Comprehensive Extraction
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1 Comprehensive Extraction Harikrishnan Hari Tulsidas Division of Nuclear Fuel Cycle & Waste Technology, Vice-Chairman, Expert Group on Resource Classification (EGRC) Member, Technical Advisory Group, UNFC International Atomic Energy Agency
2 Comprehensive extraction The term comprehensive extraction was (re)introduced by Dr. Pingru Zhong (China) during an UxP Technical Meeting, September 26-30, 2011 Roots in Russian and Chinese research, 1990s (R. Villas-Bôas) 70% of mine tailing presently seen as a resource for one commodity or other Disturb the ground once extract everything of value in one pass Brought into currency during the follow-on Training Workshop, Marrakech, October 31 November 5, 2011 Focus on unconventional U resources, mainly Phosphates; but also applicable for copper, coal, oil shales Rethink the flowsheet rethink the outcome Already happening See: New 'Comprehensive' Approaches to Uranium Mining and Extraction Approaches-to-Uranium-Mining-and-Extraction.html
3 Unconventional (Green?) U Resources Deposit typesubtype Resources UDEPO (tu) Grade (ppm) UDEPO deposits World deposits Porphyry copper Peralcaline complexes Carbonatites IOCG > 100 Lignite and coal Black shale Several hundred Phosphates Total Sea water ppb Conventional U resources tu (The Red Book 2011)
4 U & REE concentration in phosphates Country Deposit U (ppm) Algeria Djebel Onk 25 Djebel Kouif 100 Australia Duchess China Undifferentiated Egypt Abu Tartur Israel Arad 150 Jordan Shidyia 46 Morocco* Bucraa Khourigba Peru Sechura Saudia Arabia Ma aden Senegal Taiba Syria Khneifiss 75 Tanzania Minjingu 390 Togo 77 to Tunisia USA North Carolina Central Florida North Florida Idaho * U in phosphates estimated to be 6.5 million tonnes Phosphate Ln 2 O 3 (%) rock source Kola, Russia Florida, USA Algeria Morocco Tunisia 0.14 Quebec, 0.18 Canada Ontario, 1.59% (La 2 O 3 +Ce 2 O 3 ) Canada Northern (Total R 2 O 3 ) China In the estimated 70 billion tons of phosphate deposits within the Tethys realm, REE concentration averages 300 ppm. This translates to 2.1 billion tons of REE resources. It has been experimentally proven that REE also can be extracted along with U using appropriate solvents.
5 Operationalizing sustainable development Accurate and transparent management of essential materials (Natural capital/ geological endowment, EGRC-3/2012/INF.1 N.34) Closed (renewable) systems where possible: Efficient use of inputs Energy, water, chemicals Optimisation (and use) of all outputs Waste elimination/ waste as designation of last resource Recycling and reuse UNFC 2009 provides the framework for assessing projects and accounting materials throughout the life-cycle
6 Assessing comprehensive extraction Quantities associated with known and potential resources Contained in Ore concentrates/phosphoric acid/other intermediate products Not extracted; available in Wastes/PG process water Available in raffinite and slags Available in tailings and clays Not Commercial for current extraction Potential for Commercial extraction Commercially Extracted quantities Dissipated in products, wastes, environment Accurate and transparent management of essential materials
7 Sustainable outcome through integrated flow sheet
8 Solvent extraction for Uranium
9 Energy Neutral Phosphate Fertilizer Production Low-grade Phosphate rock Gases Coke & Silicia Ferrophos Thermal Process Phosphorus Slag Heat/ Electricity Incineration Heat High Temperature Gas-cooled Reactor Heat/ Electricity Extraction Rare Earth Elements Reactor fuel U 3 O 8 / 232 Th Phosphate fertilizer Reactor fuel manufacturing
10 Comprehensive extraction lifecycle Conceptual Conceptual Studies Studies Order of Magnitude Scoping Studies Studies Pre-feasibility Pre-feasibility Studies Studies Feasibility Project Studies Implementation Project Feasibility Studies Implementation Mine closure, Remediation and Decommissioning Handover Additional Quantities in Place Extraction Project Non- Commercial Project Potentially Commercial Project Commercial Project Sales Production Development Unclarified Development Pending Justified for Development Approved For Development On Production Extraction Project Development Not Viable Development On Hold Non-Sales Production (Dissipated in wastes, products & environment) ,2, ,2, ,2,3 Accurate and transparent management of essential materials throughout the lifecycle
11 Conceptual study Technical Cooperation projects active in: Tunisia Extraction of U and REE from phosphates ( ) Egypt Extraction of U and REE from strong Phos acid and granites ( ) Philippines Extraction of U and REE from Phos acid; Phosphogypsum utilization ( ) Jordan Extraction of U from Phos acid ( ) Preliminary studies are supported by laboratory and bench level tests. Ore and intermediate product characterization Recovery of commodities (U, REE, S, F ) Environmental and Social-economic Assessment Integrated flow sheet Utilization of process wastes Mine/processing plant assesment
12 Thank you Harikrishnan TULSIDAS Nuclear Technology Specialist Section of Nuclear Fuel Cycle and Materials Division of Nuclear Fuel Cycle and Waste Technology Department Nuclear Energy International Atomic Energy Agency Vienna International Centre, PO Box 100, 1400 Vienna, Austria T: (+43-1) M: (+43) F: (+43-1) Follow us on
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