Polyamide alloys Presentation

Transcription

1 Polyamide alloys Presentation ORGALLOY polyamide alloys benefit from the best properties of polyamides: mechanical strength, thermal resistance and chemical resistance, whilst offering additional major advantages such as: dimensional stability; constant mechanical properties stable electrical properties resistance to hydrolysis; easy processing; high productivity ORGALLOY products are suitable for all the traditional application sectors of engineering polymers, and may be processed using conventional processing methods for plastics 1

2 Contents Tubes / Mandrels / Profiles / Cables 3 Blow Moulding Of Technical Parts 6 Film and Packaging 8 Moulding of Engineering Parts 10 Processing 1 Nomenclature Guide 15 Applications 16 Orgalloy for Air Duct Applications 17

3 Tubes / Mandrels / Profiles / Cables Standard Units LT 4060 LT T6L DENSITY ISO R1183 g/cm MOISTURE ASORBTION 3 C, 4 hours At equilibrium 3 C in water At equilibrium 3 C/% RH ISO 6 ISO 6 ISO 6 % % % MELT FLOW PROPERTIES (after drying) ISO 1133 g/10 min 5 kg kg MELTING POINT ISO R118 C 0 0 HDT AND VICAT HDT 0.45 MPa HDT MPa Vicat 10 N A method Vicat 10 N B method THERMAL EXPANSION CTLE (from 0 C to 60 C) Along flow direction Across flow direction FLEXURAL TEST Maimum stress (D/C)* Young's Modulus (D/C)* TENSILE TEST Young's Modulus Creep Young's Modulus 1 hour Yield stress Strain at yield Strength Strain at break CHARPY IMPACT With notch 3 C (D/C)* With notch 3 C With notch 0 C (D/C)* With notch 0 C ISO R75 ISO R75 ISO 306 ISO 306 TMS Perkin Elmer ISO 178 ISO 178 ISO R57 ISO 8991 ISO R57 ISO R57 ISO R57 ISO R57 C C C C 1.E05 MPa MPa MPa MPa MPa % MPa % / /0 ISO 179/1Af ISO 179/1Ae ISO 179/1Af ISO 179/1Ae kj/m kj/m kj/m kj/m NC NC NC NC NC/NB NC/NB HARDNESS Shore D/ISO ELECTRICAL PROPERTIES Tracking resistance (Kc) Surface resistivity Volume resivtiviy Dielectric strength (1mm) Dissopation factor Tangent Delta 100 Hz 1000 Hz Hz NFC 6 0 ASTM D57 ASTM D57 ASTM D149 NFC 6 30 NFC 6 30 NFC 6 30 Volts Ohm Ohm.cm 3.1 E E FLAMMABILITY UL 94 Automotive classification Burning speed UL 94 FMVSS 30 FMVSS 30 class mm/miin * (D/C): Dry / After conditioning at 3 C and % relative humidity 3

4 Tubes / Mandrels / Profiles / Cables LE 60LMXV LE 6000 RS 60E10 LE60THM RS 6000 RS kg C /18 /0 / / / 18/13 /40 / /63 00/ /67 300/ > 100 NC/NB /17 /30 / 7/3 3/5 /3 / 16/0 1/14 17/0 1/ E E E E E E E3 13 E3 17 4

5 Tubes / Mandrels / Profiles / Cables Tubes Mandrels Profiles Cables LT 4060 LT T6L LE 60LM XV LE 6000 RS 60 E10 LE 60 THM RS 6000 RS Bending stiffness Orgalloy LE 6000 / LE 60 THM / LE 60 LM XV / LT T6L / RS 6600 Properties TUBES Good cost / performance ratio Easy processability MANDRELS Fleibility Durability Thermal resistance PROFILES Dimensional stability CABLES Dimensional stability Chemical and thermal resistance 5

6 Blow Moulding Of Technical Parts LT 4060 ES Noir T6l LT ES Noir LE 60 HM RS 6015 ES Noir T6L kg kg kg /00 800/0 /34 /100 / NC NC NC NC NC/NB NC/NB /8 / E E

7 Blow Moulding Of Technical Parts MFI 35ºC / 5 kg 35ºC / Melt Strenght Swelling LT 4060 ES Noir T6L LT ES Noir LE 60 HM RS 6015 ES Noir T6L (MPa) Binding stiffness ISO EXTRUSION MACHINE DIVERGENTE DIE PARISON time 1 diameter 1 time diameter Flow (%/s) Reduction of the diameter as a function of time time 3 diameter 3 Definition of Inflation Inflation is the ratio between the parison diameter and the diameter of the die. Melt Strength Melt strength (MS) is the measurement of a product s parison flow during etrusion. Products with an MS approaching are the most suitable for etrusion. 7

