Parylene A superior coating
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- Egbert Hood
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1 Parylene A superior coating A polymer coating superior to all other conventional coatings When reliability is your highest priority Chemical resistant Biocompatible Complete Surface Conformability Pore free, thickness 1-50µm Parylene on the tip of a pencil Conventional coating
2 Parylene History "It is well known that huge investments made in technology during the exciting days of space exploration in the late 1960s through the 1970s led to unprecedented breakthroughs in many scientific and ancillary areas. One of the latter was the use of a thin, vacuum-deposited polymer known as Parylene to protect electronics assemblies and other components from the rigors of operation beyond the earth's atmosphere. The parylene film was isolated and qualified in the late 1940s by Michael Mojzesz, University of Manchester in England. William Franklin Gorham, Union Carbide Corp., proposed an industrial vapour deposition process to produce Parylene film. In February 1965, Union Carbide announced the commercial availability of the new polymeric coating together with a unique vacuum method for film application.
3 Background ParaTech Coating INC. CA USA Est in California. License and material from Union Carbide Cores, PCB for space and aviation. Union Carbide patent ends Himont introduces Galxyl 1988 exclusive distributor of Galxyl Previously part owner of Paratech Scandinavia, from 2015 co-operation, no ownership
4 PTCS Factory in Järfälla, outside of Stockholm Sweden. In Sweden since 1999, today: 6 employees. ESD protected production area ( EPA) Supplier of coating service, equipment, and raw material. Until today supplier of coating service to over 400 customers in Europe. Owner and mother company HP Etch AB, Järfälla Sweden
5 The Parylene Process Polymer Substrate in ambient temperature Dimer Vaporizing 140 C Turns in to gas Monomer Pyrolyze 650 C Pyrolysis is chemical reaction that involves breakdown of larger molecules into smaller molecules in presence of heat. (Vacuum pump) Coating is built molecule by molecule Coating in vacuum Good penetration Cold trap Dimer Monomer Polymer
6 PTC Equipment Service Coating Manufacturing, sales of equipment and parylene raw material
7 Parylene Properties Liquid coating Parylene Uniform and Pinhole Free Stress Free, Elastic Dielectric Strength (200V/µm) Wear Resistant Bio compatible Resistant to Chemicals and Solvents Good Protection from Moisture, Water and Gases No Contaminants or Solvents that Effects the Substrates During the Process Low weight Low friction Transparent - film of optical quality Particle retention Low out gassing Fungus and bacteria resistant Radiation Resistant Resists high and low temperatures (-200 to +200 C) RoHS Compliant MIL-I-46058C Approved USPXXII, Class VI Biocompatibility rating IPC-CC-830B Compliant FDA approval of parylenecoated devices is well documented UL approval
8 Service Coating Outdoor Electronics Bobbins Semiconductors Pacemaker Sensors in Hostile Conditions Space and Military Electronics for High Reliability Corrosion Protection of Metal Surfaces Catheters Ferrite cores Flow meter components Relays Chemical Resistance for Rubber and Plastics Reducing friction on Rubber Transformers Thermistors Pacemakers Probes Electrical Isolation Wear Resistant Layer for Rubber Keypads Application examples Coca cola machine
9 Conformal Coating Comparison Ratings: E = excellent VG = very good G = good M = moderate L = low
10 Application examples GSM/SMS unit with motion detectors The unit is be mounted in a paper recycling bin without service for 3 years. When the first units was put into service several units had problems with humidity during rainstorms. Because of a tight time schedule there was no time for a redesign so by parylene coating the complete unit the original design could be kept.
11 Application examples Temperature sensor for a respirator air pump The temperature sensor fitted to the cold drier got very wet due to condensation when operating in a humid environment. (East Asia) To ensure a problem free operation all 3 temperature sensors in the compressor was parylene coated with 17µ of parylene C. In volume since Year 2000.
12 Application examples Inner sleeve for leg prosthesis The inner sleeve for this leg prosthesis is made of a very sticky rubber material which made it almost impossible to slip the sleeve into position without lubrication. With parylene coating on the outside no additional lubrication was needed
13 Application examples Valve membrane A Viton valve membrane in a gas flow controller had problems with the viton sticking to the metal valve seat. The sticking made the control of the gas flow less accurate. A parylene coating of the viton cured the problem and gave the valve excellent characteristics. O-rings O-rings has been Parylene coated for different reasons. One is to reduce friction during assembly Another is a need to increase resistance to chemical attack.
