Supporting Information. for. Advanced Materials, adma Wiley-VCH 2007
|
|
- Jared Davis
- 6 years ago
- Views:
Transcription
1 Supporting Information for Advanced Materials, adma Wiley-VCH Weinheim, Germany
2 Supporting Information Oligo(p-phenylene vinylene)s as a New Class of Piezochromic Fluorophores Jill Kunzelman, Maki Kinami, Brent R. Crenshaw, John D. Protasiewicz, and Christoph Weder* Department of Macromolecular Science and Engineering and Department of Chemistry, Case Western Reserve University 2100 Adelbert Road, Cleveland, Ohio , USA Materials. All fluorophores were prepared as described before (C. Löwe, C. Weder, Adv. Mater. 2002, 14, 1625; M. Kinami, B. R. Crenshaw and C. Weder, Chem. Mater. 2006, 18, 946), with the only modification that C18-YB was recrystallized from 1-butanol. Optical Spectroscopy. Fluorescence spectra were acquired on a SPEX Fluorolog FL3-12 spectrometer ( ex = 375 nm for YB dyes and 435 for RG dyes, emission corrected for instrument throughput and detector response) using a Y-shaped optical fiber. For temperature-dependent experients, samples were placed on a Gel Instrumente AG hotstage with a TC2 temperature controller. Optical Microscopy. Polarization microscopy studies were conducted on an Olympus BX60 equipped with a Mettler FP82 hot stage and a Mettler FP80 controller with samples placed between crossed polarizers. Dynamic experiments were conducted at a heating rate of 10 C/min. Differential Scanning Calorimetry (DSC). DSC traces were recorded under a nitrogen atmosphere on a Perkin-Elmer DSC Pyris 1 at heating and cooling rates of 10 C/min. Wide Angle X-ray Diffraction. Wide angle X-ray diffraction (WAXD) measurements were conducted at RT on a Rigaku/MSC D/Max-Ultima Wide Angle Theta/Theta X-ray Diffraction System. Powder samples were loaded onto a rectangular glass sample holder and scans were obtained using CuK radiation with an incident wavelength of 0.15 nm under a voltage of 30 kv and a current of 30 ma. The scan rate was 0.5 /min. Single Crystal X-ray Diffraction. A lustrous, orange, block-like specimen of C1-RG, approximate dimensions 0.10 mm x 0.20 mm x 0.40 mm, was used for the X-ray crystallographic analysis. The X- ray intensity data were measured at 100(2) K on a Bruker SMART APEXII CCD area detector system equipped with a graphite monochromator and a Mo K fine-focus sealed tube ( = Å) operated at 1.5 kw power (50 kv, 30 ma). The detector was placed at a distance of 6.00 cm from the crystal. A total of 2580 frames were collected with a scan width of 0.5º with an exposure time of 10.0 sec/frame. The total data collection time was 6 hours. The frames were integrated with the Bruker SAINT software package using a narrow-frame integration algorithm. The integration of the data using a triclinic unit cell yielded a total of 4531 reflections to a maximum angle of 28.54, of which 2501 were independent, completeness = 98.5%, R int = 1.76%, R sig = 1.95%) and 2203 were greater than 2 (I). The final cell constants of a = (6) Å, b = (13) Å, c = (16) Å, = 68.45(10) = (2), = (10) volume = (12) Å 3, are based upon the refinement of the XYZ-centroids of 6465 reflections above 20 (I) with 3.40 < 2 < Analysis of the data showed negligible decay during data collection. Data were corrected for absorption effects using the multi-scan technique (SADABS). The ratio of minimum to maximum apparent transmission 5
3 was The calculated minimum and maximum transmission coefficients (based on crystal size) are and The structure was solved and refined using the Bruker SHELXTL (Version 6.1) Software Package, using the space group P-1, with Z = 1 for the formula unit, C 28 H 24 N 2 O 4. The final anisotropic fullmatrix least-squares refinement on F 2 with 202 variables converged at R1 = 4.04%, for the observed data and wr2 = 9.79% for all data. The goodness-of-fit was The largest peak on the final difference electron density synthesis was e - /Å 3 and the largest hole was e - /Å 3 with an RMS deviation of e - /Å 3. All hydrogen atoms were located and positions refined. On the basis of the final model, the calculated density was g/cm 3 and F(000), 238 e -. The structure shows evidence for weak bifurcated CH O hydrogen bonding (2.446 Å) between molecules involving the outermost methoxyaryl groups. The peripheral aromatic rings are offset by 23.7 from being coplanar with the central aromatic ring. The remaining bond distances and angles are relatively standard. 6