8 Film and Packaging LE 60 LM LE 6000 LE C601 LE 60 SF LE 60 HM LE 60 THM RS 6000 R 60 ES /8 /6 / /800 / /800 / /8 /34 /100 /40 / /63 00/000 73/63 00/ > NC/NB /3 /30 / /30 / /9 /1 /8 /0 /3 / 16/0 1/ /0 1/ E E E E E3 13 E3 17 E3 17 8

9 Film and Packaging LE 60 LM LE 6000 LE C601 LE 60 SF LE 60 HM LE60 THM RS 6000 R 60 ES Viscosity Medium Medium Medium Low Medium Medium Low Low Blown film Film Hollow vessels Injection moulding Bending stiffness ISO 178 MFI 35ºC / 5 kg Properties of a 40 μm film Standards Units R 60 ES LE 6000 LE 60 THM Tensile strength m.d Stress at yield Elongation at yield Stress at break Elongation at break ISO R 57 3:95 MPa % MPa % Tensile strength t.d Stress at yield Elongation at yield Stress at break Elongation at break ISO R 57 3:95 MPa % MPa % Tear resistance Melt direction Transverse direction NFT cn cn Dart test NFT Method A Method B g g > 360 << 31 > > 360 << 31 Food Contact A number of specific ORGALLOY grades conform to the European regulations concerning materials in contact with foodstuffs. For more information please contact your nearest sales office. 9

10 Moulding of Engineering Parts LT 4060 LE 6000 RS60 E10 RS 6000 RS 6600 RS 6010 RS 660 RS 6030 RS 6630 RS 6635 A kg C C C C > > > /00 / /800 61/ 18/13 73/63 00/000 75/67 300/ / /3000 /160 /51 04/ / / /700 /40 / > NC NC NC NC /30 / 7/3 3/5 16/0 1/14 17/0 1/13 0/1 19.5/0 /16 /10 0/ 18/19 18/0 17/ /.5 /0 4.9 E E E E E E E E E E E E E15.1 E E E E3 17 E3 17 D3 6 B3 10

11 Moulding of Engineering Parts LT 4060 LE6000 RS60E10 RS6000 RS6600 RS6010 RS 660 RS6030 RS6630 RS6635 Grade Standard Impact modified G.F. reinforced Glass Fiber % 0% 0% 0% 0% 0% 10% 0% 30% 30% 35% (MPa) Binding stiffness ISO

12 Processing I Injection Drying system (recommended) Injection shrinkage and postshrinkage rates of main ORGALLOY grades // : in the flow direction : across the flow direction Fan gate 0.9 mm Plate mm *Measured after complete cooling 1

13 Processing II Tube, Mandrels, Cables Etrusion TUBES / MANDRELS / PROFILE EXTRUSION RANGE A comprehensive range for tube etrusion. These products are particulary suitable for high speed etrusion. Arkema can recommend specific equipment for enhanced performance. Series RS products can also be etruded into profiles ( RS6010 / RS ). 13

14 Processing III Film Etrusion 1) Blown film Drying system (recommended) ) Threelayer film ORGALLOY PE TRILAYER FILM Etrusion conditions ( KIEFEL Line ) FILM CONSTRUCTION * Lacqtène 1003 FE 3 d = 0,93 MFI = 0,3 (190 C,16 Kg) EXTRUSION MACHINES ø L/D 9 for PE machines ø 60 L/D 9 for ORGALLOY machine diegap: 1. mm blowup ratio:.1 14

15 Nomenclature Guide Fleible grades LT 4060 LT LT...ES Blowmoulding grades LT...T6L Heat stabilized Semifleible grades LE 60.. material PA6 based LE 60 THM LE 60 HM } Stiffness variations LE 60 LM LE... XV LE... SF Plasticized grades High fluidity grades Rigid grades R 60 ES Blown film grade RS 60.. PA6 based material RS 66.. PA6.6 based material RS.. 30 G.F. reinforced grades (+ rate%) RS.. E10 Impact modified RS... ES Blowmoulding grades 15

16 Applications Engineering components Film and packaging Hollow vessels Tubes and profiles Automotive Packaging Hollow vessels Tubes Sport Technical film Engine air intake Mandrels Industry Dimensional stability Chemical resistance Low density High productivity Agriculture Barrier property MAIN PROPERTIES Chemical, thermal and mechanical resistance Easy processability on PE etruder Sequential blow moulding Easy processability Thermal resistance Chemical resistance Fleible / rigid association Cables Durability Chemical and thermal resistance Dimensional stability Easy processability 16