14 Application examples PCB with EMC shielding A radio transmitter for very demanding outdoor use had to have the electronics protected from humidity. The electronics on the PCB is protected with a EMCshielding. Due to the parylene possibility to penetrate through small holes the thickness of the coating inside the EMC-shielding is approx. 90% of the outside thickness. 56 Kr/pcs, batch of 300
15 Sub marine motor electronic
16 Cooling plate This aluminium cooling plate is used in a device for biological cultivatvion
17 PCB for Cleaning Robot This PCB is the controle unit in a fully automatic cleaning robot for pig stables. The environment is very harsh. Humidity and corrosive fumes from the manure attacks everything. By Parylene coating the PCB operation is trouble free since Kr/pcs, batch of 30-50
18 Diesel fuel tank optical level sensor The plastic material in the sensor head could not withstand the diesel fuel. By parylene coating the sensor head, the problem was solved 150 Kr/pcs, batch of cable has to be masked
19 Power suply for portable concrete saw This 24V power supply is used in a HF power supply for a portable concrete saw. Concrete mixed cooling water can reach the electronics which causes problems. The customer had tried potting compound to fill the whole power supply. This added weight, (which is critical for a portable machine) and limited heat transfer from the supply. And it was expensive! By Parylene coating the power supply they can use a standard off the shelf supply in a very hostile environment 450 Kr/pcs, batch of 50
20 Position sensor in gear box The tip of the position sensor is made of a plastic material that could not withstand the oil in the gearbox. By using parylene coating the customer could still use their preferred sensor 60 Kr/pcs, batch of cable has to be masked
21 Silicone rubber mebran, friction reduction Silicone rubber is very sticky, making it hard during assembly or in contact with moving parts. A 2 µ thin layer of parylene solves the problem by reducing the friction. Parylene also protects from chemical attack. 3 Kr/pcs, batch of 2000
22 Wireless stand alone water meter This device is used to measure water consumtion. It is a stand alone device which need no service for 5 years. Our customer is providing the measurement service, problems sometimes occured when fitted in bathrooms due to humidity, By parylene coating the PCB s original design could be kept. 22 Kr/pcs, batch of 500 in panels with 5 pcs in each. No masking or cleaning
23 Power supply and diods
24 Masking of PCB Electronics
25 Military Aircraft Electronics
26 FAQ What is the main advantages of using Parylene? It provides a smooth, even and very thin effective layer of protection. A very effective shield against corrosion, moisture, acid, oil, grease etc. Often eliminates the use of potting or lacquering. How thick / thin can you coat? From 0,01µ to 50 microns, normally max 25μm How much voltage can parylene isolate? 5 kv / 25um. It is not entirely linear, but approximately 200 V / microns In what temperature can it be used? Resists high and low temperatures from +200 to -200 C What does it cost? It depends on how much preparation that is needed. A circuit board can be masked at 1 min. or 1 hour. The raw material and machine time is a significant factor, but usually it is the mask that is most expensive. Can I coat basically anything? A. In principle, yes. But adhesion can vary from different materials and that may require different types of pretreatment. Also the surface texture will affect the adhesion. A matt surface gives better adhesion than polished. Can I remove parylene for instance repair? Parylene can not be resolved by conventional varnishes. But can be removed mechanically with eg. micro-blasting. Can I get parylene in different colors? No.
27 Efficient coating with Paralyne Polymer We offer a unique coating technique with a multipurpose, nontoxic item, developed to the space and military industry. Paralyne coating has a thickness of only 1-30 Microns, but provides a very effective shield against corrosion, moisture, acid, oil, grease etc. and often eliminates the use of potting or lacquering. Further the polymer provides an effective insulation in limited spaces. INNOVATIVE ASPECTS AND MAIN ADVANTAGES The technique provides a smooth, even and very thin, but very effective layer of protection. The polymer is completely non-toxic and therefore also very suitable for applications within the food industry. MARKET APPLICATION EMS, Automotive, Automation, Robotics, Machine Builders, Windmill Builders, Offshore Industry, Space, Food Industry etc. Often used for pre treatment: Isopropyl Alcohol isomer of propyl alcohol with antibacterial properties HH
Think Thin Film. Innov Days Plasturgie 26 mars 2015 Lyon. Slide 1
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