B. TOBACCO OR TOBACCO PRODUCTS ( (b)(6)(iii) ) C. UNTREATED WOOD OR WOOD PRODUCTS ( (b)(6)(iv) ) D. FOOD OR ALCOHOLIC BEVERAGES ( (b)(6)(vi) ) E. DRUGS FOR PERSONAL CONSUMPTION ( (b)(6)(vii) ) F. COSMETICS FOR PERSONAL CONSUMPTION ( (b)(6)(viii) ) ( 25 ) NEI

54 SUBJECT: HAZARD COMMUNICATION CONT. Objectives: To explain the importance of the Hazard Communication standard and the requirements that are stated in it. To give the students an understanding of how to use SDS's to aid in identifying and realizing the need for additional support when in contact with Hazardous Materials. LESSON OUTLINE: I. Explain to students the purpose of the standard II. Explain the two types of hazards presented by a chemical III. Explain to students the items excluded from the standard 1:40 pm IV. Discuss the Safety Data Sheets requirements & elements V. Explain the requirements for Container Labels 1:50 pm BREAK 10 minutes Show "First On The Scene" Video 30 Minutes IMPORTANT INFORMATION! Stress the need for the students to find out where the SDS's are for their work location. NEI ( LP 26 )

55 IV. SAFETY DATA SHEETS (SDS): The Hazard Communication Standard (HCS) (29 CFR (g)), requires that the chemical manufacturer, distributor, or importer provide Safety Data Sheets (SDSs) (formerly MSDSs or Material Safety Data Sheets) for each hazardous chemical to downstream users to communicate information on these hazards. The information contained in the SDS is largely the same as the MSDS, except now the SDSs are required to be presented in a consistent user-friendly, 16- section format. Sections 1 through 8 contain general information about the chemical. Sections 9 through 11 and 16 contain other technical and scientific information. The SDS must also state that no applicable information was found when the preparer does not find relevant information for any required element. The SDS must also contain Sections 12 through 15, to be consistent with the UN Globally Harmonized System of Classification and Labeling of Chemicals (GHS), but OSHA will not enforce the content of these sections because they concern matters handled by other agencies. A brief description of all 16 sections of the SDS is presented here: Section 1: IDENTIFICATION This section identifies the chemical on the SDS as well as the recommended uses. It also provides the essential contact information of the supplier. Section 2: HAZARD(S) IDENTIFICATION This section identifies the hazards of the chemical presented on the SDS and the appropriate warning information associated with those hazards. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS This section identifies the ingredient(s) contained in the product indicated on the SDS, including impurities and stabilizing additives. This section includes information on substances, mixtures, and all chemicals where a trade secret is claimed. ( 26 ) NEI

56 SUBJECT: HAZARD COMMUNICATION CONT. Objectives: To explain the importance of the Hazard Communication standard and the requirements that are stated in it. To give the students an understanding of how to use SDS's to aid in identifying and realizing the need for additional support when in contact with Hazardous Materials. LESSON OUTLINE: I. Explain to students the purpose of the standard II. Explain the two types of hazards presented by a chemical III. Explain to students the items excluded from the standard 1:40 pm IV. Discuss the Safety Data Sheets requirements & elements V. Explain the requirements for Container Labels 1:50 pm BREAK 10 minutes Show "First On The Scene" Video 30 Minutes IMPORTANT INFORMATION! Stress the need for the students to find out where the SDS's are for their work location. NEI ( LP 27 )

57 III. SAFETY DATA SHEETS (SDS) CONT.: Section 4: FIRST-AID MEASURES This section describes the initial care that should be given by untrained responders to an individual who has been exposed to the chemical. Section 5: FIRE-FIGHTING MEASURES This section provides recommendations for fighting a fire caused by the chemical. Section 6: ACCIDENTAL RELEASE MEASURES This section provides recommendations on the appropriate response to spills, leaks, or releases, including containment and cleanup practices to prevent or minimize exposure to people, properties, or the environment. It may also include recommendations distinguishing between responses for large and small spills where the spill volume has a significant impact on the hazard. Section 7: HANDLING AND STORAGE This section provides guidance on the safe handling practices and conditions for safe storage of chemicals. Section 8: EPOSURE CONTROL/PERSONAL PROTECTION This section indicates the exposure limits, engineering controls, and personal protective measures that can be used to minimize worker exposure. Section 9: PHYSICAL AND CHEMICAL PROPERTIES This section identifies physical and chemical properties associated with the substance or mixture. Section 10: STABILITY AND REACTIVITY This section describes the reactivity hazards of the chemical and the chemical stability information. This section is broken into three parts: reactivity, chemical stability, and other. ( 27 ) NEI