17 Applications Orgalloy for Air Duct Applications Superior thermal properties Lower density Easy Processing Better cost efficiency What is Orgalloy? PA6 and Polyolefin incompatibles blend Orgalloy PA6 based alloy Intimate miture of materials Compatibilizers guarantee the Morphology and therefore, a constant level of performance Stable over multiple processing runs Polyamide (PA) Barrier Performance to Hydrocarbons Ecellent Chemical Resistance Superior Thermomechanical performance for PFT range Proven eperience in Fuel Systems Polyolefin (PO) Improves PA processability Reduces sensitivity to Moisture and Polar solvents Contributes to enhance PA s barrier performance to HCs Improves impact performance 17

18 Applications ORGALLOY range for Air Ducts LT T6L LE 6000 LE 60 THM RS 6000 RS 60XX RS 66XX LT 4060 RS LT 4060 ES black T6L LT ES black LE LT 00 FLEXURAL MODULUS (MPa) 0 BLOW MOULDING EXTRUSION INJECTION Orgalloy for Air Duct Application 1 a b 1 c b a c 1 Orgalloy OK 18

19 Applications Easier set up with Orgalloy Rubber Metal Rubber Rubber Thermo plastic TRADITIONAL ASSEMBLY More time to assemble Heavier THERMOPLASTIC COMPONENT Less parts to assemble Lower density (OY=1,04 / PA6=1,07 / TEEE=1,16) Orgalloy Properties Shrinkage measured 4h after blow moulding For mm thickness duct, mould 0 C Along flow direction shrinkage =1.6% Across flow direction shrinkage = 1.7% 1.7% 1.6% 19

20 Applications Orgalloy Joining Technique Outstanding Hot Plate Welding WELDING PROCESSING PARAMETERS Hot Plate Temperature C Heating time 710s A WELDING LINE B C Pressure time 710s A B C Joining Technique Orgalloy can be connected to metal via a rubber seal (type acrylic rubber if no high thermal requirements and fluorine rubber for turbo side). In some cases, Orgalloy is also used without sealers. Rubber seal (acrylic rubber type for normal T or fluorine rubber type for turbo side). 0

21 Applications Orgalloy Approval Clean Air Ducts References FORD MONDEO uses Orgalloy LT4060 ES black T6L FORD 认证号 :MP6G S OPEL CORSA DTI uses Orgalloy LT ES black OPEL 认证号 : PORSCHE CAYENNE TURBO uses Orgalloy LT ES black PORSCHE 认证号 :7L A Oil Filler Ducts Refrences PORSCHE 911 TURBO uses Orgalloy LT ES black PORSCHE 认证号 : PORSCHE BOXSTER uses Orgalloy LT ES black PORSCHE 认证号 :

22 Applications Conclusions Best thermal resistance for severe under bonnet conditions Low density Easy switch from competitor products to Orgalloy LT

23 Outstanding dimensional stability Dimensional variations after months at 3 C/% RH Initial state: 4 hours after moulding Very low moisture pickup One major ORGALLOY benefit: Dimensional stability. Stable stiffness. Outstanding chemical resistance No known solvents. Resistance to hydrolysis. Resistance to metallic salts. ORGALLOY 's barrier properties, a remarkable synergy A barrier to polar liquids: water, alcohol... A barrier to gases: O, CO, pentane... A barrier to aromatics: styrene, toluene... 3

24 A global chemical player, Arkema consists of 3 coherent and balanced business segments: Vinyl Products: Chlorochemicals and PVC, Vinyl Compounds, Pipes and Profiles (Alphacan), Industrial Chemicals: Acrylics, PMMA (Altuglas International), Thiochemicals, Fluorochemicals, Hydrogen Peroide, Performance Products: Technical Polymers, Specialty Chemicals (Ceca), Organic Peroides, Additives, Urea Formaldehyde Resins, Agrochemica ls (Cereagri). 4 Arkema develops its activities by combining safety and environmental protection, client proimity, industrial reliability, and competitiveness. Present in over 40 countries with 18,600 employees, Arkema achieves sales of 5. billion euros. With its 6 research centers in France, the United States and Japan, and internationally recognized brands, Arkema holds leadership positions in its principal markets. The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, Arkema epressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement. See MSDS for Health & Safety Considerations. The information contained in this document is based on trials carried out by our Research Centres and data selected from the literature, but shall in no event be held to constitute or imply any warranty, undertaking, epress or implied commitment from our part. Our formal specifications define the limit of our commitment. No liability whatsoever can be accepted by Arkema with regard to the handling, processing or use of the product or products concerned which must in all cases be employed in accordance with all relevant laws and/or regulations in force in the country or countries concerned. DIRCOM 376 FED/06.005/0 Tech Arkema, Société anonyme au capital de euros RCS Nanterre Photos Arkema