SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier siachrome PEARL 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the Automotive care products substance/mixture 1.3. Details of the supplier of the safety data sheet Manufacturer Company name: Sia Abrasives Industries AG Street: Mühlwiesenstrasse 20 Place: CH-8501 Frauenfeld/Schwetz Telephone: +41 (0) Internet: 1.4. Emergency telephone number: Supplier Company name: Street: 5 Mollem 580 Place: Telephone: Internet: Toxzentrum Zürich Sia Abrasives Industries AG BE-1730 Mollem (Belgium) +32 (2) msds.ch@sia-abrasives.com Emergency GIZ Nord +49 (0) telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Telefax: +41 (0) Telefax: + 32 (2) This mixture is not classified as hazardous according to Directive 1999/45/EC. Classification according to Regulation (EC) No. 1272/2008 [CLP] 2.2. Label elements Special labelling of certain mixtures EUH210 Safety data sheet available on request Other hazards No information available. SECTION 3: Composition/information on ingredients 3.2. Mixtures GB - EN Page 1 of 11

2 Hazardous components EC No Index No REACH No Chemical name Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity aliphatic hydrocarbons, C11-C13, isoalkanes, 10 - < 15 % (<0,1 % Benzene) Xn - Harmful R65-66 Asp. Tox. 1; H304 EUH Butoxy-2-propanol 1 - < 5 % Xi - Irritant R36/38 Skin Irrit. 2, Eye Irrit. 2A; H315 H319 Full text of R, H and EUH phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information Change contaminated, saturated clothing. After inhalation Provide fresh air. After contact with Wash with plenty of water. Take off contaminated clothing and skin wash it before reuse. After contact with Rinse immediately carefully and thoroughly with eye-bath or water. eyes After ingestion Rinse mouth immediately and drink plenty of water Most important No information available. symptoms and effects, both acute and delayed 4.3. Indication of any Treat symptomatically. immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable Foam. Dry extinguishing powder. Carbon dioxide (CO2). extinguishing media Unsuitable Full water jet extinguishing media 5.2. Special hazards Vapours can form explosive mixtures with air. In case of fire may arising from the be liberated: Carbon dioxide (CO2). Carbon monoxide. Nitrogen substance or mixture oxides (NOx). GB - EN Page 2 of 11

3 5.3. Advice for firefighters Additional information SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage In case of fire: Wear self-contained breathing apparatus. Use water spray jet to protect personnel and to cool endangered containers. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Use personal protection equipment. Do not allow to enter into surface water or drains. Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section Precautions for safe handling Advice on safe Provide adequate ventilation. handling Advice on protection Keep away from sources of ignition. - No smoking. against fire and explosion Further information Do not breathe gas/fumes/vapour/spray. on handling 7.2. Conditions for safe storage, including any incompatibilities Requirements for Keep container tightly closed. storage rooms and vessels Advice on storage Keep in a cool, well-ventilated place away from highly flammable compatibility substances. Further information Recommended storage temperature : 20 C on storage conditions 7.3. Specific end Automotive care products use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters GB - EN Page 3 of 11

4 Exposure limits (EH40) Substance ppm mg/m³ fibres/ml Category Origin Kaolin respirable dust - 2 TWA (8 h) WEL DNEL/DMEL values Substance - - STEL (15 min) WEL DNEL type Exposure route Effect Value Butoxy-2-propanol Worker DNEL, long-term dermal systemic 44 mg/kg bw/day Worker DNEL, long-term inhalation systemic 240,5 mg/m³ Consumer DNEL, acute dermal local 50 % Worker DNEL, acute dermal local 50 % Consumer DNEL, long-term dermal systemic 16 mg/kg bw/day Consumer DNEL, long-term inhalation systemic 33,8 mg/m³ Consumer DMEL, long-term oral systemic 8,75 mg/kg bw/day PNEC values Substance Environmental compartment Butoxy-2-propanol Freshwater Marine water Freshwater sediment Marine sediment Soil Value 0,525 mg/l 0,0525 mg/l 2,36 mg/kg 0,236 mg/kg 0,16 mg/kg 8.2. Exposure controls Appropriate engineering controls If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe gas/fumes/vapour/spray. GB - EN Page 4 of 11

5 Protective and Take off contaminated clothing. Wash hands before breaks and hygiene measures after work. When using do not eat or drink. Eye/face protection Wear eye/face protection. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Recommended glove articles : Rotiprotect Nitril eco, Thickness of the glove material 0,1 mm, level 2 > 30 min. (DIN EN 374), Disposable gloves Skin protection Wear suitable protective clothing. Respiratory In case of inadequate ventilation wear respiratory protection. protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Paste Colour: Odour: ph-value (at 20 C): white characteristic Changes in the physical state Melting point: Initial boiling point and 100 C boiling range: Flash point: >61 C Flammability Solid: Gas: 6 not applicable not applicable Lower explosion limits: 0,6 vol. % Upper explosion limits: 7 vol. % Ignition temperature: >200 C Auto-ignition temperature Solid: not applicable Gas: Decomposition temperature: Oxidizing properties not applicable Not oxidizing. Test method DIN GB - EN Page 5 of 11

