Annex to the Accreditation Certificate D-PL according to DIN EN ISO/IEC 17025:2005

Transcription

1 Deutsche Akkreditierungsstelle GmbH German Accreditation Body Annex to the Accreditation Certificate D-PL according to DIN EN ISO/IEC 17025:2005 Period of validity: to Holder of certificate: SGS-CSTC Standards Technical Services Co. Ltd. Guangzhou Branch 198 Kezhu Road, Scientech Park, Guangzhou Economic & Technological Development District Guangzhou Guangdong, People s Republic of China Tests in the fields: Chemical and physical-chemical testing of textiles, leather and leather goods, toys, rubber, plastics, food contact material, fashion jewellery, automotive parts, electrical and electronic equipment, as well as articles coming into contact with skin; selected sensory testing of food contact materials, selected chemical testing of food Abbreviations used: see last page Within the given testing field marked with *, the testing laboratory is permitted, without being required to inform and obtain prior approval from DAkkS, the following: the free choice of standard or equivalent testing methods. Within the given testing field marked with **, the testing laboratory is permitted, without being required to inform and obtain prior approval from DAkkS, the following: the modification, development and refinement of testing methods. The testing laboratory is permitted, without being required to inform and obtain prior approval from DAkkS, to use standard or equivalent testing methods listed here with different issue dates for the entire scope of accreditation. The listed testing methods are exemplary. The testing laboratory maintains a current list of all testing methods within the flexible scope of accreditation. 1/38

2 1 Chemical tests of consumer products 1.1 Organic hazardous substances in polymers, metals and electronics using gas chromatography / gas chromatography mass spectrometer detector (GC/GC-MS)** ASTM D DIN EN BS EN DIN EN EPA 3540C EPA 3550C EPA 8082A EPA 8270D Extraction and Determination of Plasticizer Mixtures from Vinyl Chloride Plastics (Modifications: 1) use of GC-MS instead of GC-FID - 2) use of dichloromethane:methanol (1:1) instead of tetra-chloromethane for all plastic samples) (withdrawn standard) Determination of selected organotin compounds by gas chromatography (Modifications: 1) Only applied for textiles, leather, plastics and ink - 2) Extraction by ultrasonic extraction with ethanoic carbamate solution) (withdrawn standard) Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Section Determination of phthalate content) Soxhlet Extraction (apply for Polybrominated Biphenyl (PBB), Polybrominated Diphenyl Ether (PBDE) analysis) Ultrasonic Extraction (apply for Polybrominated Biphenyl (PBB), Polybrominated Diphenyl Ether (PBDE), Hexabromocylododecane (HBCDD), Tetrabromobisphenol A (TBBPA) analysis) Polychlorinated biphenyls (PCBs) by gas chromatography (apply for PCBs, Short Chain Chlorinated Paraffin (C10-13) (SCCP) and Medium Chain Chlorinated Paraffin (C14-17) (MCCP) analysis) Semivolatile organic compounds by gas chromatographyl mass spectrometry (GC/MS) (apply for Short Chain Chlorinated Paraffin (C10-13) (SCCP), Medium Chain Chlorinated Paraffin (C14-17) (MCCP), Polyaromatic hydrocarbons (PAHs), Polybrominated Biphenyl (PBB) and Polybrominated Diphenyl Ether (PBDE), Hexabromocylododecane (HBCDD), Tetrabromobisphenol A (TBBPA) analysis) Period of validity: to /38

3 GZTC CHEM-TOP IEC ISO BS ISO DIN EN ISO ISO ZEK AfPS GS 2014:01 PAK GZTC CHEM-TOP Determination of Tetrabromobisphenol A (TBBPA) by GC-MS and HPLC-MS in solids and liquids Electrotechnical products - Determination of levels of six regulated substances (lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers) (apply for hexavalent chromium) Water quality - Determination of selected organotin compounds - Gas chromatographic method (Modifications: 1) only applied for textiles, leather, plastics and ink 2) Extraction by ultrasonic extraction with ethanoic carbamate solution) Soil quality - Determination of polycyclic aromatic hydrocarbons (PAH) - Gas chromatographic method with mass spectrometric detection (GC-MS) (Modifications: 1) only applied for textiles, leather, plastics and rubber) Testing and Validation of Polycyclic Aromatic Hydrocarbons (PAH) in the course of GS-Mark Certification Testing and Evaluation of Polycyclic Aromatic Hydrocarbons for the Granting of GS Mark Determination organic compound of SVHC in product and material 1.2 Organic hazardous substances in polymers, metals and electronics using high performance liquid chromatography / liquid chromatography mass spectrometer detector (HPLC/LC-MS)** EPA 3540C EPA 3550C Soxhlet Extraction (apply for Alkyphenol (AP), Alkylphenol Ethoxylate (APEO), Perfluorooctane Sulfonates(PFOS) and Perfluorooctyl Acid(PFOA) analysis) Ultrasonic Extraction (apply for Alkyphenol (AP), Alkylphenol Ethoxylate (APEO), Perfluorooctane Sulfonates(PFOS), Perfluorooctyl Acid(PFOA), Bisphenol A (BPA) analysis) Period of validity: to /38

