Conductive glass (NTA glass )
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1 Art Beam Co. Ltd.
2 Conductive glass (NTA glass ) Nano Technology Assorted Glass Japanese Patent No (applied for 2001, granted 2006) Vanadate glass and its manufacturing method Patent holder: Tetsuaki Nishida (Professor, Kinki University, Faculty of Humanity-Oriented Science and Engineering) License granted (No. 8389, registered in the Patent Registry on January 15, 2007) NTA glass Registered trademark (registered in 2006 by Tokai Industry) Registration number: Kinki University Nishida Laboratory 2
3 Features of NTA glass Conventional conductive glass Conventional NTA glass (black) Substrate NTA glass Conductive solid glass Thin film Substrates and processed products Thin film Powder
4 Major Advantages Conductive Low softening point NTA glass Lead- and bismuth-free Noncorrosive Use for soldering Processable by a variety of methods From machining to Focused Ion Beam (FIB)
5 Properties of NTA glass (standard) and comparison Electrical resistivity 30 Ω cm or less Glass transition point 400 C Note 10-4 Ω cm or less depending on constituents and formula References: Properties of glass (Source: Rikagaku Jiten ) Deformation point 460 C 500 C C Expansion coefficient 9.32 x 10-6 /K 20 C C x 10-6 /K Hardness 460 kg/mm 2 Approx. 5.5 (Mohs hardness) 5-7 (Mohs hardness) Transmittance 0 % 200 nm - 2,400 nm Reflectivity Thermal conductivity % 12 % 0.88 W/m K At 26 C Thermal diffusivity mm 2 /s At 26 C Specific heat (heat capacity) J/g K At 26 C Compared to aluminum with reflectivity taken as 100% 350 nm nm Compared to aluminum with reflectivity taken as 100% 750 nm - 2,600 nm Density 3.78 g/cm 3 At 26 C g/cm 3 Young's modulus Gps 5-9 Mps Modulus of rigidity 32 Gpa Poisson's ratio 0.286
6 Focused Ion Beam (FIB) Micromachining Cross-view image: Pattern of 100 nm width, 200 nm depth Machining conditions: Accelerating voltage of 40 kv, current of 11 pa/cm 2 Micromachining at the order of 10 nm Aspect ratio 1:10 High-speed machining (at more than five times the speed of aluminum material) Application in MEMS and nano imprint fields
7 Application to Nano Imprint FIB machining of NTA glass Resin coating Imprinting Main material for nano imprint technology Pattern 7
8 Glass Powder (1) Glass frit for metal paste (2) NTA glass paste
9 (1) Glass frit for metal paste Low softening point, lead- and bismuth-free Glass composition Properties Mean particle diameter Linear expansion coefficient Uses Composite oxide of V, Ba and Fe Black powder ( m) (x 10-7 / C) Electrodes, sintering aids for electrodes, conductive bonds, antistatic agents, etc. 9
10 (2) NTA glass paste (Pro Glass VP) Properties Viscosity Application method Recommended drying temperature Recommended standard operating temperature Blackish brown paste (Pa s) Screen printing 130 C -150 C for 10 to 20 minutes Temperature rise/fall: 20 C - 40 C per minute Peak temperature: Maintained at 460 C C for 5 to 10 minutes
11 Applications of NTA glass paste Encapsulant and sealant for LSI, etc. Conductive and noncorrosive
12 Application of NTA glass paste: Heat glass Conductive, noncorrosive, used for soldering
13 Other Applications Example of machining products: Ionizer discharge nozzle Conductive Noncorrosive (no dust produced) 13
14 NTA glass nanoparticles (spherical, 100 nm or less) Nanoparticles formed by use of radio-frequency thermal plasma
15 Offering dispersion samples tailored to customer s needs NTA nanoparticle dispersion (1) (DAA) (solid content 10%) Tokai Industry NTA nanoparticle dispersion (2) (DAA) (solid content 10%) Tokai Industry
16 Types and applications of MSCoating films Ti (titanium) coating Si (silicon) coating Aims Anti-abrasion Anti-corrosion, anti-erosion Appearance Tic layer Si layer Cross-sectional image Substrate S45C 10 m Substrate SUS m Applications Metal coating Molds, jigs, turret punch press and chucks * Thickness: 5-15 m * Hardness: 1,200-2,500 HV * Surface roughness: 6-20 mrz Anti-corrosion/Anti-erosion parts * Thickness: 5-10 m * Hardness: 1,000 HV * Surface roughness: 1-4 mrz
17 Art Beam Chromium-free chemical conversion coating AT-21 Chromium-free chemical conversion coating AT-21 is an environmentallyfriendly coating liquid that forms an anti-corrosive film on zinc and zinc alloy plates without the use of chromium compounds. Advantages of AT-21 coating - Environmentally-friendly Chromium-free coating - Anti-corrosive Equal to trivalent chromium coating - Cost More cost-effective than trivalent chromium coating Major constituents of AT-21 AT-21 chemical conversion c oat ing Galvanized layer Fe substrate Cross-sectional view of chemical conversion coating The major constituents of AT-21 are tannin and citric acid. Tannin is made from persimmon juice, and has anti-corrosion and antiseptic effects. This makes AT-21 an environmentally-friendly coating.
18 We look forward to doing business with you. Art Beam Co. Ltd. Joint development with
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