6 Vapour pressure: (at 20 C) Density: Water solubility: (at 20 C) Solubility in other solvents Partition coefficient: Viscosity / dynamic: (at 20 C) Vapour density: Evaporation rate: Solvent content: 9.2. Other information Solid content: 0,4 hpa 0,91 g/cm³ 760 g/l mpa s 16,91 % 3,81 % SECTION 10: Stability and reactivity Reactivity Gases/vapours, flammable Chemical stability The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions No known hazardous reactions Conditions to heat. avoid Incompatible No information available. materials Hazardous No known hazardous decomposition products. decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. GB - EN Page 6 of 11

7 Acute toxicity Chemical name Exposure routes Method Dose Species Source aliphatic hydrocarbons, C11-C13, isoalkanes, (<0,1 % Benzene) oral LD mg/kg Rat OECD 401 dermal LD mg/kg Rat OECD 402 inhalative (4 h) vapour LC mg/l Rat OECD Butoxy-2-propanol oral dermal inhalative (4 h) vapour LD50 LD50 LC mg/kg >2001 mg/kg >651 mg/l Rat Rat Rat OECD 403 Irritation and Based on available data, the classification criteria are not met. corrosivity Sensitising effects Based on available data, the classification criteria are not met. STOT-single Based on available data, the classification criteria are not met. exposure Severe effects after Based on available data, the classification criteria are not met. repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. Additional This mixture is classified as not hazardous according to information on tests regulation (EC) 1272/2008 [CLP]. SECTION 12: Ecological information Toxicity The product is not: Ecotoxic. GB - EN Page 7 of 11

8 Chemical name Aquatic toxicity Method Dose [h] [d] Species aliphatic hydrocarbons, C11-C13, isoalkanes, (<0,1 % Benzene) Acute fish toxicity Acute algae toxicity Acute crustacea toxicity LC50 >1000 mg/l 96 h Oncorhynchus mykiss (Rainbow trout) ErC50 >1000 mg/l 72 h Pseudokirchneriella subcapitata EC50 >1000 mg/l 48 h Daphnia magna (Big water flea) Algea toxicity NOEC 1000 mg/l 3 d Pseudokirchneriella subcapitata 3-Butoxy-2-propanol Acute fish toxicity Acute algae toxicity Acute crustacea toxicity LC50 > mg/l 96 h Poecilia reticulata (Guppy) ErC50 >1000 mg/l 96 h Pseudokirchneriella subcapitata EC50 >1000 mg/l 48 h Daphnia magna (Big water flea) Algea toxicity NOEC 560 mg/l 4 d Pseudokirchneriella subcapitata Persistence and degradability Chemical name Method Evaluation The product has not been tested. Value aliphatic hydrocarbons, C11-C13, isoalkanes, (<0,1 % Benzene) d Source OECD 301 F 31,3 % 28 ECHA Dossier Evidence for inherent biodegradability. 3-Butoxy-2-propanol Bioaccumulative 90% 28 Readily biodegradable (according to OECD criteria). The product has not been tested. Partition coefficient n-octanol/water Chemical name Log Pow Butoxy-2-propanol 1,2 BCF Chemical name BCF Butoxy-2-propanol <100 Species Source Mobility in soil The product has not been tested. GB - EN Page 8 of 11

9 12.5. Results of PBT The product has not been tested. and vpvb assessment Other adverse No information available. effects Further information Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation. Waste disposal number of waste from residues/unused products Waste disposal number of contaminated packaging Contaminated packaging WASTES FROM SHAPING AND PHYSICAL AND MECHANICAL SURFACE TREATMENT OF METALS AND PLASTICS; wastes from shaping and physical and mechanical surface treatment of metals and plastics; spent grinding bodies and grinding materials containing dangerous substances Classified as hazardous waste WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); plastic packaging Wash with plenty of water. Completely emptied packages can be recycled. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Inland waterways transport (ADN) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Marine transport (IMDG) UN number: UN proper shipping name: GB - EN Page 9 of 11

10 14.3. Transport hazard class(es): Packing group: Air transport (ICAO) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY yes HAZARDOUS: Danger releasing heptane; n-heptane substance: Special No information available. precautions for user Transport in not applicable bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 2010/75/EU (VOC): 11,389 % (103,641 g/l) 2004/42/EC (VOC): 16,151 % (146,977 g/l) Additional information To follow: 850/2004/EC, 79/117/EEC, 689/2008/EC National regulatory information Water contaminating 1 - slightly water contaminating class (D): Chemical For this substance a chemical safety assessment has not been safety assessment carried out. SECTION 16: Other information Changes This data sheet contains changes from the previous version in section(s): 2,9. Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) GB - EN Page 10 of 11

11 Relevant R-phrases (Number and full text) Relevant H- and EUH-phrases (Number and full text) Further Information IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% 36/38 Irritating to eyes and skin. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. EUH066 Repeated exposure may cause skin dryness or cracking. EUH210 Safety data sheet available on request. The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.) GB - EN Page 11 of 11