Test Report No. F690101/LF-CTSAYGA

Transcription

1 Test Report No. F690101/LF-CTSAYGA Page 1 of 16 HAESUNGDS CO., LTD. (Seongju-dong) 726 Ungnam-ro, Seongsan-gu Changwon-si, Gyeongnam Korea The following sample(s) was/were submitted and identified by/on behalf of the client as:- SGS File No. Product Name : AYGA : Ag Plating Item No./Part No. : Ag Plating Received Date : Test Period : to Test Results : For further details, please refer to following page(s) SGS Korea Co., Ltd. Jeff Jang / Chemical Lab Mgr t +82 (0) f +82 (0)

2 Test Report No. F690101/LF-CTSAYGA Page 2 of 16 Sample No. : AYGA Sample Description : Ag Plating Item No./Part No. : Ag Plating Materials : Metal Alloy Heavy Metals Cadmium (Cd) With reference to IEC :2013 (Determination of Cadmium by ICP-OES) 0. Lead (Pb) With reference to IEC :2013 (Determination of Lead by ICP-OES) Mercury (Hg) With reference to IEC :2013 (Determination of Mercury by ICP-OES) 2 Hexavalent Chromium (Cr VI)* µg/cm² With reference to IEC :201 (Determination of CrVI by UV-Vis) 0.1 Antimony (Sb) With reference to EPA 302(1996), US EPA 6010B(1996), ICP 10 Beryllium (Be) With reference to EPA 302(1996), US EPA 6010B(1996), ICP 0. Arsenic (As) With reference to EPA 302(1996), US EPA 6010B(1996), ICP 10 Flame Retardants-PBBs/PBDEs Monobromobiphenyl With reference to IEC :201 Dibromobiphenyl With reference to IEC :201 Tribromobiphenyl With reference to IEC :201 Tetrabromobiphenyl With reference to IEC :201 Pentabromobiphenyl With reference to IEC :201 Hexabromobiphenyl With reference to IEC :201 Heptabromobiphenyl With reference to IEC :201 Octabromobiphenyl With reference to IEC :201 Nonabromobiphenyl With reference to IEC :201 Decabromobiphenyl With reference to IEC :201 t +82 (0) f +82 (0)

3 Test Report No. F690101/LF-CTSAYGA Page 3 of 16 Sample No. : AYGA Sample Description : Ag Plating Item No./Part No. : Ag Plating Materials : Metal Alloy Flame Retardants-PBBs/PBDEs Monobromodiphenyl ether With reference to IEC :201 Dibromodiphenyl ether With reference to IEC :201 Tribromodiphenyl ether With reference to IEC :201 Tetrabromodiphenyl ether With reference to IEC :201 Pentabromodiphenyl ether With reference to IEC :201 Hexabromodiphenyl ether With reference to IEC :201 Heptabromodiphenyl ether With reference to IEC :201 Octabromodiphenyl ether With reference to IEC :201 Nonabromodiphenyl ether With reference to IEC :201 Decabromodiphenyl ether With reference to IEC :201 Phthalates Di-butyl phthalate (DBP) 0 Benzyl butyl phthalate (BBP) 0 Di-(2-ethylhexyl) phthalate (DEHP) 0 Di-isobutyl phthalate (DIBP) 0 [di(c6-c8 alkyl)phthalate] branched (DIHP) 0 [di(c7-c11 alkyl)phthalate] linear and branched (DHNUP) 0 Bis(2-methoxyethyl) phthalate (BMP, BMEP, DMEP) 0 Di-isononyl phthalate (DINP) 0 Di-isodecyl phthalate (DIDP) 0 t +82 (0) f +82 (0)