4 Figure S1. Packing down a-axis (top) and down b-axis (bottom) of C1-RG. 7
5 Table 1. Crystal data and structure refinement for C1-RG. Identification code Empirical formula test_0m C28 H24 N2 O4 Formula weight Temperature Wavelength 100(2) K A Crystal system, space group Triclinic, P-1 Unit cell dimensions a = (6) A alpha = (10) deg. b = (13) A beta = (2) deg. c = (16) A gamma = (10)deg. Volume (12) A^3 Z, Calculated density 1, Mg/m^3 Absorption coefficient mm^-1 F(000) 238 Crystal size Theta range for data collection Limiting indices 0.40 x 0.20 x 0.10 mm 1.70 to deg. -5<=h<=5, -13<=k<=13, -16<=l<=16 Reflections collected / unique 6465 / 2501 [R(int) = ] Completeness to theta = % Absorption correction Multi-scan Max. and min. transmission and Refinement method Full-matrix least-squares on F^2 Data / restraints / parameters 2501 / 0 / 202 Goodness-of-fit on F^ Final R indices [I>2sigma(I)] R1 = , wr2 = R indices (all data) R1 = , wr2 = Largest diff. peak and hole and e.a^-3 8
6 Table 2. Atomic coordinates (x 10 4 ) and equivalent isotropic displacement parameters (Å 2 x 10 3 ) for C1-RG. U(eq) is defined as one third of the trace of the orthogonalized Uij tensor. x y z U(eq) C(1) 1763(3) 6793(1) 11706(1) 28(1) C(2) 3870(2) 8023(1) 10003(1) 17(1) C(3) 5597(3) 6774(1) 9942(1) 19(1) C(4) 7495(2) 6855(1) 9062(1) 18(1) C(5) 7749(2) 8157(1) 8254(1) 14(1) C(6) 5942(2) 9400(1) 8329(1) 15(1) C(7) 4008(2) 9336(1) 9180(1) 17(1) C(8) 9849(2) 8225(1) 7344(1) 14(1) C(9) 10761(2) 6923(1) 7136(1) 18(1) C(10) 10863(2) 9411(1) 6757(1) 14(1) C(11) 12935(2) 9681(1) 5861(1) 14(1) C(12) 14281(2) 8680(1) 5396(1) 15(1) C(13) 13709(2) 11024(1) 5439(1) 15(1) C(14) 13345(3) 13311(1) 5553(1) 24(1) N(1) 11401(3) 5868(1) 6990(1) 28(1) O(1) 1976(2) 8095(1) 10830(1) 22(1) O(2) 12380(2) 11995(1) 5903(1) 19(1) 9
7 Table 3. Bond lengths [Å] and angles [deg] for C1-RG. C(1)-O(1) (14) C(1)-H(1) 0.974(17) C(1)-H(1A) 1.010(17) C(1)-H(1B) 0.980(17) C(2)-O(1) (13) C(2)-C(3) (16) C(2)-C(7) (15) C(3)-C(4) (15) C(3)-H(3) 0.976(15) C(4)-C(5) (15) C(4)-H(4) 0.968(14) C(5)-C(6) (15) C(5)-C(8) (14) C(6)-C(7) (15) C(6)-H(6) 0.971(14) C(7)-H(7) 0.964(14) C(8)-C(10) (15) C(8)-C(9) (15) C(9)-N(1) (15) C(10)-C(11) (14) C(10)-H(10) 0.952(14) C(11)-C(12) (15) C(11)-C(13) (14) C(12)-C(13)# (14) C(12)-H(12) 0.949(14) C(13)-O(2) (12) C(13)-C(12)# (14) C(14)-O(2) (13) C(14)-H(14A) 0.996(15) C(14)-H(14B) 1.012(15) C(14)-H(14C) 0.970(15) O(1)-C(1)-H(1) 111.3(10) O(1)-C(1)-H(1A) 111.2(9) H(1)-C(1)-H(1A) 108.9(13) O(1)-C(1)-H(1B) 103.9(9) H(1)-C(1)-H(1B) 110.3(13) H(1A)-C(1)-H(1B) 111.2(13) O(1)-C(2)-C(3) (10) O(1)-C(2)-C(7) (10) C(3)-C(2)-C(7) (10) C(2)-C(3)-C(4) (10) C(2)-C(3)-H(3) 121.9(8) C(4)-C(3)-H(3) 119.0(8) C(5)-C(4)-C(3) (10) C(5)-C(4)-H(4) 119.7(8) C(3)-C(4)-H(4) 118.4(8) C(4)-C(5)-C(6) (10) C(4)-C(5)-C(8) (9) C(6)-C(5)-C(8) (9) C(7)-C(6)-C(5) (10) C(7)-C(6)-H(6) 117.8(8) C(5)-C(6)-H(6) 121.0(8) C(6)-C(7)-C(2) (10) C(6)-C(7)-H(7) 121.0(8) C(2)-C(7)-H(7) 118.8(8) C(10)-C(8)-C(9) (10) C(10)-C(8)-C(5) (9) C(9)-C(8)-C(5) (9) N(1)-C(9)-C(8) (12) 10
8 C(8)-C(10)-C(11) (10) C(8)-C(10)-H(10) 115.9(8) C(11)-C(10)-H(10) 112.9(8) C(12)-C(11)-C(13) (9) C(12)-C(11)-C(10) (9) C(13)-C(11)-C(10) (9) C(13)#1-C(12)-C(11) (10) C(13)#1-C(12)-H(12) 117.9(8) C(11)-C(12)-H(12) 120.1(8) O(2)-C(13)-C(12)# (9) O(2)-C(13)-C(11) (9) C(12)#1-C(13)-C(11) (10) O(2)-C(14)-H(14A) 109.6(8) O(2)-C(14)-H(14B) 111.6(8) H(14A)-C(14)-H(14B) 109.0(12) O(2)-C(14)-H(14C) 105.2(9) H(14A)-C(14)-H(14C) 109.3(12) H(14B)-C(14)-H(14C) 111.9(12) C(2)-O(1)-C(1) (9) C(13)-O(2)-C(14) (8) Symmetry transformations used to generate equivalent atoms: #1 -x+3,-y+2,-z+1 11
9 Table 4. Anisotropic displacement parameters (Å 2 x 10 3 ) for C1-RG. The anisotropic displacement factor exponent takes the form: -2 2 [ h 2 a* 2 U h k a* b* U12 ]. U11 U22 U33 U23 U13 U12 C(1) 33(1) 24(1) 22(1) -4(1) 13(1) -7(1) C(2) 16(1) 21(1) 16(1) -9(1) 5(1) -7(1) C(3) 22(1) 16(1) 18(1) -4(1) 5(1) -6(1) C(4) 19(1) 14(1) 20(1) -6(1) 4(1) -3(1) C(5) 14(1) 17(1) 14(1) -6(1) 1(1) -5(1) C(6) 17(1) 15(1) 14(1) -5(1) 1(1) -5(1) C(7) 17(1) 16(1) 18(1) -8(1) 2(1) -3(1) C(8) 14(1) 15(1) 14(1) -6(1) 1(1) -2(1) C(9) 20(1) 17(1) 17(1) -4(1) 7(1) -6(1) C(10) 14(1) 15(1) 15(1) -7(1) 1(1) -3(1) C(11) 13(1) 15(1) 13(1) -4(1) 1(1) -3(1) C(12) 16(1) 14(1) 15(1) -4(1) 2(1) -5(1) C(13) 15(1) 14(1) 15(1) -6(1) 1(1) -2(1) C(14) 34(1) 16(1) 27(1) -11(1) 12(1) -10(1) N(1) 37(1) 18(1) 29(1) -9(1) 17(1) -9(1) O(1) 27(1) 19(1) 20(1) -7(1) 13(1) -7(1) O(2) 25(1) 14(1) 21(1) -9(1) 10(1) -6(1) 12