58 SUBJECT: HAZARD COMMUNICATION CONT. Objectives: To explain the importance of the Hazard Communication standard and the requirements that are stated in it. To give the students an understanding of how to use SDS's to aid in identifying and realizing the need for additional support when in contact with Hazardous Materials. LESSON OUTLINE: I. Explain to students the purpose of the standard II. Explain the two types of hazards presented by a chemical III. Explain to students the items excluded from the standard 1:40 pm IV. Discuss the Safety Data Sheets requirements & elements V. Explain the requirements for Container Labels 1:50 pm BREAK 10 minutes Show "First On The Scene" Video 30 Minutes IMPORTANT INFORMATION! Stress the need for the students to find out where the SDS's are for their work location. NEI ( LP 28 )

59 III. SAFETY DATA SHEETS (SDS) CONT.: Section 11: TOICOLOGICAL INFORMATION This section identifies toxicological and health effects information or indicates that such data are not available. Section 12: ECOLOGICAL INFORMATION (non-mandatory) This section provides information to evaluate the environmental impact of the chemical(s) if it were released to the environment. Section 13: DISPOSAL CONSIDERATIONS (non-mandatory) This section provides guidance on proper disposal practices, recycling or reclamation of the chemical(s) or its container, and safe handling practices. To minimize exposure, this section should also refer the reader to Section 8 (Exposure Controls/Personal Protection) of the SDS. Section 14: TRANSPORT INFORMATION (non-mandatory) This section provides guidance on classification information for shipping and transporting of hazardous chemical(s) by road, air, rail, or sea. Section 15: REGULATORY INFORMATION (non-mandatory) This section identifies the safety, health, and environmental regulations specific for the product that is not indicated anywhere else on the SDS. Section 16: OTHER INFORMATION This section indicates when the SDS was prepared or when the last known revision was made. The SDS may also state where the changes have been made to the previous version. You may wish to contact the supplier for an explanation of the changes. Other useful information also may be included here. Employers must ensure that the SDSs are readily accessible to employees for all hazardous chemicals in their workplace. For example, employers may keep the SDSs in a binder or on computers as long as the employees have immediate access to the information without leaving their work area when needed and a back-up is available for rapid access to the SDS in the case of a power outage or other emergency. ( 28 ) NEI

60 SUBJECT: HAZARD COMMUNICATION CONT. Objectives: To explain the importance of the Hazard Communication standard and the requirements that are stated in it. To give the students an understanding of how to use SDS's to aid in identifying and realizing the need for additional support when in contact with Hazardous Materials. LESSON OUTLINE: I. Explain to students the purpose of the standard II. Explain the two types of hazards presented by a chemical III. Explain to students the items excluded from the standard 1:40 pm IV. Discuss the Safety Data Sheets requirements & elements V. Explain the requirements for Container Labels 1:50 pm BREAK 10 minutes 2:00 pm Show "First On The Scene" Video 30 Minutes 2:30 pm IMPORTANT INFORMATION! Stress the need for the students to find out where the SDS's are for their work location. NEI ( LP 29 )

61 V. CONTAINER LABELS: OSHA has updated the requirements for labeling of hazardous chemicals under its Hazard Communication Standard (HCS). As of June 1, 2015, all labels will be required to have the following: Product Identifier Supplier Identifier Chemical Identity Hazard Pictograms Signal Words Hazard Statements Precautionary Information A sample revised HCS label, identifying the required label elements, is shown below. Supplemental information can also be provided on the label as needed. ( 29 ) NEI

62 SUBJECT: EMERGENCY RESPONSE GUIDEBOOK Time of Lesson: 30 minute Lecture & Exercise Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 30, Emergency Response Guidebook Objectives: To give the students an understanding of how to use the Emergency Response Guidebook as a guide to protecting themselves and the public. LESSON OUTLINE: 2:30 pm I. Review the 5 sections of the Emergency Response Guidebook II. Explain the three steps on how to use the book 2:45 pm III. Have the students complete the exercise then review it IMPORTANT INFORMATION! Have the students use their book. NEI ( LP 30 )