4 Test Report No. F690101/LF-CTSAYGA Page 4 of 16 Sample No. : AYGA Sample Description : Ag Plating Item No./Part No. : Ag Plating Materials : Metal Alloy Phthalates Di-n-octyl phthalate (DNOP) 0 Di-n-hexyl phthalate (DNHP) 0 Di-n-pentyl phthalate(dpp, DnPP) 0 Chlorinated Paraffin Alkanes, C10~13, Short Chain Chlorinated Paraffins(SCCP) With reference to ISO Chlorinated Organic Substances Polychlorinated Biphenyls (PCBs) With reference to US EPA 8082,(US EPA 30C), by GC/MS 3 Polychlorinated terphenyls (PCTs) With reference to US EPA 8082,(US EPA 30C), by GC/MS 3 Polychlorinated Naphthalene (PCN) With reference to US EPA 8081 A(US EPA 30C), by GC/MS Polymer Identification PVC ** FT-IR - Negative Halogen Content Bromine(Br) With reference to EN 1482:2016, IC 30 Chlorine(Cl) With reference to EN 1482:2016, IC 30 Fluorine(F) With reference to EN 1482:2016, IC 30 Iodine(I) With reference to EN 1482:2016, IC 0 Organotin Compounds t +82 (0) f +82 (0)

5 Test Report No. F690101/LF-CTSAYGA Page of 16 Sample No. : AYGA Sample Description : Ag Plating Item No./Part No. : Ag Plating Materials : Metal Alloy Organotin Compounds Tributyltin (TBT) With reference to ISO 1733, GC/MS 0.02 Triphenyltin (TPhT) With reference to ISO 1733, GC/MS 0.02 Dibutyltin (DBT) With reference to ISO 1733, GC/MS 0.02 Dioctyltin (DOT) With reference to ISO 1733, GC/MS 0.02 Tributyltin oxide (TBTO) With reference to ISO 1733, GC/MS 0.02 PFCs Perfluorootanoic acid (PFOA) CEN/TS 1968 : 2010, HPLC/MS 1 PFOS^ CEN/TS 1968 : 2010, HPLC/MS 1 ^ PFOS refer to Perfluorooctanesulfonic acid and its derivatives including Perfluoroctanesulfonic acid, Perfluoroctane sulfonamide, N-Methylperfluoroctane sulfonamide, N-Ethylperfluoroctane sulfonamide, N-Methylperfluoroctane sulfonamidoethanol and N-Ethylperfluoroctane sulfonamidoethanol Flame Retardants Hexabromocyclododecane (HBCDD) USEPA 340C, LC/MS NOTE: (1) = Not detected.(<mdl) (2) = ppm (3) MDL = Method Detection Limit (4) - = No regulation () Negative = Undetectable / Positive = Detectable (6) ** = Qualitative analysis (No Unit) (7) * = a. The sample is positive for CrVI if the CrVI concentration is greater than 0.13 ug/cm2. The sample coating is considered to contain CrVI. b. The sample is negative for CrVI if CrVI is n.d. (concentration less than 0.10 ug/cm2). The coating is considered a non-crvi based coating. c. The result between 0.10 ug/cm2 and 0.13 ug/cm2 is considered to be inconclusive - unavoidable coating variations may influence the determination. t +82 (0) f +82 (0)

6 Test Report No. F690101/LF-CTSAYGA Page 6 of 16 Picture of Sample as Received: AYGA t +82 (0) f +82 (0)

7 Test Report No. F690101/LF-CTSAYGA Page 7 of 16 Testing Flow Chart for RoHS:Cd/Pb/Hg/Cr 6+ /PBBs&PBDEs Testing Sample cutting / weighing Sample Preparation Cd/Pb/Hg/Cr PBBs/PBDEs 6+ Cr Acid Digestion with Microwave/Hotplate Sample Solvent Extraction Nonmetallic Material Metallic Material Filtration Concentration/Dilution of Extraction Solution Dissolving by ultrasonication Digesting at 10~160 Boiling water extraction Solution Residue 1) Alkali Fusion / Dry Ashing 2) Acid to dissolve Filtration GC/MS DATA Digestion at 60 by ultrasonication ph adjustment Separating to get aqueous phase Adding 1,-diphenylcar bazide for color UV-Vis ICP-OES/AAS Adding 1,-diphenylcarbazide for color DATA DATA UV-Vis DATA The samples were dissolved totally at the acid digestion step of the above flow chart for Cd,Pb,Hg Section Chief : Minkyu Park t +82 (0) f +82 (0)

