JINGLE BELLS. SECTION 1: Identification. SECTION 2: Hazard(s) identification Identification Product form Product name CAS No Product code

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name CAS No Product code JINGLE BELLS Date of issue: 10/03/2017 Revision date: 10/03/2017 Version: 1.0 : Mixture : JINGLE BELLS : N/A 1.2. Recommended use and restrictions on use 1.3. Supplier : Emergency telephone number Emergency number : Chemtrec - USA: International: SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 4 Serious eye damage/eye irritation Category 2 Skin sensitization, Category 1 Combustible liquid Causes serious eye irritation May cause an allergic skin reaction 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : Combustible liquid May cause an allergic skin reaction Causes serious eye irritation : Keep away from heat/sparks/open flames/hot surfaces. - No smoking Avoid breathing dust/fume/gas/mist/vapors/spray Wash hands, forearms and face thoroughly after handling Contaminated work clothing must not be allowed out of the workplace Wear protective gloves/protective clothing/eye protection/face protection If on skin: Wash with plenty of water/ If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Specific treatment (see... on this label) If skin irritation or rash occurs: Get medical advice/attention If eye irritation persists: Get medical advice/attention Wash contaminated clothing before reuse In case of fire: Use media other than water to extinguish Store in a well-ventilated place. Keep cool Dispose of contents/container to Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) 10/03/2017 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification METHYL ANTHRANILATE (CAS No) Eye Irrit. 2, H319 ORANGE SWEET OIL (CAS No) Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 DIETHYL PHTHALATE (DEP) (CAS No) Acute Tox. 3 (Inhalation:vapour), H331 MENTHOL CRYSTALS (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2, H319 METHYL OCTINE CARBONATE (CAS No) Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact Symptoms/effects after eye contact : May cause an allergic skin reaction. : Eye irritation Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : Combustible liquid Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. 10/03/2017 EN (English US) 2/7

3 Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. ACGIH ACGIH TWA (mg/m³) 5 mg/m³ (Diethyl phthalate; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) ACGIH Remark (ACGIH) URT irr 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : PALE YELLOW TO YELLOW Odor : CHARACTERISTIC, MATCHING THE RETAINER SAMPLE. 10/03/2017 EN (English US) 3/7

4 Odor threshold ph Melting point Freezing point Boiling point Flash point : 67 C Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C : :. Relative density : ( ) Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information : Insoluble. Refractive index : ( ) SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE US (vapors) ATE US (dermal) 8600 mg/kg (Rat) > 7940 mg/kg (Rabbit) > 5 mg/l/4h (Rat) 8600 mg/kg body weight 3 mg/l/4h 1600 mg/kg body weight 4500 mg/kg body weight 10/03/2017 EN (English US) 4/7

5 2780 mg/kg body weight 2600 mg/kg body weight LD50 oral rat > 5000 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rabbit > 5000 mg/kg body weight (Rabbit; Experimental value; Equivalent or similar to OECD 402) Skin corrosion/irritation Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : May cause an allergic skin reaction. Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/effects after skin contact Symptoms/effects after eye contact SECTION 12: Ecological information Toxicity Ecology - general : May cause an allergic skin reaction. : Eye irritation. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. LC50 fish 2 17 ppm (LC50; 96 h; Pimephales promelas) EC50 Daphnia 2 52 mg/l (EC50; 48 h) LC50 fish 1 EC50 Daphnia 1 Threshold limit algae μg/l (LC50; Equivalent or similar to OECD 203; 96 h; Pimephales promelas; Flow-through system; Fresh water; Read-across) 0.67 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) 8 mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Desmodesmus subspicatus; Static system; Fresh water; Experimental value) Persistence and degradability Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available Bioaccumulative potential BCF fish (BCF) BCF fish (BCF; 504 h) BCF other aquatic organisms ppb (BCF) BCF other aquatic organisms ppb (BCF) Log Pow Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 10/03/2017 EN (English US) 5/7

6 BCF other aquatic organisms (BCF; BCFWIN) Log Pow (QSAR; KOWWIN) Bioaccumulative potential Potential for bioaccumulation (4 Log Kow 5) Mobility in soil Surface tension N/m (20 C) Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Not subject to reporing requirements of the United States SARA Section 313 CERCLA RQ 1000 lb Not listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA 10/03/2017 EN (English US) 6/7

7 EU-Regulations National regulations US State regulations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 10/03/2017 Full text of H-phrases: H226 H227 H302 H304 H315 H317 H319 H331 H400 H410 Flammable liquid and vapor Combustible liquid Harmful if swallowed May be fatal if swallowed and enters airways Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Toxic if inhaled Very toxic to aquatic life Very toxic to aquatic life with long lasting effects SDS US (GHS HazCom 2012) - Lebermuth This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 10/03/2017 EN (English US) 7/7