1.4. Emergency telephone number :

Transcription

1 Mixed Powder Date of issue: Revision date:12/18/2015 : Version: 6.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet Eurotungstene 9 rue André Sibellas - BP152X Grenoble cedex 09 France tel : +33(0) fax : +33(0) msds-eurotungstene@erametgroup.com 1.4. Emergency telephone number Emergency number : Country Organisation/Company Address Emergency number Comment National Poisons Information Service (Belfast Centre) Royal Victoria Hospital National Poisons Information Service (Birmingham Centre) City Hospital National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Llandough Hospital NPIS Edinburgh (Scottish Poisons Information Bureau) Royal Infirmary of Edinburgh Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre, Wolfson Unit SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Grosvenor Road BT12 6BA Belfast Dudley Road B18 7QH Birmingham Penarth CF64 2XX Cardiff 51 Little France Crescent EH16 4SA Edinburgh Avonley Road SE14 5ER London Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle (UK only), UK only, Monday to Friday, to hours UK only, Monday to Friday, to hours UK only, Monday to Friday, to hours UK only, Monday to Friday, to hours Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Sensitisation Respiratory, Category 1 Sensitisation Skin, Category 1 Carcinogenicity (inhalation) Category 1B Reproductive toxicity, Category 2 Specific target organ toxicity Repeated exposure, Category 1 Hazardous to the aquatic environment Acute Hazard, Category 1 H334 H317 H350i H361f H372 H400 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16 3/3/2016 EN (English) 1/8

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) Child-resistant fastening Tactile warning : Danger GHS08 GHS09 : H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H350i - May cause cancer by inhalation H361f - Suspected of damaging fertility H372 - Causes damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects : P201 - Obtain special instructions before use P260 - Do not breathe dust/fume/gas/mist/vapours/spray P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective clothing, eye protection P284 - [In case of inadequate ventilation] wear respiratory protection P308+P313 - IF exposed or concerned: Get medical advice/attention : No : No 2.3. Other hazards Other hazards not contributing to the classification : Inhalation of dust may cause irritation of the respiratory system. This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Cobalt Powder (CAS No) (EC no) (EC index no) (REACH-no) Iron. (CAS No) (EC no) Copper powder (CAS No) (REACH-no) tungsten carbide powder (CAS No) (EC no) Nickel Powder; [Particle Diameter < 1 mm] (CAS No) (EC no) (EC index no) Full text of H-statements: see section 16 SECTION 4: First aid measures <5 Acute Tox. 4 (Oral), H302 Acute Tox. 1 (Inhalation:dust,mist), H330 Eye Irrit. 2, H319 Resp. Sens. 1B, H334 Skin Sens. 1, H317 Carc. 1B, H350i Repr. 2, H361f Aquatic Acute 1, H400 (M=10) Aquatic Chronic 1, H410 <10 Not classified <10 Aquatic Acute 1, H400 Aquatic Chronic 3, H412 <70 Not classified <25 Skin Sens. 1, H317 Carc. 2, H351 STOT RE 1, H372 Aquatic Chronic 3, H Description of first aid measures First-aid measures general First-aid measures after inhalation : Medical examination necessary even merely on suspicion of intoxication. : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Where appropriate artificial ventilation. Get medical advice/attention. 3/3/2016 EN (English) 2/8

3 First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Wash with plenty of water/... Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. : In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Remove contact lenses, if present and easy to do. Continue rinsing. Consult an ophthalmologist. When in doubt or if symptoms are observed, get medical advice. : If swallowed, rinse mouth with water (only if the person is conscious) Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Chronic symptoms : Allergic reactions. : Cough. Respiratory complaints. May cause sensitisation of susceptible persons. : Allergic reactions. Skin irritation, dermatitis and sensitisation. : Irritating to eyes. : Abdominal pain. Vomiting Indication of any immediate medical attention and special treatment needed No special requirements. SECTION 5: Firefighting measures : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Co-ordinate fire-fighting measures to the fire surroundings. Extinguishing/inerting agent. extinguish by smothering. Foam. ABC-powder. Carbon dioxide (CO2). : Full water jet Special hazards arising from the substance or mixture Fire hazard : In case of fire may be liberated: Metal oxide smoke, toxic Advice for firefighters Precautionary measures fire Firefighting instructions Other information : Co-ordinate fire-fighting measures to the fire surroundings. : In case of fire: Wear self-contained breathing apparatus. : Do not allow run-off from fire-fighting to enter drains or water courses. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Avoid generation of dust For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate area. : Wear breathing apparatus if exposed to vapours/dusts/aerosols. Avoid contact with skin and eyes. Wear personal protection equipment (see chapter 8). : Remove persons to safety Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections : Collect spillage. : Take up dust-free and set down dust-free. Clean contaminated objects and areas thoroughly observing environmental regulations. Retain contaminated washing water and dispose it. : Treat the recovered material as prescribed in the section on waste disposal. See protective measures under point 7 and 8. Treat the recovered material as prescribed in the section on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be exposed to any process in which this product is used. : Provide adequate ventilation as well as local exhaustion at critical locations. Avoid generation of dust. Avoid contact with skin and eyes. Avoid release to the environment. : Do no eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wash hands before break and at end of works. 3/3/2016 EN (English) 3/8