8 Test Report No. F690101/LF-CTSAYGA Page 8 of 16 Flow Chart for Inorganic Elements Testing Inorganic Elements Mechanic_Sample Sample Measurement Acid Digestion with Microwave/Hotplate Filtration Residue Total Digestion ICP-AES DATA Major Inorganic Heavy Metals Antimony(Sb), Beryllium(Be), Phosphorus(P), Arsenic(As) etc. t +82 (0) f +82 (0)

9 Test Report No. F690101/LF-CTSAYGA Page 9 of 16 Flow Chart for Halogen Test Sample screening using XRF. Liquid containing water(>80%) Yes No Weigh the samples into the combustion boat. Add absorption solution into the bomb or tube. Admit O2 gas or O2 +Ar2 gas and start the combustion. Allow during absorption of the burnt gas. Dilute the solution (EPA300) Analyze absorbed solution using Ion Chromatography. Data t +82 (0) f +82 (0)

10 Test Report No. F690101/LF-CTSAYGA Page 10 of 16 Flow Chart for PVC Test Sample pretreatment / Separation Flame Test Sample analyzed by FT-IR Check wave number of C-CI Bonding Cl contents check (If necessary) QA / QC review / Check analysis result Data t +82 (0) f +82 (0)

11 Test Report No. F690101/LF-CTSAYGA Page 11 of 16 Flow Chart for PFOS/PFOA Test Sample pretreatment / Separation Sample extraction Concentrate/Dilute Extracted solution Analysis was performed by HPLC/MS QA / QC review / Check analysis result Data t +82 (0) f +82 (0)

12 Test Report No. F690101/LF-CTSAYGA Page 12 of 16 Organotin Flow Chart Start Sample preparation Sample extraction (Derivatization) Cleanup Concentration Extracted solution Analysis was performed by GC/MS End t +82 (0) f +82 (0)

13 Test Report No. F690101/LF-CTSAYGA Page 13 of 16 PCBs,PCTs,PCNs Flow Chart Sample 1.0 g Sample Size (3 x 3 x 2) mm 3 Is sample soluble? No Yes Place in a pre-washed test tube Place sample in a pre -weighed paper thimble Add ml of MC/Acetone(6:4) and tightly cap and sonicate for 3hr at 0 Soxhlet extraction for 6 hours with 80 ml of MC/Acetone(6:4) Cool to room temperature, filter(0.4 m) the extract and transfer the filtrate to autosampler vial Cool to room temperature, Concentrate to 1 ml by Rotary Vaccum Evaporator GC/MS Analysis transfer to the ml volumetric flask and make up with MC/Acetone(6:4) to the line t +82 (0) f +82 (0)

14 Test Report No. F690101/LF-CTSAYGA Page 14 of 16 SCCP Analysis Flow Chart Sample pretreatment Sample extraction by organic solvent Concentrate/Dilute Extracted solution GC/ECD analysis t +82 (0) f +82 (0)

15 Test Report No. F690101/LF-CTSAYGA Page 1 of 16 Testing Flow Chart for HBCD Sample pretreatment Sample extraction by organic solvent Concentrate/Dilute Extracted solution LC/MS analysis DATA t +82 (0) f +82 (0)

16 Test Report No. F690101/LF-CTSAYGA Page 16 of 16 Flow Chart for Phthalate Test Sample pretreatment / Separation Sample dissolved / extracted by THF Dilute Extracted solution Analysis was performed by GC/MS Data *** End of Report *** t +82 (0) f +82 (0)