Test Report No. F690101/LF-CTSAYAA

Transcription

1 Test Report No. F690101/LF-CTSAYAA Page 1 of 16 SAMSUNG ELECTRO-MECHANICS CO., LTD. 10 Maeyoung-ro, Yeoungtong-gu Suwon-si, Gyeonggi-do Korea The following sample(s) was/were submitted and identified by/on behalf of the client as:- SGS File No. Product Name : AYAA : MLCC B(X7R) Y(X7S) Z(X7T) TYPE Item No./Part No. : N/A Received Date : Test Period : Test Comments to : By the applicant's specific request, the sampling and testing was performed only for the part indicated in the photo without disassembly. Test Results : For further details, please refer to following page(s) SGS Korea Co., Ltd. Jeff Jang / Chemical Lab Mgr t +82 (0) f +82 (0)

2 Test Report No. F690101/LF-CTSAYAA Page 2 of 16 Sample No. : AYAA Sample Description : MLCC B(X7R) Y(X7S) Z(X7T) TYPE Item No./Part No. : N/A Materials : N/A Heavy Metals Antimony (Sb) With reference to EPA 302(1996), US EPA 6010B(1996), ICP 10 Arsenic (As) With reference to EPA 302(1996), US EPA 6010B(1996), ICP 10 Beryllium (Be) With reference to EPA 302(1996), US EPA 6010B(1996), ICP Cadmium (Cd) With reference to IEC :2013 (Determination of Cadmium by ICP-OES) 0. Lead (Pb) With reference to IEC :2013 (Determination of Lead by ICP-OES) Mercury (Hg) With reference to IEC :2013 (Determination of Mercury by ICP-OES) 2 Hexavalent Chromium (Cr VI) With reference to IEC 62321:2008 (Determination of Hexavalent Chromium by spot test/colorimetric Method using UV-Vis) 1 Flame Retardants-PBBs/PBDEs Monobromobiphenyl With reference to IEC :201 Dibromobiphenyl With reference to IEC :201 Tribromobiphenyl With reference to IEC :201 Tetrabromobiphenyl With reference to IEC :201 Pentabromobiphenyl With reference to IEC :201 Hexabromobiphenyl With reference to IEC :201 Heptabromobiphenyl With reference to IEC :201 Octabromobiphenyl With reference to IEC :201 Nonabromobiphenyl With reference to IEC :201 Decabromobiphenyl With reference to IEC :201 t +82 (0) f +82 (0)

3 Test Report No. F690101/LF-CTSAYAA Page 3 of 16 Sample No. : AYAA Sample Description : MLCC B(X7R) Y(X7S) Z(X7T) TYPE Item No./Part No. : N/A Materials : N/A Flame Retardants-PBBs/PBDEs Monobromodiphenyl ether With reference to IEC :201 Dibromodiphenyl ether With reference to IEC :201 Tribromodiphenyl ether With reference to IEC :201 Tetrabromodiphenyl ether With reference to IEC :201 Pentabromodiphenyl ether With reference to IEC :201 Hexabromodiphenyl ether With reference to IEC :201 Heptabromodiphenyl ether With reference to IEC :201 Octabromodiphenyl ether With reference to IEC :201 Nonabromodiphenyl ether With reference to IEC :201 Decabromodiphenyl ether With reference to IEC :201 Phthalates Benzyl butyl phthalate (BBP) 0 Di-butyl phthalate (DBP) 0 Di-(2-ethylhexyl) phthalate (DEHP) 0 Di-isodecyl phthalate (DIDP) 0 Di-isononyl phthalate (DINP) 0 Di-n-octyl phthalate (DNOP) 0 Di-isobutyl phthalate (DIBP) 0 Di-ethyl phthalate(dep) 0 Di-methyl phthalate (DMP) 0 t +82 (0) f +82 (0)