10 Table 5. Hydrogen coordinates (x 10 4 ) and isotropic displacement parameters (Å 2 x 10 3 ) for C1-RG. x y z U(eq) H(1) 3700(40) 6290(17) 12098(13) 35(4) H(3) 5540(30) 5841(16) 10502(12) 25(4) H(4) 8700(30) 5978(15) 9030(12) 24(3) H(6) 5950(30) 10330(15) 7764(11) 19(3) H(7) 2720(30) 10187(15) 9217(11) 21(3) H(10) 10180(30) 10208(15) 6973(11) 18(3) H(12) 13820(30) 7766(15) 5652(11) 21(3) H(1A) 990(40) 6148(18) 11409(14) 39(4) H(14A) 15540(30) 13114(15) 5712(12) 25(4) H(1B) 360(40) 7095(17) 12206(13) 37(4) H(14B) 12880(30) 13876(15) 4729(13) 26(4) H(14C) 12300(30) 13815(16) 6007(12) 27(4) 13
11 a b c Figure S2. (a) Normalized fluorescence spectra of crystals (solid) and a CHCl 3 solution (dashed) of C18-YB. (b, c) Pictures taken under excitation (365 nm) of crystals (b) and a CHCl 3 solution (c) of C18-YB Figure S3. Normalized fluorescence spectra of a C18-YB/KBr mixture pressed for 1 min at 1500 psi (solid) and the same sample heated to 130 C (dashed). 14
12 Figure S4. Normalized fluorescence spectra of C18-YB as-prepared (solid), after grinding (dashed), and after grinding/heating to 130 C for 5 min (dotted) Figure S5. Normalized fluorescence spectra of C18-YB slowly cooled from 145 C (solid) to 130 C (dashed) and to 35 C (dotted). 15
13 Figure S6. Normalized fluorescence spectra of C12-YB as-prepared (solid), pressed for 1 min at 1500 psi (dotted), pressed for 1 min at 1500 psi / heated to 130 C for 5 min (dashed), and the same sample subsequently heated to 155 C (dash-dotted) (deg) Figure S7. Powder X-ray diffraction pattern of C18-YB pressed for 19.5 h at 1500 psi. 16
14 a b c d Figure S8. Normalized fluorescence spectra of (a) C1-RG, (b) C1-YB, (c) C18-RG as-prepared, and of (d) C18-RG recrystallized from 1-butanol (solid) and pressed for 5 min at 1500 psi (dashed). 17
15 a (a) (deg) (b) b Figure S9. (a) X-ray diffraction patterns of C1-RG as-prepared (curve a) and of crystals grown by slow evaporation of a mixture of chloroform and hexanes (curve b). (b) X-ray diffraction pattern predicted by Mercury of C1-RG based on single crystal data. 18
Brian T. Makowski, a Joseph Lott, a Brent Valle, b Kenneth D. Singer b* and Christoph Weder a,c*
Brian T. Makowski, a Joseph Lott, a Brent Valle, b Kenneth D. Singer b* and Christoph Weder a,c* a Department of Macromolecular Science and Engineering and b Department of Physics, Case Western Reserve
More informationELECTRONIC SUPPLEMENTARY INFORMATION
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 17 Design of Yb 3+ optical bandwidths by crystallographic modification of disordered
More informationGeneration Response. (Supporting Information: 14 pages)
Cs 4 Mo 5 P 2 O 22 : A First Strandberg-Type POM with 1D straight chains of polymerized [Mo 5 P 2 O 23 ] 6- units and Moderate Second Harmonic Generation Response (Supporting Information: 14 pages) Ying
More informationSupporting Information. Photochromic, Photoelectric and Fluorescent Properties
Supporting Information Multifunctional Open-Framework Zinc Phosphate C 12 H 14 N 2 [Zn 6 (PO 4 ) 4 (HPO 4 )(H 2 O) 2 ]: Photochromic, Photoelectric and Fluorescent Properties Junbiao Wu, Yan Yan, Bingkun
More informationSupporting Information for
Supporting Information for Interior Aliphatic C-H Bond Activation on Iron(II) N-Confused Porphyrin Through Synergistic Nitric Oxide Binding and Iron Oxidation Wei-Min Ching a,b and Chen-Hsiung Hung* a
More informationDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Supporting Information for Synthesis of 2,6-Hexatertiarybutylterphenyl Derivatives, 2,6- (2,4,6-t-Bu 3 C 6 H 2 ) 2 C 6 H 3 X, where X = I, Li, OH, SH, N 3, or NH 2. Konstantin V. Bukhryakov, Richard R.
More informationExperimental. Crystal data. C 3 H 6 N 6 O 6 M r = Orthorhombic, Pbca a = (8) Å b = (7) Å c = (9) Å.
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Redetermination of cyclo-trimethylenetrinitramine Patrick Hakey, Wayne Ouellette,* Jon Zubieta and Timothy Korter
More informationElectronic Supplementary Information. Synthesis and crystal structure of a rare square-planar Co (II) complex of a hydroxyamidinate ligand.
