GTC Tour. Coffeyville Resources Nitrogen Fertilizer. June 17, 2008
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1 GTC Tour of Coffeyville Resources Nitrogen Fertilizer Facility June 17, 2008
2 Coolwater Demonstration Project
3 Coffeyville Nitrogen Plant
4 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
5 Block Flow Diagram Linde ASU Nitrogen Ammonia Synthesis Hydrogen UAN Plant NH 3 Product UAN Product Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
6 Linde Air Separation Unit
7 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Slag Sulfur Recovery H 2 S
8 Refinery Cokers
9 Coke Handling
10 Coke Conveyor and Rod Mill Structure
11 Main and Spare Gasifier Structures
12 M Main Gasifier Vessel
13 Slag
14 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
15 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Raw H 2 CO 2 Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
16 CO 2 Absorber
17 H2S Concentrator and Stripper
18 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Tessenderlo Kerley Sulfur Recovery H 2 S
19 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen CO2 Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification CO2 Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
20 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis UAN Plant UAN Product Hydrogen Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Raw H 2 Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
21 PSA Vessels
22 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis Hydrogen UAN Plant UAN Product Oxygen Quench Gasifier Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
23 Ammonia Synthesis and Refrigeration
24 Syn-gas and Refrigeration Compressors
25 Ammonia Storage Tank
26 Block Flow Diagram NH 3 Product ASU Nitrogen Ammonia Synthesis Ammonia UAN Plant UAN Product Oxygen Quench Gasifier Hydrogen Pressure Swing Absorption (PSA) Recycle Raw H 2 Syn-gas CO Shift/ Scrubbing Gas Cooling CO 2 CO 2 Purification Acid Gas Removal (Selexol) CO 2 Vent Coke Grinding Slurry Preparation Sulfur Recovery H 2 S
27 UAN Plant
28 UAN Rail Loading Facility
29 Operators at work in the control room
30 Nitrogen Fertilizer 101
31 Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants
32 Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants It does not build up in the soil, so it needs to p be applied each growing season
33 Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen.
34 Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen. In 2005, the US produced 8.7 million tons of ammonia.
35 Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen. In 2005, the US produced 8.7 million tons of ammonia. In 2005, the US consumed 14.7 million tons of ammonia.
36 Nitrogen Fertilizer 101 Nitrogen is a basic nutrient for all plants. It does not build up in the soil, so it needs to be applied each growing season. Ammonia is the basic building block for nearly all fertilizers that contain nitrogen. In 2005, the US produced 8.7 million tons of ammonia. In 2005, the US consumed 14.7 million tons of ammonia. Nearly all was produced using natural gas!
37 Nitrogen Fertilizer 102
38 Nitrogen Fertilizer 102 Ammonia cash cost build-up (example) Gas Cost $10 per mmbtu x Gas consumption 32 mmbtu per short ton = Gas cost $320 per short ton + other production costs $20 per ton = Total Cash Cost $340 per ton
39 Nitrogen Fertilizer Market Global market
40 Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US
41 Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US US Production is in decline primarily due to low cost gas overseas
42 Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US US Production is in decline primarily due to low cost gas overseas Due to infrastructure limitations (pipelines, rail cars), domestic plants continue to operate when the demand (and price) support it.
43 Nitrogen Fertilizer Market Global market Ammonia and urea are imported into the US US Production is in decline primarily due to low cost gas overseas Due to infrastructure limitations (pipelines, rail cars), domestic plants continue to operate when the demand (and price) support it. US Demand is set by acres of corn (primarily) and wheat (to a lesser extent).
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