4 7.2. Conditions for safe storage, including any incompatibilities Technical measures Incompatible products Heat and ignition sources Special rules on packaging 7.3. Specific end use(s) : Keep container tightly closed and in a well-ventilated place. : Acid. Oxidising. : Remove all sources of ignition. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Cobalt Powder ( ) : Repeat the labelling if the packaging is divided up. WEL TWA (mg/m³) 0.1 mg/m³ USA - ACGIH ACGIH TWA (mg/m³) 0.02 mg/m³ USA - NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ Iron. ( ) USA - ACGIH ACGIH TWA (mg/m³) 10 mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 10 mg/m³ Nickel Powder; [Particle Diameter < 1 mm] ( ) WEL TWA (mg/m³) 0.5 mg/m³ USA - ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³ (inhalable) 0.1 mg/m³ (soluble) 1.5 mg/m³ (inhalable fraction) USA - NIOSH NIOSH REL (TWA) (mg/m³) mg/m³ USA - OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Respiratory protection : Technical measures and the application of suitable work processes have priority over personal protection equipment. : In case of dust production: protective goggles. Gloves. Dust production: dust mask with filter type P3. In case of dust production: dustproof clothing. : The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. Recommended glove articles. DIN EN 374 : Dust protection eye glasses : Provide adequate ventilation as well as local exhaustion at critical locations. If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn. Recommended respiratory protection articles. Filtering Half-face mask (DIN EN 149) Environmental exposure controls : Do not allow uncontrolled discharge of product into the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Metal powder. Colour : dark grey. Odour : odourless. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : No data available Freezing point : No data available 3/3/2016 EN (English) 4/8

5 Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Viscosity Explosive properties Oxidising properties Explosive limits 9.2. Other information Other properties : No data available : No : Not applicable. : Flammable. : No data available : Insoluble. : not explosive. : Not oxidizing. : Not applicable : Particle size (µm). SECTION 10: Stability and reactivity Reactivity The product is stable at normal handling and storage conditions Chemical stability The product is stable at normal handling and storage conditions Possibility of hazardous reactions The product is stable at normal handling and storage conditions Conditions to avoid Avoid generation of dust Incompatible materials A fire or explosion hazard arises since highly flammable gas (hydrogen) is released when it is in contact with : Strong acid Hazardous decomposition products metallic oxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LC50 inhalation rat (mg/l) Cobalt Powder ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (Vapours - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard > 5 mg/l/4h 550 mg/kg > 2000 mg/kg mg/l/4h ph ph : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : May cause cancer by inhalation. : Suspected of damaging fertility. : Causes damage to organs through prolonged or repeated exposure. 3/3/2016 EN (English) 5/8

6 SECTION 12: Ecological information Toxicity Ecology - general Cobalt Powder ( ) LC50 fish 1 LC50 other aquatic organisms 1 LC50 other aquatic organisms 2 : Very toxic to aquatic life with long lasting effects. > 1.5 mg/l FRESH WATER 0.61 mg/l FRESH WATER 2.32 mg/l (marine water) Persistence and degradability Bioaccumulative potential Log Pow Log Kow not applicable not applicable Cobalt Powder ( ) BCF fish 1 < 10 BCF fish 2 < 10 BCF other aquatic organisms Log Pow Log Kow Bioaccumulative potential Mobility in soil Not required. Not applicable Low. Ecology - soil not applicable Results of PBT and vpvb assessment This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects Other adverse effects : Not dangerous for the ozone layer. SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste treatment methods Sewage disposal recommendations Ecology - waste materials : Disposal must be done according to official regulations. : Waste disposal according to EC directives 75/442/EEC and 91/689/EEC in the corresponding versions, covering waste and dangerous waste. Do not empty into drains. Dispose of this material and its container to hazardous or special waste collection point. : Do not discharge into drains or the environment. : Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : UN proper shipping name Proper Shipping Name (ADR) Transport document description (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 9 Danger labels (ADR) : 9 3/3/2016 EN (English) 6/8

7 : Packing group Packing group (ADR) Environmental hazards Dangerous for the environment Marine pollutant Other information : III : Yes : Yes : No supplementary information available Special precautions for user - Overland transport Classification code (ADR) : M7 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Hazard identification number (Kemler No.) : Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment For the following substances of this mixture a chemical safety assessment has been carried out Cobalt Powder SECTION 16: Other information Indication of changes: according to Regulation (EC) No. 453/2010. Abbreviations and acronyms: ACGIH American Conference of Governmental Industrial Hygienists BAF Bioaccumulation Factor BCF Bioconcentration Factor CAS NOEC NIOSH Chemical Abstract Service No Observed Effect Concentration National Institute of Occupational Safety and Health LD50 Lethal Dose 50 LC50 Lethal Concentration 50 EINECS European Inventory of Existing Commercial Chemical Substances DNEL Derived No Effect Level NOHSC National Occupational Health & Safety Commission OSHA PEL Occupational Safety and Health Administration Permissible Exposure Limits 3/3/2016 EN (English) 7/8

8 PBT PNEC Persistent, Bioaccumulative and Toxic Predicted No Effect Concentration REACH Registration, Evaluation, Autorisation of CHemicals REL SCOEL STOT STP TWA Recommended Exposure Limits Scientific Committee on Occupational Exposure Limits Specific Target Organ Toxicity Sewage Treatment Plant Time Weighted Average vpvb very Persistent and very Bioaccumulative Other information : The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. Full text of H- and EUH-statements: Acute Tox. 1 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 1 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Carc. 1B Carcinogenicity (inhalation) Category 1B Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Repr. 2 Reproductive toxicity, Category 2 Resp. Sens. 1 Sensitisation Respiratory, Category 1 Resp. Sens. 1B Sensitisation Respiratory, Category 1B Skin Sens. 1 Sensitisation Skin, Category 1 STOT RE 1 Specific target organ toxicity Repeated exposure, Category 1 H302 H317 H319 H330 H334 H350i H351 H361f H372 H400 H410 H412 Harmful if swallowed May cause an allergic skin reaction Causes serious eye irritation Fatal if inhaled May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause cancer by inhalation Suspected of causing cancer Suspected of damaging fertility Causes damage to organs through prolonged or repeated exposure Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 3/3/2016 EN (English) 8/8