Electronic Supplementary Information Synthesis and crystal structure of a rare square-planar Co (II) complex of a hydroxyamidinate ligand. Mihaela Cibian, a Sofia Derossi, a and Garry S. Hanan* a Département
More informationSupplementary Material (ESI) for Chemical Communications. Solid-state single-crystal-to-single-crystal transformation from a 2D
Supplementary Material (ESI) for Chemical Communications Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release Yuan-Chun He, a
More informationSupporting Information for:
Supporting Information for: Capture of Ni II, Cu I and Zn II by Thiolate Sulfurs of an N 2 S 2 Ni Complex: A Role for a Metallothiolate Ligand in the Acetyl-coenzyme A Synthase Active Site Melissa L. Golden,
More informationSupporting Information for Manuscript B516757D
Supporting Information for Manuscript B516757D 1. UV-Vis absorption spectra Absorbance (a.u.) 0.4 0.2 5F 6F 7F 0.0 300 400 500 Wavelength (nm) Figure S1 UV-Vis spectra of, 5F, 6F and 7F in CHCl 3 solutions
More informationFundamentals of Crystalline State and Crystal Lattice p. 1 Crystalline State p. 2 Crystal Lattice and Unit Cell p. 4 Shape of the Unit Cell p.
Fundamentals of Crystalline State and Crystal Lattice p. 1 Crystalline State p. 2 Crystal Lattice and Unit Cell p. 4 Shape of the Unit Cell p. 7 Crystallographic Planes, Directions, and Indices p. 8 Crystallographic
More informationSupporting Information
Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Supplementary Online Data Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid Chris Ritchie 1, Carsten Streb 1, Johannes
More informationGas Induced Conversion of Hybrid Perovskite Single Crystal to. Single crystal for Great Enhancement of Their Photoelectric
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Gas Induced Conversion of Hybrid Perovskite Single Crystal to Single crystal
More informationWorkshop in X-ray structure analysis
10th International Symposium and Summer School on Bioanalysis Workshop in X-ray structure analysis Practical parts II & III Ivica Đilović & Dalibor Milić Zagreb, 7 July 010 Aims and objectives You will:
More informationSupporting Information
Supporting Information Access to Hexahydrocarbazoles: The Thorpe Ingold Effects of the Ligand on Enantioselectivity Hao Chen, Lijia Wang, Feng Wang, Liu-Peng Zhao, Pan Wang, and Yong Tang* anie_201700042_sm_miscellaneous_information.pdf
More informationBasic Crystallography
Basic Crystallography Data collection and processing Louise N. Dawe, PhD Wilfrid Laurier University Department of Chemistry and Biochemistry References and Additional Resources Faculty of Science, Bijvoet
More informationThree-dimensionally Packed Nano-helical Phase. in Chiral Block Copolymers
Three-dimensionally Packed Nano-helical Phase in Chiral Block Copolymers Rong-Ming Ho, Yeo-Wan Chiang, Chi-Chun Tsai, Chu-Chieh Lin, Bao-Tsan Ko, Bor-Han Huang Supporting Information Table S1 Table S2
More informationExperimental Details and Crystal Structure Refinement from
Experimental Details and Crystal Structure Refinement from Long, J. M., J. Rakovan, J. A. Jaszczak, A. Sommer, and R. Anczkiewicz. 2013. Fluorapatite from a remarkable occurrence of graphite and associated
More informationApplication Note. Raman Spectroscopy Analysis of Crystalline Polymorphs for Pharmaceutical Development
Raman Applications in the Pharmaceutical Industry Impurity Analysis (Identification of micro impurities - sizes less than 1 µm) Evaluation of Synthetized Compounds (Structural analysis in combination with
More informationSmithsonian Museum Conservation Institute
Smithsonian Museum Conservation Institute XRD Analysis of the Corrosion Products from a Tlingit Copper Rattle MCI#6241 Object: Tlingit Stikine Rattle Owner/Custodian: National Museum of the American Indian
More informationCorrelation between the Structure and Catalytic. Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration
Supporting Information Correlation between the Structure and Catalytic Activity of [Cp*Rh(Substituted Bipyridine)] Complexes for NADH Regeneration Vinothkumar Ganesan, Dharmalingam Sivanesan and Sungho
More informationGEOLOGY 333 LAB 14. Lab Final Exam See information sheet for details
GEOLOGY 333 LAB 14 X-RAY DIFFRACTION OF EVERYDAY MATERIALS Lab Final Exam See information sheet for details! Next week during Lab (10 am - noon, May 2, 69 CAB).! 25% of Lab grade, out of 65 points plus
More informationSupporting Information. Low temperature synthesis of silicon carbide nanomaterials using
Supporting Information Low temperature synthesis of silicon carbide nanomaterials using solid-state method Mita Dasog, Larissa F. Smith, Tapas K. Purkait and Jonathan G. C. Veinot * Department of Chemistry,
More informationCharacterization of Materials Using X-Ray Diffraction Powder Diffraction
Praktikum III, Fall Term 09 Experiment P1/P2; 23.10.2009 Characterization of Materials Using X-Ray Diffraction Powder Diffraction Authors: Michael Schwarzenberger (michschw@student.ethz.ch) Philippe Knüsel
More informationFundamentals of Crystalline State p. 1 Introduction p. 1 Crystalline state p. 2 Crystal lattice and crystal structure p. 4 Shape of the unit cell p.
