: SV B/N Surrogate Mix

Transcription

1 Date of issue: 12/02/2015 Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code Product group : Mixture : SV B/N Surrogate Mix : AL : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec : Laboratory Use : Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Phenova 6390 Joyce Dr. Suite Golden, CO - United States T F info@phenova.com Emergency telephone number Emergency number : ChemTel Assistance (US/Canada) ChemTel Assistance (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Carc. 2 H351 Aquatic Chronic 3 H412 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.3; R40 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) No labeling applicable GHS08 : Warning : Methylene Chloride : H351 - Suspected of causing cancer H412 - Harmful to aquatic life with long lasting effects : P273 - Avoid release to the environment P281 - Use personal protective equipment as required P308+P313 - IF exposed or concerned: Get medical advice/attention P405 - Store locked up 16/04/2015 EN (English US) 1/1

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Methylene Chloride (Component) nitrobenzene-d5 (Component) 2-Fluorobiphenyl (Component) (CAS No) (EC no) (EC index no) (CAS No) (EC no) (EC index no) (CAS No) (EC no) Carc. 2, H Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Carc. 2, H351 Repr. 1B, H360F STOT RE 1, H372 Aquatic Chronic 3, H Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 16/04/2015 EN (English US) 2/1

3 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Gently wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep container closed when not in use. Keep container tightly closed and in a well-ventilated place. Keep away from any flames or sparking source. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-Fluorobiphenyl ( ) : Sources of ignition. Direct sunlight. USA OSHA OSHA PEL (TWA) (mg/m³) 450 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 75 ppm USA OSHA OSHA PEL (STEL) (mg/m³) 675 mg/m³ USA OSHA OSHA PEL (STEL) (ppm) 110 ppm 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Either local exhaust or general room ventilation is usually required. : Avoid all unnecessary exposure. Gloves. Protective clothing. Protective goggles. Safety glasses. Hand protection Eye protection Skin and body protection Respiratory protection Other information : Wear chemically resistant protective gloves. Wear suitable gloves resistant to chemical penetration. : Chemical goggles or safety glasses. Safety glasses. : Wear chemically protective gloves, lab coat or apron to prevent prolonged or repeated skin contact. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Colorless. Odor : characteristic. ph Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature 16/04/2015 EN (English US) 3/1

4 Flammability (solid, gas) Relative density Solubility Explosive properties Oxidizing properties Explosion limits : Non flammable 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit ATE CLP (oral) ATE CLP (dermal) 2-Fluorobiphenyl ( ) ATE CLP (oral) LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms 855 mg/kg body weight (Rat; Experimental value) 760 mg/kg body weight (Rabbit; Experimental value) mg/kg body weight mg/kg body weight mg/kg body weight > 2000 mg/kg (Rat; Literature study) > 2000 mg/kg (Rabbit; Literature study) : Suspected of causing cancer. May cause cancer :. 16/04/2015 EN (English US) 4/1

5 SECTION 12: Ecological information Toxicity Ecology - water LC50 fish 1 LC50 other aquatic organisms 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 TLM fish 2 Threshold limit other aquatic organisms 1 Threshold limit algae 1 Threshold limit algae 2 LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 Threshold limit algae 1 Threshold limit algae 2 : Harmful to aquatic life with long lasting effects. 4.3 mg/l (48 h; Oryzias latipes; Non deuterium form) ppm (96 h; Non deuterium form) 4 mg/l (24 h; Daphnia magna; Non deuterium form) 10.3 mg/l (96 h; Skeletonema; Non deuterium form) 92 mg/l (96 h; Brachydanio rerio; Non deuterium form) 35 mg/l (48 h; Daphnia magna; Non deuterium form) 20-24,6 h; Pisces; Non deuterium form ,6 h; Pisces; Non deuterium form ,96 h; Non deuterium form 33 mg/l (168 h; Scenedesmus quadricauda; Non deuterium form) 1.9 mg/l (72 h; Microcystis aeruginosa; Non deuterium form) 193 mg/l (96 h; Pimephales promelas; Flow-through system) mg/l (48 h; Daphnia magna) 220 mg/l (96 h; Lepomis macrochirus; Flow-through system) 1450 mg/l (192 h; Scenedesmus quadricauda; Cell numbers) 550 mg/l (192 h; Microcystis aeruginosa) Persistence and degradability SV B/N Surrogate Mix Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) ThOD BOD (% of ThOD) Persistence and degradability Bioaccumulative potential SV B/N Surrogate Mix Bioaccumulative potential May cause long-term adverse effects in the environment. Not readily biodegradable in water. Biodegradable in the soil. Low potential for adsorption in soil. 0 g O₂/g substance 1.95 g O₂/g substance 0 % ThOD Not readily biodegradable in water. Biodegradable in the soil. Not established. BCF fish 1 15 (672 h; Pimephales promelas; Non deuterium form) BCF fish (42 days; Cyprinus carpio; Non deuterium form) BCF other aquatic organisms 1 24 (Chlorella sp.; Non deuterium form) Log Pow 1.85 (Calculated; 1.86; Experimental value; EU Method A.8: Partition Coefficient) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). BCF fish (Cyprinus carpio; Test duration: 6 weeks) Log Pow 1.25 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Surface tension Ecology - soil Results of PBT and vpvb assessment N/m (20 C) May be harmful to plant growth, blooming and fruit formation Other adverse effects Additional information : Avoid release to the environment 16/04/2015 EN (English US) 5/1

6 SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 2810 UN-No.(IATA) : UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IATA) Proper Shipping Name (IMDG) Transport document description (ADR) Packing group : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. : TOXIC LIQUID, ORGANIC, N.O.S. : TOXIC LIQUID, ORGANIC, N.O.S. : TOXIC LIQUID, ORGANIC, N.O.S. : UN 2810 TOXIC LIQUID, ORGANIC, N.O.S. (dichloromethane( )), 6.1, III, (E) Class (ADR) : 6.1 Classification code (ADR) : T1 Class (IATA) : 6.1 Class (IMDG) : 6.1 Class (ADN) : 6.1 Hazard labels (ADR) : 6.1 Hazard labels (IATA) : Packing group Packing group (ADR) Packing group (IATA) Packing group (IMDG) Packing group (ADN) Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 60 Classification code (ADR) : T1 Orange plates : Special provision (ADR) : 274, 614 Transport category (ADR) : 2 Tunnel restriction code (ADR) : E Limited quantities (ADR) : 5l Excepted quantities (ADR) : E Transport by sea Air transport CAO packing instructions (IATA) : /04/2015 EN (English US) 6/1

7 CAO max net quantity (IATA) : 220L PCA packing instructions (IATA) : 655 PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) PCA max net quantity (IATA) PCA Excepted quantities (IATA) Special provision (IATA) ERG code (IATA) : Y642 : 2L : 60L : E1 : A137 : 6L Inland waterway transport Carriage prohibited (ADN) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. PHV SDS EU Copyright 2015 Phenova, Inc. License granted to make paper copies for internal use. The information contained in this is based on our current knowledge. The information contained in this document should be used only as a guide for appropriate safety precautions and should not be considered to be all inclusive. Users should make their own investigation to determine the suitability of the information for their particular purposes. The document does not represent any guarantee of the properties of the product. Phenova, Inc. shall not be held liable for any damage resulting from the handling or use of this product. Visit the Terms and Conditions of Sale link at for additional terms and conditions of sale. 16/04/2015 EN (English US) 7/1