MAE 214 FUEL CELL FUNDAMENTALS & TECHNOLOGY. Fuel Cell Introduction
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1 MAE 214 FUEL CELL FUNDAMENTALS & TECHNOLOGY Fuel Cell Introduction NFCRC DR. JACK BROUWER MAE 214 Lecture #1 Spring, 2005 Fuel Cell Introduction History Basic Operation Fuel Cell Stack Fuel Cell Types Fuel Cell System Fuel Cell Advantages and Applications 1
2 Fuel Cell History Sir William Grove, 1839, Reverse Hydrolysis Thomas Bacon, 1950s, Fuel Cell Stack Late 1950s, Alkaline Fuel Cell First Used In Space Program 1960s to Present: Used In Every Manned Space Program 1960s to Present: Other Fuel Cell Types Discovered Phosphoric Acid Solid Oxide Molten Carbonate Proton Exchange Membrane 1970s to Present: Land Applications - Stationary Power Production 1990 to Present: Seriously Considered For Terrestrial Transportation Applications Fuel Cell Basic Operation FUEL CELL FUEL AIR AIR ELECTROCHEMISTRY PRODUCTS ELECTRICITY THERMAL ENERGY EXHAUST SPECIES COMBUSTION FUEL AIR AIR COMBUSTION PRODUCTS THERMAL ENERGY EXHAUST SPECIES 2
3 BASIC OPERATION Continuous battery Fuel and oxidant (air) supplied - never needs charging Reverse hydrolysis - convert hydrogen to water Ionic transport through electrode-electrolyte assembly Electrode-electrolyte assembly - sandwich BASIC OPERATION 2e Load Fuel In Oxidant In Positive Ion or Negative Ion 1/2 O 2 H O 2 H O 2 Depleted Fuel and Product Gases Out Anode Electrolyte (Ion Conductor) Depleted Oxidant and Product Gases Out Cathode 3
4 Basic Operation: Fuel Cell Basic Operation: Fuel Cell 4
5 Basic Operation: Fuel Cell Triple Phase Boundary (TPB) Reactions Hydrogen Fuel Only (Most Basic Reactions) H + 2e 1/2 O 2 + 2H + 2e - O 5
6 TRIPLE PHASE BOUNDARY Interface between gas phase, electrode and electrolyte surfaces Place where electrochemistry actually takes place (molecular level) Increasing the available TPB is how one increases power density ELECTRODE ELECTROLYTE GAS PHASE 2-D Rendering of one fuel cell compartment Triple Phase Boundary (TPB) Larminie and Dicks,
7 Fuel Cell Introduction History Basic Operation Fuel Cell Stack Fuel Cell Types Fuel Cell System Fuel Cell Advantages and Applications FUEL CELL STACK Increase voltage to useful levels Bundle or stack many electrode-electrolyte assemblies together Stack 7
8 Fuel Cell Stack Larminie and Dicks, 2003 Fuel Cell Stack Larminie and Dicks,
9 Fuel Cell Stack Larminie and Dicks, 2003 Fuel Cell Stack Larminie and Dicks,
10 Fuel Cell Stack Larminie and Dicks, 2003 Fuel Cell Stack Larminie and Dicks,
11 Fuel Cell Stack Larminie and Dicks, 2003 Fuel Cell Introduction History Basic Operation Fuel Cell Stack Fuel Cell Types Fuel Cell System Fuel Cell Advantages and Applications 11
12 Fuel Cell Types Various types of Fuel Cell technology Characterized by electrolyte material PAFC MCFC SOFC PEMFC AFC Electrolyte Operating Temperature H 3 PO 4 ~ 200 C Molten Carbonate Salt ~ 650 C Ceramic YSZ (or LSGM) C ( C) Sulfonic -acid Polymer (or PBI) C (160 o C) KOH/ O C Fuels / Reformate /CO/ Reformate /CO/CH 4 / Reformate / Reformate Reforming External External/ Internal External/ Internal External Oxidant Electrical Efficiency (LHV)* O 2 /Air 36-45% CO 2 /O 2 / Air 45-55% * Based on natural gas operation (with reformation) O 2 /Air 40-50% O 2 /Air 32-40% O 2 /Air 32-40% Depleted fuel and product gases out SOFC PAFC and PEMFC Fuel in MCFC AFC Fuel Cell Types e Load O O O 2 CO 2 O H + O 2 O O 2 CO 3 CO 2 O 2 H (OH) 2 O O 2 2 Depleted oxidant & product gases out 1000 o C ( o C) 200 o C o C (160 o C) o C o C Oxidant in Anode Electrolyte (ion conductor) Cathode 12
13 Fuel Cell Types Throughout MAE 214 course: Touch on all fuel cell types Will focus instruction on one high temperature and one low temperature fuel cell Proton Exchange Membrane (PEMFC) Solid Oxide (SOFC) Both are solid-state fuel cells These are the two types of fuel cells currently receiving the most attention Government funding Industry and Market funding Rapid technology advancement today Fuel Cell Introduction History Basic Operation Fuel Cell Stack Fuel Cell Types Fuel Cell System Fuel Cell Advantages and Applications 13