Preface p. xvii Fundamentals of Crystalline State p. 1 Introduction p. 1 Crystalline state p. 2 Crystal lattice and crystal structure p. 4 Shape of the unit cell p. 6 Content of the unit cell p. 7 Asymmetric
More informationOn the quantitative recycling of Raney-Nickel catalysts on a labscale
On the quantitative recycling of Raney-Nickel catalysts on a labscale Waldemar M. Czaplik, Jörg-M. Neudörfl and Axel Jacobi von Wangelin* Supporting information General Toluene was freshly dried and distilled
More information16.2 Scanning Infrared Spectrometers
16.2 Scanning Infrared Spectrometers it's difficult to find materials transparent in the infrared water vapor and atmospheric CO 2 can cause problems there are three common sources high diffraction orders
More informationApplication Note. Introduction. Analysis of crystal polymorphism by Raman Spectroscopy for Medicine Development
Application Note Analysis of crystal polymorphism by Raman Spectroscopy for Medicine Introduction Crystal polymorphism is a phenomenon where Raman applications in the pharmaceutical Industry compounds
More informationMulti-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2014 Supporting Information Multi-step and multi-component organometallic synthesis in one pot
More informationThe first measurement will be performed with a sample temperature of 35 by executing the following steps:
Work Instructions The experimental procedure of this practical is subdivided into two parts. In one part, a phase diagram of DEPE lipids is scanned through different temperatures, where a phase transition
More informationSolution-processed CdS thin films from a single-source precursor
Electronic Supplementary Information: Solution-processed CdS thin films from a single-source precursor Anthony S. R. Chesman,* a Noel W. Duffy, a Alessandro Martucci, b Leonardo De Oliveira Tozi, a Th.
More informationTransmission Electron Microscopy (TEM) Prof.Dr.Figen KAYA
Transmission Electron Microscopy (TEM) Prof.Dr.Figen KAYA Transmission Electron Microscope A transmission electron microscope, similar to a transmission light microscope, has the following components along
More informationPractical X-Ray Diffraction
Typical Example Practical X-Ray Diffraction White powder sample of NaCl,KCl,KNO 3 (trace of H 2 O) Département de chimie Université Laval Prof. Josée BRISSON Dr. Wenhua BI 2014-03-20 Powder X-Ray Diffraction
More informationMicrostructural Evolution of Ti-Mo-Ni-C Powder by Mechanical Alloying
Materials Transactions, Vol. 50, No. 1 (2009) pp. 117 to 122 #2009 The Japan Institute of Metals Microstructural Evolution of -Mo-Ni-C Powder by Mechanical Alloying Hiroyuki Hosokawa, Kiyotaka Kato, Koji
More informationInstrument Configuration for Powder Diffraction
Instrument Configuration for Powder Diffraction Advanced X-ray Workshop S.N. Bose National Centre for Basic Sciences, 14-15/12/2011 Innovation with Integrity Overview What is the application? What are
More informationMatrix-free synthesis of spin crossover micro-rods showing large hysteresis loop. centered at room temperature
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Matrix-free synthesis of spin crossover micro-rods showing large hysteresis loop centered at room
More informationLUMINESCENCE PROPERTIES OF EUROPIUM AND TERBIUM ACTIVATED YTTRIUM NIOBIUM/TANTALATE PHOSPHORS UNDER VUV-UV EXCITATION
Moldavian Journal of the Physical Sciences, Vol., N4, 28 LUMINESCENCE PROPERTIES OF EUROPIUM AND TERBIUM ACTIVATED YTTRIUM NIOBIUM/TANTALATE PHOSPHORS UNDER VUV-UV EXCITATION M. Nazarov 1, 2, E.J. Popovici
More informationCadmium Oxide Nano Particles by Sol-Gel and Vapour- Liquid-Solid Methods
Nano Vision, Vol.1 (1), 47-53 (2011) Cadmium Oxide Nano Particles by Sol-Gel and Vapour- Liquid-Solid Methods S. SAKTHIVEL* and D. MANGALARAJ 1 *PG and Research Department of Physics, Rajah Serfoji Govt.
More informationCRYSTAL STRUCTURE DETERMINATION OF PHARMACEUTICALS WITH ELECTRON DIFFRACTION
CRYSTAL STRUCTURE DETERMINATION OF PHARMACEUTICALS WITH ELECTRON DIFFRACTION Dr. Partha Pratim Das Application Specialist, NanoMEGAS SPRL, Belgium pharma@nanomegas.com www.nanomegas.com This document was
More informationEarth & Planetary Science Applications of X-Ray Diffraction: Advances Available for Research with our New Systems
Earth & Planetary Science Applications of X-Ray Diffraction: Advances Available for Research with our New Systems James R. Connolly Dept. of Earth & Planetary Sciences University of New Mexico 401/501
More informationS2 RANGER LE: Analysis of Light Elements in Cement, Slags and Feldspar
S2 RANGER LE: Analysis of Light Elements in Cement, Slags and Feldspar 1 Welcome Today s topics: S2 RANGER LE o o o Overview XFlash LE detector Improved X-ray tube Analysis of Light Elements in Cement
More information9/28/2013 9:26 PM. Chapter 3. The structure of crystalline solids. Dr. Mohammad Abuhaiba, PE
Chapter 3 The structure of crystalline solids 1 2 Why study the structure of crystalline solids? Properties of some materials are directly related to their crystal structure. Significant property differences
More informationSynthesis calcium-titanate (CaTiO 3 )
Synthesis calcium-titanate (CaTiO 3 ) Vera Petrovic The Advanced School of Electrical Engineering,Belgrade, Vojvode Stepe 283, SCG Abstract Ceramic materials have been in use in many different areas of
More informationExperiment 2b X-Ray Diffraction* Optical Diffraction Experiments
* Experiment 2b X-Ray Diffraction* Adapted from Teaching General Chemistry: A Materials Science Companion by A. B. Ellis et al.: ACS, Washington, DC (1993). Introduction Inorganic chemists, physicists,
More information9/16/ :30 PM. Chapter 3. The structure of crystalline solids. Mohammad Suliman Abuhaiba, Ph.D., PE
Chapter 3 The structure of crystalline solids 1 Mohammad Suliman Abuhaiba, Ph.D., PE 2 Home Work Assignments HW 1 2, 7, 12, 17, 22, 29, 34, 39, 44, 48, 53, 58, 63 Due Sunday 17/9/2015 3 Why study the structure
More informationA SOLVENT-FREE COMPOSITE SOLID ELECTROLYTES OF Li 2 CO 3 Al 2 O 3 SYSTEM PREPARED VIA WATER BASED SOL GEL METHOD
18 TH INTERNATIONAL CONFERENCE ON COMPOSITE MATERIALS A SOLVENT-FREE COMPOSITE SOLID ELECTROLYTES OF Li 2 CO 3 Al 2 O 3 SYSTEM PREPARED VIA WATER BASED SOL GEL METHOD M. Sulaiman 1, *, A.A. Rahman 1, N.S.