4 Test Report No. F690101/LF-CTSAYAA Page 4 of 16 Sample No. : AYAA Sample Description : MLCC B(X7R) Y(X7S) Z(X7T) TYPE Item No./Part No. : N/A Materials : N/A Phthalates [di(c7-c11 alkyl)phthalate] linear and branched (DHNUP) 0 [di(c6-c8 alkyl)phthalate] branched (DIHP) 0 Bis(2-methoxyethyl) phthalate (BMP, BMEP, DMEP) 0 Di-iso-pentyl phthalate(dipp) 0 Di-n-hexyl phthalate (DNHP) 0 Di-n-pentyl phthalate(dpp, DnPP) 0 Chlorinated Paraffin Alkanes, C10~13, Short Chain Chlorinated Paraffins(SCCP) With reference to ISO Chlorinated Organic Substances Polychlorinated Biphenyls (PCBs) With reference to US EPA 8082,(US EPA 30C), by GC/MS 3 Polychlorinated terphenyls (PCTs) With reference to US EPA 8082,(US EPA 30C), by GC/MS 3 Polychlorinated Naphthalene (PCN) With reference to US EPA 8081 A(US EPA 30C), by GC/MS Chlorinated Phenols PCP (Pentachlorophenol) with reference to 64 LFGB, B and ISO 17070, GC/MS 0.0 Polymer Identification t +82 (0) f +82 (0)

5 Test Report No. F690101/LF-CTSAYAA Page of 16 Sample No. : AYAA Sample Description : MLCC B(X7R) Y(X7S) Z(X7T) TYPE Item No./Part No. : N/A Materials : N/A Polymer Identification PVC ** FT-IR - Negative Halogen Content Bromine(Br) With reference to EN 1482:2016, IC 30 Chlorine(Cl) With reference to EN 1482:2016, IC 30 Flame Retardants Hexabromocyclododecane (HBCDD) USEPA 340C, LC/MS Other(s) PFOS (Perfluorooctane Sulfonates-Acid/Metal Salt/Amide) US EPA 340C/30C, LC/MS 1 PFOA (Perfluorooctanoic acid) US EPA 340C/30C, LC/MS 1 NOTE: (1) = Not detected.(<mdl) (2) = ppm (3) MDL = Method Detection Limit (4) - = No regulation () Negative = Undetectable / Positive = Detectable (6) ** = Qualitative analysis (No Unit) (7) * = a. The sample is positive for CrVI if the CrVI concentration is greater than 0.13 ug/cm2. The sample coating is considered to contain CrVI. b. The sample is negative for CrVI if CrVI is n.d. (concentration less than 0.10 ug/cm2). The coating is considered a non-crvi based coating. c. The result between 0.10 ug/cm2 and 0.13 ug/cm2 is considered to be inconclusive - unavoidable coating variations may influence the determination. t +82 (0) f +82 (0)

6 Test Report No. F690101/LF-CTSAYAA Page 6 of 16 Picture of Sample as Received: AYAA t +82 (0) f +82 (0)

7 Test Report No. F690101/LF-CTSAYAA Page 7 of 16 Testing Flow Chart for RoHS:Cd/Pb/Hg/Cr 6+ /PBBs&PBDEs Testing Cd/Pb/Hg Mechanic_Sample PBBs/PBDEs Mechanic_Sample Cr 6+ Mechanic_Sample Sample Measurement Sample Measurement Sample Measurement Acid Digestion with Microwave/Hotplate Filtration Residue Total Digestion ICP-AES/AAS/MS DATA Solvent Extraction of the Sample Screen Analysis Concentration/Dilution of Extraction Solution Filtration GC/MS DATA Nonmetallic Material Adding Extraction Solution Heating to 90~9 C for Extraction Filtration and ph Adjustment Adding 1,-Diphenylcarbazide for Color Development UV-Vis DATA The samples were dissolved totally by pre-conditioning method according to above flow chart for Cd,Pb,Hg. Section Chief : Gilsae Yi t +82 (0) f +82 (0)

