ACULYN Excel. CEET meeting 03-05/06/2014. Dow.com. The Dow Chemical Company
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1 ACULYN Excel CEET meeting 03-05/06/2014 The Dow Chemical Company Dow.com
2 ACULYN Excel, high-performing suspending agent Dow s new suspension aid helps formulators provide consumers multi-functional body washes exhibiting low ph and thus mildness to the skin while exhibiting good clarity. Broad Compatibility Globally approved ACULYN Excel Efficient in suspending visual cues Clear formulations Versatility with surfactants Viscosity built 2
3 ACULYN Excel suspension aid offers clarity and efficient suspension whatever the ph ACULYN Excel NTU: 41.5 «Acrylates Copolymer» 1 NTU: «Acrylates Crosspolymer-4» NTU: 29.4 «Acrylates Copolymer» 2 NTU: 105 ACULYN Excel NTU: 13.0 Acrylates Crosspolymer -4 NTU: 18.0 ACULYN Excel NTU: 18.0 Acrylates Crosspolymer -4 NTU: 6.6 Clear Hazy Clear Blueish At ph 5.0, 12% surfactant (SLES-CAPB), 2.2% ai polymer Suspension and clarity No suspension At ph 5.0, 15% surfactant (SLES-CAPB), 2.2% ai polymer Suspension and clarity No suspension At ph 6.5, 15% surfactant (SLES-CAPB), 2.2% ai polymer 3
4 1.000E7 ACULYN Excel vs ph Viscosity (Pa.s) E E5 Minimum Viscosity for bubbles suspension CRUX 1 dec ph 4,5 CRUX 1 dec 2,2% ph 5,0 CRUX 1 dec ph 5,5 Crux1 dec 2,2% ph 6,0 CRUX 1 dec ph 6, viscosity (Pa.s) Minimum Viscosity for beads suspension Good to very good suspension properties whatever the ph ph 4.5 ph 5.0 ph 5.5 ph 6.0 ph E E E shear rate (1/s) Shear Rate (1/s) 4
5 % active level required for beads suspension at ph5 ACULYN Excel Rheology Modifier is an affordable solution versus other suspension aids at low ph 2.50% 2.00% 1.50% 1.00% ACULYN Excel Acrylates Crosspolymer-4 ACULYN Excel Rheology Modifier consistently beats the competitive grade in terms of suspension efficiency (lower use levels required) in various surfactant systems. 0.50% 0.00% High Betaine content Low surfactant content Classical SLES/Betaine mild surfactant With cationic polymers 5
6 ACULYN Excel Product Features INCI / CTFA Name Acrylates Copolymer Appearance White liquid emulsion Solids % ph Solubilised Viscosity at 1% (12 rpm, 25C) 2,300 5,500 cps Preservation 0.55% Benzoic acid Shelf Life 18 months Recommended use level 4 8% as is ACULYN Excel is an hydrophobically modified acrylic rheology modifier. ACULYN Excel is compatible with main personal care ingredients present in cleansing products. ACULYN Excel is cold processible. ACULYN Excel is freeze sensitive. These are typical properties, not to be construed as specifications. 6
7 Formulation guidelines later addition of RM recommended for isethionate-containing formulations (need for heat) no impact on clarity nor suspension no impact on clarity nor suspension - water RECOMMENDED PROTOCOL - ACULYN Excel - Anionic surfactant / (Nonionic surfactant) / Amphoteric surfactant - Sodium Hydroxide qs ph>8 - citric acid qs ph specification - (cationic polymer solution) - perfume / preservative / (colorant) / (beads/glitters/...) 7
8 Performance in SLES / CAPB systems ph 5.0 ph 5.0 ph 5.0 Influence of SLES degree of ethoxylation: Conditions: 9% SLES /3% CAPB Influence of SLES/ CAPB ratio Conditions: 3/1: 9% SLES / 3% CAPB 4/1: 9.6% SLES / 2.4% CAPB 5/1: 10% SLES / 2% CAPB Influence of total surfactant content Conditions: 10%: 7.5% SLES / 2.5% CAPB 12%: 9% SLES / 3% CAPB 14%: 10.5% SLES / 3.5% CAPB 17%: 13% SLES / 4% CAPB 8
9 Performance in SLES / CAPB systems Whatever the SLES/CAPB system parameters, clarity and suspension always go in opposite directions the higher the ACULYN Excel use level, the better the clarity 9
10 ACULYN Excel, high-performing suspending agent ACULYN Excel Rheology Modifier is differentiated from industry benchmarks as it is: Able to suspend both beads and bubbles Has a broader surfactants versatility Demonstrates excellent performance to Acrylates Crosspolymer-4 at all ph including low ph values Exhibits similar performance to the industry benchmark (Acrylates Copolymer) at higher ph values thus enabling brand owners who are covering different ph values to select a more versatile suspension aid. 10
11 Thank You
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