More informationTravaux Pratiques de Matériaux de Construction. Etude de Matériaux Cimentaires par Diffraction des Rayons X sur Poudre
Travaux Pratiques de Matériaux de Construction Section Matériaux 6 ème semestre 2015 Etude de Matériaux Cimentaires par Diffraction des Rayons X sur Poudre Study Cementitious Materials by X-ray diffraction
More informationPolymorphism of glycine. Thermodynamic and structural aspects. E. Boldyreva, V. Drebushchak, T. Drebushchak, I. Paukov, Yu. Kovalevskaya, E.
Polymorphism of glycine. Thermodynamic and structural aspects E. Boldyreva, V. Drebushchak, T. Drebushchak, I. Paukov, Yu. Kovalevskaya, E. Shutova Outline Introduction Control of the crystallization of
More informationGrowth and Characterization of NLO Single Crystal: BIS L- Alanine Potassium Chloride (BIS-LAKCL)
International Journal of ChemTech Research CODEN (USA): IJCRGG ISSN : 0974-4290 Vol.6, No.5, pp 2704-2709, Aug-Sept 2014 Growth and Characterization of NLO Single Crystal: BIS L- Alanine Potassium Chloride
More informationZINC/IRON PHASE TRANSFORMATION STUDIES ON GALVANNEALED STEEL COATINGS BY X-RAY DIFFRACTION
Copyright JCPDS - International Centre for Diffraction Data 2003, Advances in X-ray Analysis, Volume 46. 291 ZINC/IRON PHASE TRANSFORMATION STUDIES ON GALVANNEALED STEEL COATINGS BY X-RAY DIFFRACTION S.
More informationThe effect of the chemical environment on the kinetics of carbon phases formation at high-pressure and high-temperature
The effect of the chemical environment on the kinetics of carbon phases formation at high-pressure and high-temperature A.E.L. Villanueva 1,2, K.S. Trentin 1,3, J.A.H. da Jornada 1,4, N.M. Balzaretti 1,
More informationJSM-7800F Field Emission Scanning Electron Microscope
JSM-7800F catalogue JSM-7800F Field Emission Scanning Electron Microscope We provide high performance The Ultimate Research Tool for Multi-Disciplinary Research Institutions Extreme resolution The super
More informationSupplementary Material (ESI) for Dalton Transactions This journal is (c) The Royal Society of Chemistry 2009 Supplementary data
Supplementary data Structural and Biological Investigation of Ferrocene-Substituted 3- Methylidene-1,3-dihydro-2H-indol-2-ones John Spencer, *, Andrew P. Mendham, Arun K. Kotha, Simon C. W. Richardson,
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Synthesis and optical properties of covalently bound Nile Red in mesoporous
More informationChapter 8: Strain Hardening and Annealing
Slide 1 Chapter 8: Strain Hardening and Annealing 8-1 Slide 2 Learning Objectives 1. Relationship of cold working to the stress-strain curve 2. Strain-hardening mechanisms 3. Properties versus percent
More informationWhat if your diffractometer aligned itself?
Ultima IV Perhaps the greatest challenge facing X-ray diffractometer users today is how to minimize time and effort spent on reconfiguring of the system for different applications. Wade Adams, Ph.D., Director,
More informationDevelopment of Elastic Polylactic Acid Material Using Electron Beam Radiation
ELECTRONICS Development of Elastic Polylactic Acid Material Using Electron Beam Radiation Shinichi KANAZAWA Sumitomo Electric Fine Polymer has developed a technology for fabricating a brand new elastic
More informationANALYTICAL PERFORMANCE OF A HANDHELD EDXRF SPECTROMETER WITH MINIATURE X-RAY TUBE EXCITATION
JPACSM 56 ANALYTICAL PERFORMANCE OF A HANDHELD EDXRF SPECTROMETER WITH MINIATURE X-RAY TUBE EXCITATION Volker Thomsen and Debbie Schatzlein NITON LLC Billerica, MA ABSTRACT The analytical performance of
More informationSupporting Information Benchmarking Cellulose Nanocrystals: From the Laboratory to Industrial Production
Benchmarking Cellulose Nanocrystals: From the Laboratory to Industrial Production Michael S. Reid 1, Marco Villalobos 2 and Emily D. Cranston 1* 1 Department of Chemical Engineering, McMaster University
More informationCatalytic Effect of Solvent Vapors on the Spontaneous Formation of Caffeine-Malonic Acid Co-Crystal
Supporting Information for Catalytic Effect of Solvent Vapors on the Spontaneous Formation of Caffeine-Malonic Acid Co-Crystal Canran Ji, Mikaila C. Hoffman, and Manish A. Mehta * Department of Chemistry
More informationSupplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry 2009
Supplementary Information Silver Nanoparticles with Planar Twinned Defects: Effect of Halides for Precise Tuning of Plasmon Absorption from 400 to >900 nm by Nicole Cathcart, Andrew J. Frank and Vladimir
More informationThe Empyrean Tube. Advanced eco-friendly design, powerful performance
The Empyrean Tube Advanced eco-friendly design, powerful performance The Empyrean Tube The industrial benchmark, redefined PANalytical s Empyrean Tubes set the standard, both for X-ray diffraction (XRD)
More informationA New Theranostic System Based on Gold Nanocages and Phase-Change Materials with Unique Features for Photoacoustic Imaging and Controlled Release
1/2011 Supporting Information A New Theranostic System Based on Gold Nanocages and Phase-Change Materials with Unique Features for Photoacoustic Imaging and Controlled Release Geon Dae Moon,, Sung-Wook
More informationRadiation Shielding Glass RD 30 RD 50
Radiation Shielding Glass RD 30 RD 50 2 SCHOTT is a leading international technology group in the areas of specialty glass and glass-ceramics. With more than 130 years of outstanding development, materials
More informationSUPPLEMENTARY INFORMATION
In the format provided by the authors and unedited. ARTICLE NUMBER: 16178 DOI: 10.1038/NENERGY.2016.178 Enhanced Stability and Efficiency in Hole-Transport Layer Free CsSnI3 Perovskite Photovoltaics Supplementary
More informationPreparation of Bi-Based Ternary Oxide Photoanodes, BiVO 4,
Preparation of Bi-Based Ternary Oxide Photoanodes, BiVO 4, Bi 2 WO 6 and Bi 2 Mo 3 O 12, Using Dendritic Bi Metal Electrodes Donghyeon Kang, a, Yiseul Park, a, James C. Hill, b and Kyoung-Shin Choi a,*