8 Test Report No. F690101/LF-CTSAYAA Cr6+ Mechanic_Sample Page 8 of 16 Sample Measurement Metallic Material Boiling water extraction (0 ± ) cm2 0 ml DI water Remove sample after boiling for 10 min Filter the solution by 0.4 µm if necessary 1 ml orthophosphoric acid 2 ml as sample blank 2 ml as sample 1 ml diphenylcarbazide aci UV-VIS Absorbance Value <0.1 µg/cm2 0.1 µg/cm2 Absorbance Value 0.13 µg/cm2 Absorbance Value >0.13 µg/cm2 Negative result Inconclusive Positive result t +82 (0) f +82 (0)

9 Test Report No. F690101/LF-CTSAYAA Page 9 of 16 Flow Chart for Inorganic Elements Testing Inorganic Elements Mechanic_Sample Sample Measurement Acid Digestion with Microwave/Hotplate Filtration Residue Total Digestion ICP-AES DATA Major Inorganic Heavy Metals Antimony(Sb), Beryllium(Be), Phosphorus(P), Arsenic(As) etc. t +82 (0) f +82 (0)

10 Test Report No. F690101/LF-CTSAYAA Page 10 of 16 Flow Chart for Halogen Test Sample screening using XRF. Liquid containing water(>80%) Yes No Weigh the samples into the combustion boat. Add absorption solution into the bomb or tube. Admit O2 gas or O2 +Ar2 gas and start the combustion. Allow during absorption of the burnt gas. Dilute the solution (EPA300) Analyze absorbed solution using Ion Chromatography. Data t +82 (0) f +82 (0)

11 Test Report No. F690101/LF-CTSAYAA Page 11 of 16 Flow Chart for PVC Test Sample pretreatment / Separation Flame Test Sample analyzed by FT-IR Check wave number of C-CI Bonding Cl contents check (If necessary) QA / QC review / Check analysis result Data t +82 (0) f +82 (0)

12 Test Report No. F690101/LF-CTSAYAA Page 12 of 16 Flow Chart for PFOS/PFOA Test Sample pretreatment / Separation Sample extraction Concentrate/Dilute Extracted solution Analysis was performed by HPLC/MS QA / QC review / Check analysis result Data t +82 (0) f +82 (0)

13 Test Report No. F690101/LF-CTSAYAA Page 13 of 16 PCBs,PCTs,PCNs Flow Chart Sample 1.0 g Sample Size (3 x 3 x 2) mm 3 Is sample soluble? No Yes Place in a pre-washed test tube Place sample in a pre -weighed paper thimble Add ml of MC/Acetone(6:4) and tightly cap and sonicate for 3hr at 0 Soxhlet extraction for 6 hours with 80 ml of MC/Acetone(6:4) Cool to room temperature, filter(0.4 m) the extract and transfer the filtrate to autosampler vial Cool to room temperature, Concentrate to 1 ml by Rotary Vaccum Evaporator GC/MS Analysis transfer to the ml volumetric flask and make up with MC/Acetone(6:4) to the line t +82 (0) f +82 (0)

14 Test Report No. F690101/LF-CTSAYAA Page 14 of 16 SCCP Analysis Flow Chart Sample pretreatment Sample extraction by organic solvent Concentrate/Dilute Extracted solution GC/ECD analysis t +82 (0) f +82 (0)

15 Test Report No. F690101/LF-CTSAYAA Page 1 of 16 Testing Flow Chart for HBCD Sample pretreatment Sample extraction by organic solvent Concentrate/Dilute Extracted solution LC/MS analysis DATA t +82 (0) f +82 (0)

16 Test Report No. F690101/LF-CTSAYAA Page 16 of 16 Flow Chart for Phthalate Test Sample pretreatment / Separation Sample dissolved / extracted by THF Dilute Extracted solution Analysis was performed by GC/MS Data *** End of Report *** t +82 (0) f +82 (0)