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1 McMillan, 2004 F. Frankel - copyright Systems Nanotechnology - NSF / NNI context and challenges for manufacturing - M.C. Roco National Science Foundation, and National Nanotechnology Initiative Workshop on Nanomanufacturing, February 11, 2008
2 Benchmark with experts in over 20 countries Nanostructure Science and Technology Book, Springer, 1999 Nanotechnology is the control and restructuring of matter at dimensions of roughly 1 to 100 nanometers (from atomic size to about 100 molecular diameters), where new phenomena enable new applications. (measure- control- manipulate- integrate at the nanoscale) M.C. Roco, 02/11/08
3 Five Generations of Products and Productive Processes Timeline for beginning of industrial prototyping and nanotechnology commercialization ( ; 2020-) 1 st : Passive nanostructures (1 st generation products) Ex: coatings, nanoparticles, nanostructured metals, polymers, ceramics ~ 2000 ~ 2005 nd : Active nanostructures Ex: 3D transistors, amplifiers, targeted drugs, actuators, adaptive structures 2 nd CMU ~ 2010 Reference: AIChE Journal, Vol. 50 (5), rd : Systems of nanosystems Ex: guided assembling; 3D networking and new hierarchical architectures, robotics, evolutionary ~ th : Molecular nanosystems Ex: molecular devices by design, atomic design, emerging functions 5 th : Converging technologies Ex: nano-bio-info from nanoscale, cognitive technologies; large complex systems from nanoscale New R&D challenges
4 Participants in the NNI (NSET) FY agencies; FY NNI agencies 4 WG: NEHI (env.), NILI (industry), MANU, GIN (global) NIH USDA FS NIST NASA DOD DOTr DOS IC FDA NRC DOC BIS USPTO ITC USGS DOE NSF DOT EPA USDA DOJ DHS DOC TA CPSC NIOSH DOL DOEd 2001: Six Agencies 2002: Seven New Agencies : Four New Agencies 2005: Six New Agencies 2006: Three New Agencies MC Roco, 02/11/08
5 NSF - a pioneer at the international level in Nanoscale Science and Engineering (NSE) or link from FY 2009: $397M ~1/4 of Federal and ~1/12 of World Investment Fundamental research - seven PCAs with new priorities Establishing the infrastructure - over 3,500 active projects; 25 large centers, 2 user facilities (NNIN, NCN), multidisciplinary teams Training and education over 10,000 students and teachers/yr Fiscal Year NSF $97M $150M 2002 $199M 2003 $221M 2004 $254M 2005 $338M 2006 $344M 2007 $389M 2008 $389M 2009 $397M NSE ($M) MC Roco, 02/11/08
6 FY 2009 NNI Budget Request $1,445 million Fiscal Year NNI 2000 $270M 2001 $464M 2002 $697M 2003 $862M 2004 $989M 2005 $1,200M 2006 $1,303M 2007 $1,425M 2008 $1,491M R 2009 $1,525M * Includes Congressionally directed additional funding February 4, Request NNI ($ million) MC Roco, 02/11/08
7 Context Nanotechnology in the World National government investments (est. NSF) millions $ / year W. Europe Japan USA Others Total Country / Region Gov. Nanotech R&D, 2006 ($M) Specific Nanotech R&D, 2006 ($/Capita) USA EU-25 ~ Japan ~ China Korea Taiwan ~ 280 ~ 315 ~ Seed funding ( ) NNI Preparation (vision / benchmark) 1 st Strategic Plan (passive nanostructures) 2 nd Strategic Plan (active ns. & systems) Industry R&D ($6B) has exceeded national government R&D ($4.6B) in 2006 J. Nanoparticle Research, 7(6), 2005, MC. Roco