More informationInfluence of Bulk Graphite Thickness on the Accuracy of X-Ray Diffraction Measurement. I. Introduction
Influence of Bulk Graphite Thickness on the Accuracy of X-Ray Diffraction Measurement Jane Y. Howe 1*, Burl O. Cavin 1, Amy E. Drakeford 2, Roberta A. Peascoe 1, Tracy L. Zontek 2, and Douglas J. Miller
More informationMA-SHS of ZrC and ZrB2 in Air from The Zr/B/C Powder. the original is available online at Instructions for use
Title MA-SHS of ZrC and ZrB2 in Air from The Zr/B/C Powder Author(s)Tsuchida, Takeshi; Yamamoto, Satoshi CitationEURO CERAMICS VIII, PTS 1-3: 85-88 Issue Date 2004 Doc URL http://hdl.handle.net/2115/15876
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Supporting Information Hierarchical Orthorhombic V 2 O 5 Hollow Nanospheres
More informationElectronic Supplementary Information
Electronic Supplementary Information Liquid Crystal Polymer Based Single Layer Chemo-responsive Actuator Tahseen Kamal, and Soo-Young Park* Contents Materials Actuator film preparation Characterizations
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2013. Supporting Information for Adv. Funct. Mater., DOI: 10.1002/adfm.201302405 Self-Assembly Mechanism of Spiky Magnetoplasmonic Supraparticles
More informationThe Effects of the Adding V2O5 on the Oxide Semiconductor Layer of a Dye-sensitized Solar Cell
, pp.66-71 http://dx.doi.org/10.14257/astl.2016.140.14 The Effects of the Adding V2O5 on the Oxide Semiconductor Layer of a Dye-sensitized Solar Cell Don-Kyu Lee Electrical Engineering, Dong-Eui University,
More informationGood Diffraction Practice Webinar Series
Good Diffraction Practice Webinar Series LYNXEYE XE - Combining 1D Speed with 0D Background June 27 2013 www.bruker-webinars.com Welcome Brian Jones Product Manager - XRD Bruker AXS Inc. Madison, Wisconsin,
More informationArgon Plasma Sustained in Different Discharge Configurations
WDS'1 Proceedings of Contributed Papers, Part II, 76 8, 21. ISBN 978-8-7378-14-8 MATFYZPRESS Argon Plasma Sustained in Different Discharge Configurations L. Schmiedt, V. Hrachová Charles University Prague,
More informationTHE TEXTURE STRENGTHENING EFFECT IN A MAGNESIUM ALLOY PROCESSED BY SEVERE PLASTIC DEFORMATION
The Rev. texture Adv. Mater. strengthening Sci. 31 (2012) effect 157-162 in a magnesium alloy processed by severe plastic deformation 157 THE TEXTURE STRENGTHENING EFFECT IN A MAGNESIUM ALLOY PROCESSED
More informationAnalysis of strongly absorbing chromophores by UV-visible ATR spectroscopy
Technical Note: AN 915 Rev. B Analysis of strongly absorbing chromophores by UV-visible ATR spectroscopy Walter M. Doyle and Lani Tran This paper illustrates the potential of the attenuated total reflectance
More informationX-Ray Diffraction by Macromolecules
N. Kasai M. Kakudo X-Ray Diffraction by Macromolecules With 351 Figures and 56 Tables Kodansha ~Springer ... Contents Preface v Part I Fundamental 1. Essential Properties of X-Rays................. 3 1.1
More informationCHAPTER 3 EFFECT OF L -LYSINE MONOHYDROCHLORIDE DIHYDRATE ON THE GROWTH AND PROPERTIES OF ADP SINGLE CRYSTALS
55 CHAPTER 3 EFFECT OF L -LYSINE MONOHYDROCHLORIDE DIHYDRATE ON THE GROWTH AND PROPERTIES OF ADP SINGLE CRYSTALS 3.1 INTRODUCTION As mentioned in the previous chapter, ammonium dihydrogen orthophosphate
More informationFluorescence Quenching of Human Serum Albumin by Caffeine
CHEM 411L Instrumental Analysis Laboratory Revision 2.1 Fluorescence Quenching of Human Serum Albumin by Caffeine In this laboratory exercise we will examine the fluorescence of Human Serum Albumin (HSA)
More informationReduction of the Sample Size in the Analysis of Rock by EDXRF
Copyright (C) JCPDS International Centre for Diffraction Data 1999 873 Reduction of the Sample Size in the Analysis of Rock by EDXRF Riidiger Harmel, Ulrike Otto, Olaf Haupt, Clemens Sch$er and Walter
More informationSupporting Information for. Nitric Oxide Reactivity of Copper(II) Complexes of Bidentate Amine Ligands: Effect of. Substitution on Ligand Nitrosation
1 Supporting Information for Nitric Oxide Reactivity of Copper(II) Complexes of Bidentate Amine Ligands: Effect of Substitution on Ligand Nitrosation Moushumi Sarma and Biplab Mondal Department of Chemistry,
More informationImaging of protein crystals with two photon microscopy
Supporting Information Imaging of protein crystals with two photon microscopy Pius Padayatti,*, Grazyna Palczewska,*, Wenyu Sun, Krzysztof Palczewski,# and David Salom Polgenix Inc., Cleveland, Ohio 44106,
More informationQuantitative phase analysis using the Rietveld method for samples in the Ti-Cr binary systems
586 Quantitative phase analysis using the Rietveld method for samples in the Ti-Cr binary systems Ofer Beeri and Giora Kimmel Nuclear Research Center Negev, P.O.Box 9001, Beer-Sheva, 84190 Israel Abstract
More informationGrowth Of TiO 2 Films By RF Magnetron Sputtering Studies On The Structural And Optical Properties
Journal of Multidisciplinary Engineering Science and Technology (JMEST) Growth Of TiO 2 Films By RF Magnetron Sputtering Studies On The Structural And Optical Properties Ahmed K. Abbas 1, Mohammed K. Khalaf
More informationImproving understanding of energetic materials: Compression behavior and co-crystal synthesis
Improving understanding of energetic materials: Compression behavior and co-crystal synthesis Przemyslaw Dera University of Hawaii School of Ocean and Earth Science and Technology Hawaii Institute of Geophysics
More informationThermoelectric Properties and Site-Selective Rb + /K + Distribution in the K 2-x Rb x Bi 8 Se 13 Series
Chem. Mater. 2003, 15, 3035-3040 3035 Thermoelectric Properties and Site-Selective Rb + /K + Distribution in the K 2-x Rb x Bi 8 Se 13 Series Theodora Kyratsi, Duck-Young Chung, John R. Ireland, Carl R.
