ARDEX A 828. Safety Data Sheet according to Regulation (EU) 2015/830 Date of issue: 2/3/2017 Revision date: Supersedes: Version: 1.
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1 Date of issue: 2/3/2017 Revision date: Supersedes: Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Danish product registration number : Product code : 28512, Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Wall Smoothing Compounds Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Manufacturer Ardex Skandinavia A/S Marielundvej 4 DK Herlev T F ardex@ardex.dk 1.4. Emergency telephone number Emergency number : Giftlinien: Country Organisation/Company Address Emergency number Comment Germany Vergiftungs-Informations- Mathildenstraße (0) For medical information in Freiburg Zentrale German and English language SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Precautionary statements (CLP) Extra phrases : P102 - Keep out of reach of children : Dispose of contents/container in accordance with regional/national/international/local regulations Nordic countries regulation Denmark MAL code : Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 2/3/2017 EN (English) 1/6
2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] calcium sulfate (CAS No) (EC no) Full text of H-statements: see section Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. : Wash skin with plenty of water. : Immediately rinse with water for a prolonged period while holding the eyelids wide open. Get medical advice/attention if you feel unwell. : Rinse mouth. Give nothing or a little water to drink. Do NOT induce vomiting Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Not expected to present a significant hazard under anticipated conditions of normal use. : Non flammable Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity in case of fire Hazardous decomposition products in case of fire : No fire hazard Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting : No specific measures are necessary. : Contain the extinguishing fluids by bunding. Do not allow run-off from fire-fighting to enter drains or water courses. : Ensure that firefighters are protected. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Spilled material may present a slipping hazard For non-emergency personnel Protective equipment : See Heading 7. Emergency procedures : Ventilate spillage area. Measures in case of dust release : Avoid dust formation For emergency responders Protective equipment : For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling : Collect spillage. Additional hazards when processed : See Heading 8. : Recover mechanically the product. On land, sweep or shovel into suitable containers. : Place in a suitable container for disposal in accordance with the waste regulations (see Section 13). 2/3/2017 EN (English) 2/6
3 Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. Do not eat, drink or smoke when using this product. Avoid dust formation. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Does not require any specific or particular technical measures. : Keep only in original container. Store in a dry place. Belgium Limit value (mg/m³) 10 mg/m³ (Calcium (sulfate de) (anhydrate, hemihydrate, dihydrate, gypse); Belgium; Timeweighted average exposure limit 8 h) France VME (mg/m³) 10 mg/m³ (Calcium (sulfate de); France; Timeweighted average exposure limit 8 h; VL: Valeur non réglementaire indicative) United Kingdom WEL TWA (mg/m³) 10 mg/m³ Gypsum inhalable dust; United Kingdom; Time-weighted average exposure limit 8 h; Workplace exposure limit (EH40/2005); Gypsum respirable dust; 4 mg/m³; United Kingdom; Time-weighted average exposure limit 8 h; Workplace exposure limit (EH40/2005) USA - ACGIH ACGIH TWA (mg/m³) 10 mg/m³ (Calcium sulfate; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction) 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves Type Material Permeation Thickness (mm) Penetration Standard Reusable gloves Eye protection: Nitrile rubber (NBR), Butyl rubber, Natural rubber 6 (> 480 minutes) 2 In case of dust production: protective goggles Respiratory protection: In case of inadequate ventilation wear respiratory protection Device Filter type Condition Standard Reusable half mask Type P1 Dust protection Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Powder. Colour : white. Odour : odourless. Odour threshold ph : 8-9 Relative evaporation rate (butyl acetate=1) Melting point Freezing point : 2/3/2017 EN (English) 3/6
4 Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information Bulk density : : : Non flammable : : Water: 2.4 g/l : : : kg/m³ SECTION 10: Stability and reactivity Reactivity No information available about this product Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid No available data Incompatible materials No data available Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard > 1584 mg/kg bodyweight (Rat; OECD 420: Acute Oral toxicity Acute Toxic Class Method; Experimental value) ph: 8-9 ph: 8-9 SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 2/3/2017 EN (English) 4/6
5 LC50 fish mg/l (LC50; 96 h) Persistence and degradability Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD. Biodegradability: not applicable Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential No bioaccumulation. No bioaccumulation data available Mobility in soil Ecology - soil No information available Results of PBT and vpvb assessment This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste treatment methods Waste disposal recommendations : Disposal must be done according to official regulations. : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Refer to manufacturer/supplier for information on recovery/recycling. Empty remaining contents. Entrust the thoroughly decontaminated packaging to a licensed waste-contractor. European List of Waste (LoW) code : mixed construction and demolition wastes other than those mentioned in , and SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user - Overland transport - Transport by sea 2/3/2017 EN (English) 5/6
6 - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference Storage class (LGK) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV GISCODE GEV EMICODE Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) : LGK 13 - Non-combustible solids : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : CP1 - Putty, based on calcium sulphate : EC 1 PLUS - very low emission Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information ARDEX SDS EU This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2/3/2017 EN (English) 6/6
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