63 EMERGENCY RESPONSE GUIDEBOOK The Emergency Response Guidebook is primarily a guide to aid first responders in quickly identifying the specific or generic hazards of the material(s) involved in an incident, and protect themselves and the general public during the initial response phase of the incident. I. SECTIONS: COLOR DESCRIPTION A. WHITE TABLE OF PLACARDS Guide numbers are circled at the top of the placards class. B. YELLOW CHEMICALS BY ID # (NUMERICAL ORDER) Use this section if only the chemicals ID number is known. C. BLUE CHEMICALS BY NAME (ALPHABETICAL) Use this section if the chemicals name is known. D. ORANGE GUIDE SECTIONS Use this section to find out initial information in an emergency. II. E. GREEN ISOLATION DISTANCE / WATER REACTIVE Use this section if the chemicals are highlighted in yellow or blue. HOW TO USE THE GUIDEBOOK: The following steps are used in the guidebook during an incident: STEP 1 = STEP 2 = STEP 3 = IDENTIFY THE MATERIAL (BY THE NAME, ID#, OR PLACARD). LOOK UP THE MATERIAL'S 3-DIGIT GUIDE NUMBER. TURN TO THE NUMBERED GUIDE AND READ CAREFULLY. GASOLINE UN 1203 ( 30 ) NEI

64 SUBJECT: EMERGENCY RESPONSE GUIDEBOOK CONT. Objectives: To give the students an understanding of how to use the Emergency Response Guidebook as a guide to protecting themselves and the public. LESSON OUTLINE: I. Review the 5 sections of the Emergency Response Guidebook II. Explain the three steps on how to use the book 2:45 pm III. Have the students complete the exercise then review it 3:00 pm BREAK 10 minutes 3:10 pm IMPORTANT INFORMATION! Have the students use their book. NEI ( LP 31 )

65 III. EERCISE: Fill in the blanks using the Emergency Response Guidebook. Provide either the product name or ID number, the guide number, and the inital isolation distance for a small spill (when highlighted), if available. UN 1104 HEANES AMYL ACETATE ID 1208 GUIDE 143 USE GUIDE FEET GUIDE FEET 150 FT. LIQUIDS 75 FT. SOLIDS ARSINE UN 2553 ID GUIDE METERS 500 FEET GUIDE FT. LIQUIDS 75 FT. SOLIDS NOT LISTED USE GUIDE FEET UN PENTOL GUIDE FT. LIQUIDS 75 FT. SOLIDS DIMETHYL ETHER GUIDE FT. ID 2705-GUIDE 153P 150 FT. LIQUIDS ( 31 ) 75 FT. SOLIDS NEI

66 SUBJECT: PERSONAL PROTECTIVE EQUIPMENT Time of Lesson: 30 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 32 Objectives: To explain to students how to select and use proper personal protective equipment provided to them. LESSON OUTLINE: 3:10 pm I. Discuss with students the protection that PPE affords II. Discuss the three types of protective clothing 3:25 pm III. Discuss the three types of respiratory protection IV. Review with students the levels of protection IMPORTANT INFORMATION! NEI ( LP 32 )

67 PERSONAL PROTECTIVE EQUIPMENT The purpose of personal protective equipment is to shield or isolate individuals from the chemical, physical, and biologic hazards that they may encounter. I. SELECTION OF PROTECTION: Careful selection and use of adequate PPE should protect the following: A. RESPIRATORY SYSTEM E. HANDS B. SKIN F. FEET C. EYES G. BODY/HEAD D. FACE H. HEARING Personal Protective Equipment (PPE) includes both Chemical Protective Clothing (CPC) and Respiratory Protection. II. PROTECTIVE CLOTHING: Protective clothing is designed to protect the wearer from heat and/or hazardous materials contacting the skin or eyes. Protective clothing is divided into three types: A. STRUCTURAL FIRE FIGHTING PROTECTIVE CLOTHING Configured as a coat and trousers, or as a coverall, and designed to provide protection to the fire fighter's body. B. CHEMICAL PROTECTIVE CLOTHING Designed and intended to provide protection, generally, against chemical exposure. Clothing appropriate for an incident is greatly dependent on the types of hazards that are present. C. HIGH TEMPERATURE PROTECTIVE CLOTHING There is no NFPA standard on high temperature protective clothing. ( 32 ) NEI