More informationLayer Thickness Analysis of Thin Metal Coatings with. Bruker Nano Analytics, Berlin, Germany Webinar, June 8 th 2017
Layer Thickness Analysis of Thin Metal Coatings with micro-xrf on SEM Bruker Nano Analytics, Berlin, Germany Webinar, June 8 th 2017 09.06.2017 Presenters Stephan Boehm Product Manager Micro-XRF/SEM Bruker
More informationDirectional Surface Plasmon Coupled Emission
Journal of Fluorescence, Vol. 14, No. 1, January 2004 ( 2004) Fluorescence News Directional Surface Plasmon Coupled Emission KEY WORDS: Surface plasmon coupled emission; high sensitivity detection; reduced
More informationOxygen Content and Valence of Ru in RuSr 2 (Gd 0.75 Ce 0.25 ) 2 Cu 2 O 10-d (Ru-1222) Magnetosuperconductor
Oxygen Content and Valence of Ru in RuSr 2 (Gd 0.75 Ce 0.25 ) 2 Cu 2 O 10-d (Ru-1222) Magnetosuperconductor V.P.S. Awana 1, M. Karppinen 1, H. Yamauchi 1, M. Matvejeff 1, R.S. Liu 2 and L.-Y. Jang 3 1
More informationCrystal Phase-Controlled Synthesis of Cu 2 FeSnS 4 Nanocrystals with Band Gap around 1.5 ev
Crystal Phase-Controlled Synthesis of Cu 2 FeSnS 4 Nanocrystals with Band Gap around 1.5 ev Xiaoyan Zhang, a,b Ningzhong Bao,* c Karthik Ramasamy, a Yu-Hsiang A. Wang, a Yifeng Wang, c Baoping Lin b and
More informationSYNTHESIS OF NANOSIZE SILICON CARBIDE POWDER BY CARBOTHERMAL REDUCTION OF SiO 2
2nd International Conference on Ultrafine Grained & Nanostructured Materials (UFGNSM) International Journal of Modern Physics: Conference Series Vol. 5 (2012) 263 269 World Scientific Publishing Company
More informationScintillating Optical Fibers
Scintillating Optical Fibers Plastic Scintillating Fibers Saint-Gobain Crystals manufactures a variety of plastic scintillating, wavelength-shifting and light-transmitting fibers used for research and
More informationWhat is a crystal? Historic definition before the advent of crystallography. - A material with a regularly repeating structural motif
What is a crystal? Historic definition before the advent of crystallography - A solid with well-defined faces Crystallographic definition - A material with a regularly repeating structural motif The strict
More informationX-Ray Diffraction Analysis
162402 Instrumental Methods of Analysis Unit III X-Ray Diffraction Analysis Dr. M. Subramanian Associate Professor Department of Chemical Engineering Sri Sivasubramaniya Nadar College of Engineering Kalavakkam
More informationIntroduction Oil Sands Background Naphthenic Acids Background Fluorescence Method and Materials Results Discussion Concluding Remarks
Introduction Oil Sands Background Naphthenic Acids Background Fluorescence Method and Materials Results Discussion Concluding Remarks Acknowledgements Oil sands largest deposit outside the Middle East
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. Electronic Supplementary Information A terbium(iii) lanthanide organic framework as a platform for recyclable multi-responsive
More informationDoris Ehrt and Doris Möncke. Friedrich Schiller University of Jena, Otto-Schott-Institut, Fraunhoferstr. 6, D Jena, Germany,
Charge transfer absorption of Fe 3+ and Fe + complexes and UV radiation induced defects in different glasses Doris Ehrt and Doris Möncke Friedrich Schiller University of Jena, Otto-Schott-Institut, Fraunhoferstr.
More informationSystematic Errors and Sample Preparation for X-Ray Powder Diffraction. Jim Connolly EPS , Spring 2010
Systematic Errors and Sample Preparation for X-Ray Powder Diffraction Jim Connolly EPS400-001, Spring 2010 Introduction Most systematic errors in diffraction experiments are related to the characteristics,
More informationField Effect Transistors Based on Van-der-Waals. Grown and Dry Transferred All-Inorganic
Supporting Information for Field Effect Transistors Based on Van-der-Waals Grown and Dry Transferred All-Inorganic Perovskites Ultrathin Platelets Chengxue Huo #, Xuhai Liu #, Xiufeng Song, Ziming Wang,
More information