8 FY 2007 NNI investment in nanomanufacturing (FY $48.1M; FY $50.2M), FY $62.1M).
9 TOOLS Eight Nanoscale Science and Engineering networks with national outreach Network for Computational Nanotechnology (2002-) 25,000 users/ 2007 National Nanotechnology Infrastructure Network (2003-) 4,500 users/ 2007 TOPICAL Nationwide Impact Nanotechnology Center Learning and Teaching (2004-) 1 million students/ 5yr Center for Nanotechnology lnformal Science Education (2005-) 100 sites/ 5yr Network for Nanotechnology in Society (2005-) Involve academia, public, industry National Nanomanufacturing Network (2006-) 4 NSETs, DOD centers, and NIST Environmental Implications of Nanotechnology (2008-) with EPA GENERAL RESEARCH AND EDUCATION NSEC Network (2001-) 17 research & education centers MRSEC Network (2001-) 6 new research & education centers since 2000 MC Roco, 02/11/08
10 Manufacturing: Transforming raw materials into products with desired properties and performance generally in large quantities Defining Nanomanufacturing (1) : Aims at building material structures, components, devices/ machines, and systems with nanoscale features in one, two and three dimensions. It includes - bottom-up directed assembling of nanostructure building blocks (from the atomic, molecular, supramolecular levels), - top-down high-resolution processing (ultraprecision engineering, fragmentation methods, positioning assembling), - engineering of molecules and supramolecular systems (molecules as devices by design, nanoscale machines, etc.), - hierarchical integration with larger scale systems. Atoms, nanostructures materials/ devices/ molecules (intermediate) machines/ systems M.C. Roco, 02/11/08
11 Nanomanufacturing: Several challenges Efficiently create structures in the nm range Combine top-down and bottom-up approaches Integration along scales with larger systems Large scale production and economical scale up: different concepts and principles? Interaction non-living and living structures Replication (ex: lithography, thermodynamic cycle) Self-replication (ex: bio, DNA-based) Revolutionary processes envisioned (open system) Extend existing manufacturing capabilities if possible Specific nanotechnology processes and equipment; Expand on existing infrastructure? M.C. Roco, 02/11/08
12 FY 2008 NS&E Priorities Research Areas (1) The long-term objective is building a foundation of fundamental research to understand and restructure matter at nanoscale in all areas of S&E A. Scientific challenges - New theories at nanoscale Ex: transition from quantum to classical physics, collective behavior, for simultaneous phenomena - Non-equilibrium processes - Designing new molecules with engineered functions - New architectures for assemblies of nanocomponents - The emergent behavior of nanosystems MC Roco, 02/11/08
13 FY 2008 NS&E Priorities Research Areas (2) B. Development of nanotechnology - Tools for measuring and restructuring with atomic precision and time resolution of chemical reactions - Understanding and use of quantum phenomena - Understanding and use of multi-scale selfassembling - Nanobiotechnology sub-cellular and systems approach - Nanomanufacturing of active nanostructures and nanosystems, modular and platform based, in-place, hierarchical MC Roco, 02/11/08
14 Challenges for Systems Nanotechnology Understanding mechanisms and patterns of system behavior as a function of components, interaction forces and networks at the nanoscale. Consider systems with large number of nanocomponents and non-linear interactions Tools for measuring, simulation and manufacturing of bio/engineering nanosystems Development of a new framework for risk assessment to address emerging functions of nanosystems with potential use in consumer products, medical treatments, food industry and other areas MC Roco, 02/11/08 Integrated circuits that are smaller and faster are possible with microfluidics systems built from or incorporating nanocomponents. Ferreira, Conceptual schematic of a manufactured nanosystem. The hope for this device is its use to identify the molecular signature of breast tumors. X Zhang,
15 FY 2008 NS&E Priorities Research Areas (3) C. Integration of nanotechnology in application areas - Replacing electron charge as the information carrier in electronics -Energy conversion, water filtration / desalinization using new principles - Efficient nanomanufacturing and sustainable environment - Nano-bio interfaces between the human body and manmade devices SEM micrographs of membranes (UIUC) - Nano-informatics for better communication and nanosystem design MC Roco, 02/11/08
16 Key EHS priorities - New instrumentation for nanoparticle characterization and nanotoxicity - Transport phenomena and physico- chem.- biological processes of nanoscale dispersions in the natural and working environments - Predictive models for interaction of nanomaterials with cells/living tissues - Separation of nanoparticles from fluids - Safety of manufacturing nanoparticles MC Roco, 02/11/08 FY 2008 NS&E Priority Research Areas (4) D. Societal dimensions of nanotechnology - Understanding & sustainable ENV; EHS including research for natural/ incidental/ manufactured nanomaterials - Formal (earlier K-12 and public education integrated in K Gray) and informal education - Social issues and public engagement
17 Nano radio (Zettl Group, UCSB)
18 This workshop Part of a periodical evaluation process of the nanomanufacturing frontiers (a NNN function) Looking for creative ideas, preparing manufacturing for the next generation of nanoproducts Facilitate exchanges, partnerships, and research planning MC Roco, 02/11/08
19 Reserves
20 National Nanomanufacturing Network origins The Four Nanomanufacturing NSECs Center for Hierarchical Manufacturing (CHM) - U. Mass Amherst/UPR/MHC/Binghamton Center for High-Rate Nanomanufacturing (CHN) - Northeastern/U. Mass Lowell/UNH Center for Scalable and Integrated Nanomanufacturing (SINAM) - UC Berkeley/UCLA/UCSD/Stanford/UNC Charlotte Center for Nanoscale Chemical-Electrical-Mechanical Manufacturing Systems (Nano-CEMMS) - UIUC/CalTech/NC A&T 20
21 NNI-Industry Consultative Boards for Advancing Nanotech CCR Key for development of nanotechnology, Reciprocal gains NNI-Electronic Industry (SRC lead), 10/ Collaborative activities in key R&D areas 5 working groups, Periodical joint actions and reports NSF-SRC agreement for joint funding; other joint funding NNI-Chemical Industry (CCR lead) Joint road map for nanomaterials R&D; Report in working groups, including on EHS Use of NNI R&D results, and identify R&D opportunities NNI Organizations and business (IRI lead) Joint activities in R&D technology management 2 working groups (nanotech in industry, EHS) Exchange information, use NNI results, support new topics NNI Forestry and paper products (AF&PA lead, 4/2007), 10/2004- Workshop / roadmap for R&D Exchange information M.C. Roco, 02/23/2008
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