68 SUBJECT: PERSONAL PROTECTIVE EQUIPMENT CONT. Objectives: To explain to students how to select and use proper personal protective equipment provided to them. LESSON OUTLINE: I. Discuss with students the protection that PPE should afford II. Discuss the three types of protective clothing 3:25 pm III. Discuss the three types of respiratory protection IV. Review with students the levels of protection 3:40 pm IMPORTANT INFORMATION! NEI ( LP 33 )

69 III. RESPIRATORY PROTECTION: Equipment designed to protect the wearer from the inhalation of contaminants. Respiratory protection is divided into three types: A. SELF-CONTAINED BREATHING APPARATUS ( SCBA ) A respirator worn by the user that supplies a respirable atmosphere that is either carried in or generated by the apparatus. B. SUPPLIED AIR RESPIRATORS ( SAR ) Supplies breathing air from a source located at some distance from the user and connected to the user by an air-line hose. C. AIR PURIFYING RESPIRATORS ( APR ) Passes ambient air through a filtering or absorbing device prior to inhalation by the user. They do not have a separate air supply. Inhalation of toxics is one of the principal causes of serious injury to responders, so respiratory protection is of the utmost importance. IV. LEVELS OF PROTECTION: Personal protective equipment is divided into four categories based on the degree of protection afforded. A. LEVEL A Selected when the greatest level of skin, respiratory, and eye protection is required. B. LEVEL B Selected when the highest level of respiratory protection is necessary but a lesser level of skin protection is needed. C. LEVEL C Concentration(s) and type(s) of airborne substance is known and the criteria for using air purifying respirators are met. D. LEVEL D A work uniform affording minimal protection, used for nuisance contamination only. The selection of Personal Protective Equipment should be based on the hazardous materials and/or conditions present and be appropriate for the hazards encountered. ( 33 ) NEI

70 SUBJECT: HAZARDOUS MATERIALS DEFINITIONS Time of Lesson: 25 minutes Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 34 Objectives: To give students an understanding of basic hazardous material terms they may encounter while review different types of reference sources. LESSON OUTLINE: 3:40 pm Review hazardous materials terms with students 4:05 pm BREAK 10 minutes IMPORTANT INFORMATION! TAKE A LOOK AT YOUR TIME: If you are running out of time, take less time going over this information. If you need to add more time, go over this information in detail. NEI ( LP 34 )