14 Fuel Cell System FUEL CELL POWER PLANT Fuel cell stack Fuel processing Reformer and gas clean-up Electric power conversion inverter and power conditioner Balance of plant heat exchangers, controls, valves, fans, Fuel Cell System MAJOR SYSTEM COMPONENTS Fuel processing Source for the hydrogen Water - need energy for hydrolysis Hydrocarbons - consume some of the fuel s energy Technology for conversion Emissions? Reliability Efficiency Cost Power conversion and electronics Direct current (DC) to alternating current (AC) Needed for today s end-use technologies Technology Efficiency Reliability Cost 14
15 Fuel Cell System MAJOR SYSTEM COMPONENTS (CONT D) Air In Controls Air Filter GT Turbine Reliability Exhaust Start GT Combustor Compressor By-Pass Valve Safety Recuperator Blow-Off Air Valve Hydrogen Start Air Solid Oxide Heater Fuel Cell (SOFC) Fuel Integration Desulfurizer AC Direct-Drive Generator DC Inert Gas Cooler Generator Reformed Fuel Flow Anode Exhaust Gas Flow Fuel Reforming Reactor Fuel Fuel By-Pass Flow Valve Rectifier Air In DC Current Out Balance of plant Valves Regulators Seals Plumbing Sensors/displays Heat exchangers Humidifiers / Condensers Fuel Heater Fuel Inlet (Natural Gas) Fuel Cell System Fuel Processor - System design variations Low temperature fuel cell system 15
16 Fuel Cell System Fuel Processor - System design variations High temperature fuel cell system Fuel Cell Introduction History Basic Operation Fuel Cell Stack Fuel Cell Types Fuel Cell System Fuel Cell Advantages and Applications 16
17 Fuel Cell Advantages/Disadvantages ADVANTAGES: Zero To Ultra-low Pollutant Emissions (NOx, SOx, HC, CO) High Fuel-to-Electricity Conversion Efficiency Low Noise Modularity and Applicability to Diverse Applications stationary, mobile, portable, POTENTIAL FOR: High Reliability (No/Few Moving Parts) High Energy Density (e.g., compared to batteries) Power Quality Siting/Licensing Ease Distributed Generation Benefits DISADVANTAGES: Cost, Cost, Cost Track Record Low Power Density (e.g., compared to gas turbine engine) Reliability, Availability, Maintainability, Durability And User Friendliness (RAMDU) Fuel Cell Applications DISTRIBUTED GENERATION Stage: Initial Commercialization High-cost Residential Power Million Homes (> $0.10 / $ /kWhr, $500 Annual Savings New Homes 60% Natural Gas Connection Possible Developing World Market No Electricity - 2 Billion People DG Paradigm may offer cost savings (cellular phone analogy) Plug Power FuelCell Energy Hydrogenics UTC Fuel Cells Ballard-Ebara GM / Hydrogenics Idatech Nuvera Siemens Westinghouse 17
18 Fuel Cell Applications TRANSPORTATION Buses Passenger Vehicles / Light Trucks Electric Bikes Golf Carts Trucks Shipping/Submarines Locomotives Snowmobiles Aircraft Other SCHATZ ENERGY RESEARCH CENTER FORD FOCUS TOYOTA FCHV BOEING BWXT McDermott U.S. Navy POLARIS 440 PRO X RACER NEBUS MANHATTAN SCIENTIFICS BURLINGTON NORTHERN GERMAN TYPE U 212 Fuel Cell Applications GM_Opel Hydrogen 1 Honda FCX V3 Daimler Chrysler NeCar 4 Mazda Demio Nissan FCV Toyota FCHV Ford P2000 H2 BMW 700 Series GM Precept 18
19 Fuel Cell Applications PORTABLE POWER Low Power Remote (Hearing Aids, Smoke Detectors, Hotel Locks, Etc.) DCH / Enable PDAs Pagers Wireless Handsets/ Cellular Markets Laptop Computers Power Tools Toshiba Manhattan Scientifics Smart Fuel Cells Casio Fraunhofer ISE Ballard Power Systems Fuel Cell Applications Scooters Electric Wheelchair Camping Lanterns Medical Devices Lawnmowers Digital Cameras / Handheld Cameras Dedicated Handheld Game Devices Portable Signs Manhattan Scientifics Ballard Power Systems H Power Smart Fuel Cell H Power Ball Aerospace 19
20 Fuel Cell Introduction History Basic Operation Fuel Cell Stack Fuel Cell Types Fuel Cell System Fuel Cell Advantages and Applications Fuel Cell Introduction Introductory Course Meant to be multi-disciplinary Mechanical engineering Aerospace engineering Chemical engineering Materials science Electrical engineering Chemistry Physics Social Sciences Several lecturers throughout quarter Prof. Jack Brouwer Prof. Scott Samuelsen Prof. Dan Mumm 20
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