: Hydrochloric Acid, 0.1N (0.1M)

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Product code Hydrochloric Acid, 0.1N (0.1M) Date of issue: 07/03/2013 Revision date: 10/11/2017 Supersedes: 06/07/2016 Version: 1.1 : Mixtures : Hydrochloric Acid, 0.1N (0.1M) : LC Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A H315 H319 Full text of H statements : see section 16 Causes skin irritation Causes serious eye irritation 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) : H315 - Causes skin irritation H319 - Causes serious eye irritation : P264 - Wash exposed skin thoroughly after handling P280 - Wear protective gloves, eye protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash it before reuse : None. SECTION 3: Composition/Information on ingredients 3.1. Substances 10/11/2017 EN (English US) Page 1

2 3.2. Mixtures Name Product identifier % GHS-US classification Water (CAS-No.) Not classified Hydrochloric Acid, 37% w/w (CAS-No.) Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 3, H402 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Chronic symptoms : Possible inflammation of the respiratory tract. : Causes skin irritation. : Causes serious eye irritation. : Nausea. Vomiting. : Affection/discolouration of the teeth Immediate medical attention and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Explosion hazard : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Not flammable. : Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting Other information SECTION 6: Accidental release measures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. : Personal precautions, protective equipment and emergency procedures General measures : Try to stop release. Dike and contain spill For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Gloves. Safety glasses. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 10/11/2017 EN (English US) 2/7

3 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Wash exposed skin thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Packaging materials : Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep container closed when not in use. : Strong bases. metals. cyanides. : Do not store in corrodable metal. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH Ceiling (mg/m³) 2.98 mg/m³ ACGIH ACGIH Ceiling (ppm) 2 ppm OSHA OSHA PEL (Ceiling) (mg/m³) 7 mg/m³ OSHA OSHA PEL (Ceiling) (ppm) 5 ppm IDLH US IDLH (ppm) 50 ppm NIOSH NIOSH REL (ceiling) (mg/m³) 7 mg/m³ NIOSH NIOSH REL (ceiling) (ppm) 5 ppm 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure Individual protection measures/personal protective equipment Personal protective equipment: Gloves. Safety glasses. Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: 10/11/2017 EN (English US) 3/7

4 Respiratory protection not required in normal conditions Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph : 1 Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density : 1 Molecular mass Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials metals. Strong bases. cyanides Hazardous decomposition products Hydrogen chloride. : Liquid : Colorless : Odorless : Non flammable. : g/mol : Soluble in water. Soluble in ethanol. Soluble in methanol. :. : None. 10/11/2017 EN (English US) 4/7

5 SECTION 11: Toxicological information Information on toxicological effects Likely routes of exposure Acute toxicity LD50 oral rat LD50 dermal rabbit ATE US (oral) ATE US (dermal) LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Chronic symptoms : Skin and eye contact 700 mg/kg 5010 mg/kg 700 mg/kg body weight 5010 mg/kg body weight mg/kg mg/kg body weight : Causes skin irritation. ph: 1 : Causes serious eye irritation. ph: 1 Based on available data, the classification criteria are not met 3 - Not classifiable Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met. : Possible inflammation of the respiratory tract. : Causes skin irritation. : Causes serious eye irritation. : Nausea. Vomiting. : Affection/discolouration of the teeth. SECTION 12: Ecological information Toxicity LC50 fish mg/l (LC50; 96 h) EC50 Daphnia 1 < 56 mg/l (EC50; 72 h) Persistence and degradability Hydrochloric Acid, 0.1N (0.1M) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) Biodegradability: not applicable. No test data on mobility of the components available. 10/11/2017 EN (English US) 5/7

6 ThOD Persistence and degradability Bioaccumulative potential Hydrochloric Acid, 0.1N (0.1M) Bioaccumulative potential Log Pow 0.25 (QSAR) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Bioaccumulative potential Mobility in soil Ecology - soil May be harmful to plant growth, blooming and fruit formation Other adverse effects Effect on the global warming GWPmix comment Other information : No known effects from this product. : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Hydrochloric Acid, 37% w/w CAS-No % EPA TSCA Regulatory Flag RQ (Reportable quantity, section 304 of EPA's List of Lists) SARA Section 302 Threshold Planning Quantity (TPQ) SARA Section 311/312 Hazard Classes T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA lb 500 lb Immediate (acute) health hazard International regulations CANADA 10/11/2017 EN (English US) 6/7

7 EU-Regulations National regulations US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 10/11/2017 Other information Full text of H-phrases: see section 16: H302 H314 H315 H318 H319 H335 H402 NFPA health hazard NFPA fire hazard NFPA reactivity : None. Harmful if swallowed Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Causes serious eye irritation May cause respiratory irritation Harmful to aquatic life : 1 - Materials that, under emergency conditions, can cause significant irritation. : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health Flammability Physical Personal protection : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 10/11/2017 EN (English US) 7/7