71 HAZARD COMMUNICATION GLOSSARY ACUTE EFFECT - An adverse effect on a human or animal, with symptoms developing rapidly and quickly becoming a crisis. See "Chronic Effect". ANTIDOTE - An agent that neutralizes or counteracts the effects of a poison. ASPHYIANTS - A chemical gas or vapor that can cause unconsciousness or death by suffocation. Simple asphyxiates, such as nitrogen, either use up or displace oxygen in the air. Chemical asphyxiates, such as carbon monoxide, interfere with the body's ability to receive or use an adequate supply of oxygen. BOILING POINT - The temperature at which liquid changes to a vapor. Expressed in degrees Fahrenheit at sea level pressure. Flammable materials with low boiling points generally present special fire hazards. BURNBACK - The distance a flame will travel from the ignition source back to the aerosol container. C.A.S. NUMBER - Chemical Abstracts Service, a service of the American Chemical Society, identifies particular chemicals with a number. CARCINOGEN - A chemical is considered to be a carcinogen if it is a substance or agent that may cause cancer in humans or animals. CHEMICAL - An element, chemical compound or mixture of elements and/or compounds. CHEMICAL FAMILY - Agroup of compounds with related chemical and physical properties, such as ketone or aldehyde family. CHEMICAL NAME - The scientific designation of a chemical in accordance with the naming system developed by the International Union of Pure and Applied Chemistry. CHRONIC EFFECT - An adverse effect on an animal or human. Symptoms develop slowly over a long period of time or recur frequently. CARBON DIOIDE - (CO 2 ) Aheavy, colorless, nonflammable and relatively nontoxic gas. Produced by the combustion and decomposition of organic substances and as a by-product of many chemical processes. Also used as a fire fighting agent. COMBUSTIBLE - A substance capable of fueling a fire. According to DOT, any liquid having a flash point at or above 140 o F and less than 200 o F is a combustible liquid. CONCENTRATION - The amount of a substance in a stated unit of mixture or solution. For example, 5 parts (of acetone) per million (parts air). See PPM CORROSIVE - Asubstance that, according to the DOT, causes visible destruction or permanent changes in human skin tissue at the site of contact. Or, a liquid that has a severe corrosive rate on steel. DECOMPOSITION - The breakdown of a chemical or substance into different parts or simpler compounds. Decomposition can occur due to heat, chemical reaction, decay, etc. DEFATTING - The removal of natural oils from the skin by fat dissolving solvent. DERMATITIS - An inflammation of the skin. D.O.T. - The U.S. Department of Transportation regulates the transportation of materials. EMULSION - A stable mixture of two or more immiscible liquids held in suspension by small percentages of substances called emulsifiers. EVAPORATION RATE - The rate at which a material is converted to vapor (evaporates) at a given temperature and pressure when compared to the evaporation rate of a given substance. For example, this MSDS shows n-buac (normal butyl acetate) as a given substance. EPOSURE - Subjection to a hazardous chemical through any route of entry (inhalation, ingestion, injection, and absorption). FLAME ETENSION - The distance a flame will travel from the aerosol container when exposed to an ignition source. FLAMMABLE - A material that is easily ignited and burns very rapidly. FLAMMABLE LIQUID - As defined by DOT, any liquid with a flash point below 140 o F. FLASH POINT - The minimum temperature at which a liquid will give off enough flammable vapor just above the surface to ignite in the presence of an ignition source. HAZARDOUS CHEMICAL - Any chemical that is a physical or health hazard. HEALTH HAZARD - Means a chemical which is classified as posing one of the following hazardous effects: acute toxicity (any route of exposure); skin corrosion or irritation; serious eye damage or eye irritation; respiratory or skin sensitization; germ cell mutagenicity; carcinogenicity; reproductive toxicity; specific target organ toxicity (single or repeated exposure); or aspiration hazard. IGNITABLE - Asolid, liquid, or compressed gas that has a flash point of less than 140 o F. Capable of being set on fire. INCOMPATIBLE - The term used for two substances to indicate that one material cannot be mixed with the other without the possibility of a dangerous reaction. INGESTION - Taking a substance into the body through the mouth. INHALATION - The breathing of an airborne substance into the body (lungs), through the nose, mouth and breathing passages. May be in the form of a gas, vapor, fume, mist or dust. IRRITANT - A substance that produces an irritating effect when it contacts the skin, eyes, nose or respiratory system. ( 34 ) NEI

72 SUBJECT: HAZARDOUS MATERIALS DEFINITIONS CONT. Objectives: To give students an understanding of basic hazardous material terms they may encounter while review different types of reference sources. LESSON OUTLINE: 3:40 pm Review hazardous materials terms with students 4:05 pm BREAK 10 minutes 4:15 pm IMPORTANT INFORMATION! TAKE A LOOK AT YOUR TIME: If you are running out of time, take less time going over this information. If you need to add more time, go over this information in detail. NEI ( LP 35 )

73 LOWER EPLOSIVE LIMIT - (LEL) The lowest concentration of a substance that will produce a fire or flash when an ignition source is present. It is expressed as a percent of vapor or gas in the air by volume. At concentrations below the LEL, the mixture is too "lean" to burn. MELTING POINT - The temperature at which a solid substance changes to a liquid. MITURE - Any combination of two or more chemicals if the combination is not, in whole or in part, the result of a chemical reaction. MUTAGEN - Asubstance or agent capable of changing the genetic material of a living cell. N/A - An abbreviation for Not Applicable. NARCOSIS - Stupor or unconsciousness caused by exposure to a chemical. NIOSH - The National Institute for Occupational Safety and Health is a federal agency that trains occupational health and safety professionals, conducts research and tests and certifies respirators, etc. OSHA - The Occupational Safety and Health Administration is a federal agency that publishes and enforces health and safety regulations for most businesses and industries. OIDIZER - A chemical that initiates or promotes combustion in other materials, thereby causing fire either of itself or through the release of oxygen or other gases. PERMISSIBLE EPOSURE LIMIT - (PEL) An exposure limit established by OSHA as a legal standard. May be a timeweighted average (TWA) limit or a minimum concentration exposure limit. ph - Value that represents the acidity or alkalinity of an aqueous (water-based) solution. PHYSICAL HAZARD - Means a chemical that is classified as posing one of the following hazardous effects: explosive; flammable (gases, aerosols, liquids, or solids); oxidizer (liquid, solid or gas); self-reactive; pyrophoric (liquid or solid); self-heating; organic peroxide; corrosive to metal; gas under pressure; or in contact with water emits flammable gas. PARTS PER MILLION (PPM) - Aunit for measuring the concentration of a gas or vapor in contaminated air. Also used to indicate the concentration of a particular substance in a liquid or solid. SPECIFIC GRAVITY - The weight of a material compared to the weight of an equal volume of water; an expression of the density (or heaviness) of the material. Insoluble materials with specific gravity less than 1 will float, an important consideration for fire suppression and spill clean up. TERATOGEN - Asubstance or agent to which exposure of a pregnant female can cause malformations in the fetus. THRESHOLD LIMIT VALUE (TLV) - Aterm used to express the airborne concentration of a material to which nearly all persons can be exposed day after day without adverse effects. TOIN - A substance that is poisonous to varying degrees. UPPER EPLOSIVE LIMIT (UEL) - The highest concentration of a substance that will burn or explode when an ignition source is present. Expressed in percent of vapor or gas in the air by volume. UNSTABLE - Achemical that in the pure state, will vigorously polymerize, decompose, condense, or become selfreactive under conditions of shock, pressure or temperature. VAPOR - The gaseous form of substances that are usually liquid or solid. VAPOR DENSITY - The weight of a vapor or gas compared to the weight of an equal volume of air. An expression of density of the vapor or gas. Materials lighter than air have vapor densities less than 1. Lighter materials tend to rise and dissipate. Heavier vapors are likely to concentrate in low places where they may create fire or health hazards. VAPOR PRESSURE - The pressure exerted by a saturated vapor above its own liquid in a closed container. Vapor pressure is usually expressed as pounds per square inch, but on MSDS's is in millimeters of mercury (mmhg) at 68 o F. The lower the boiling point of a substance, the higher its vapor pressure. VISCOSITY - A fluid's internal resistance to flow. VOLATILE - The tendency or ability of a liquid to vaporize. Liquids such as alcohol or gasoline are volatile because they have a tendency to evaporate quickly. WATER-REACTIVE - A chemical that reacts with water to release a gas that is either flammable or presents a health hazard. POLYMERIZATION - Achemical reaction in which one or more small molecules combine to form larger molecules. A hazardous polymerization is a reaction that takes place at a rate that releases large amounts of energy. REACTIVITY - A substance's tendency to undergo a chemical reaction or change that may result in dangerous side effects, such as explosion, burning and corrosive or toxic emissions. RESPIRATOR - A device that is designed to protect the wearer from inhaling harmful contaminants. SENSITIZER - A substance that may cause no reaction in a person during initial exposure, but to which further exposure will cause an allergic response. SOLUBILITY - The percentage of a material (by weight) that will dissolve in water at a specified temperature. ( 35 ) NEI

74 Supplemental information to be used at the Instructor's discretion. Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 36 NOTE TO INSTRUCTOR: Have a copy of your company's form available NEI ( LP 36 )

75 Attachment " A " UNIFORM HAZARDOUS WASTE MANIFEST ( 36 ) NEI

76 Supplemental information to be used at the Instructor's discretion. Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 37 NOTE TO INSTRUCTOR: Have a copy of your company's form available NEI ( LP 37 )

77 Attachment "A " UNIFORM HAZARDOUS WASTE MANIFEST CONTINUATION SHEET ( 37 ) NEI

78 Supplemental information to be used at the Instructor's discretion. Instructor Training Aids: PowerPoint Program Students Materials: Workbook Page 38 NOTE TO INSTRUCTOR: Have a copy of your company's form available NEI ( LP 38 )

79 Attachment " B " STRAIGHT BILL OF LADING ( 38 ) NEI