4 EPA 8321B EN EN GZTC CHEM-TOP Solvent-extractable nonvolatile compounds by high performance liquid chromatography/thermospray/mass spectrometry (HPLC/TS/MS) or ultraviolet (UV) detection (apply for Perfluorooctane Sulfonates(PFOS) and Perfluorooctyl Acid(PFOA)analysis by HPLC/MS) Child use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Bisphenol A (BPA)) Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Determination of Bisphenol A (BPA)) Determination organic compound of SVHC in product and material 1.3 Heavy metals in polymers, metals and electronics using inductive-coupled plasma atomic emission spectrometry (ICP-OES)** EPA 3050B EPA 3051A EPA 3052 EPA 6010C EPA 6020A IEC Acid digestion of sediments, sludges, and soils (Modifications: 1) Apply for Lead & Cadmium analysis in metal - 2) Digestion procedures is changed) Microwave assisted acid digestion of sediments, sludges, soils, and oils (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products, paper) Microwave assisted acid digestion of siliceous and organically based matrices (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products, paper) Inductively coupled plasma-atomic emission spectrometry Inductively coupled plasma-mass spectrometry Determination of certain substances in Electrotechnical Products- Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS Period of validity: to /38

5 IEC EN EN GZTC CHEM-TOP Determination of certain substances in Electrotechnical Products- Part 5:Cadmium, Lead and Chromium in polymers and electronics and Cadmium and lead in metals by AAS, AFS, ICP-OES and ICP-MS Child use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Migration of certain elements) Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Determination of Migration of certain elements) Determination inorganic compound of SVHC in product and material 1.4 Heavy metals in polymers, metals and electronics using atomic absorption spectrometry (AAS)** EN 1122 method B BS EN 1122 method B DIN EN 1122 method B IEC IEC EN EN GZTC CHEM-TOP Plastics - Determination of cadmium - Wet decomposition method Determination of certain substances in Electrotechnical Products- Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS Determination of certain substances in Electrotechnical Products- Part 5:Cadmium, Lead and Chromium in polymers and electronics and Cadmium and lead in metals by AAS, AFS, ICP-OES and ICP-MS Child use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Migration of certain elements) Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Determination of Migration of certain elements) Determination inorganic compound of SVHC in product and material Period of validity: to /38

6 1.5 Chromium VI in polymers, metals and electronics using UV-VIS spectrophotometer* IEC ISO BS EN ISO DIN EN ISO EPA 3060A EPA 7196A ISO BS EN ISO EN ISO Electrotechnical products - Determination of levels of six regulated substances (lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers) (apply for hexavalent chromium) Leather - Chemical tests - Determination of chromium VI content Alkaline digestion for hexavalent chromium Chromium, hexavalent (colorimetric) Metallic and other inorganic coatings - Chromate conversion coatings on zinc, cadmium, aluminium-zinc alloys and zincaluminium alloys - Test methods 1.5 Halogen and sulfur in polymers, metals and electronics using Ion chromatography (IC)* EN BS EN Characterization of waste - Halogen and sulfur content - Oxygen combustion in closed systems and determination methods 1.6 Heavy metals and bromine in polymers, metals and electronics using X-ray fluorescence spectrometry * IEC Determination of certain substances in electrotechnical products - Part 3-1: Screening - Lead, mercury, cadmium, total chromium and total bromine by X-ray fluorescence spectrometry Period of validity: to /38

7 1.7 Chemical testing of consumer products, including electrical and electronic equipment GZTC CHEM-TOP ASTM E EN EN Polyvinyl Chloride (PVC) detection in plastic and coating by FT-IR Standard Practice for General Techniques for Obtaining Infrared Spectra for Qualitative Analysis (apply for PVC qualitative analysis) Child use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Nitrosamine and Nitrosatable, Volatile Compound) Child use and care articles Cutlery and feeding utensils - Safety requirements and tests (Determination of Volatile Compound) 2 Chemical tests of textiles, leather and leather goods, toys, rubber and plastics as well as articles coming into contact with skin 2.1 Organic hazardous substances in textile, leather, rubber, plastic using gas chromatography / gas chromatography mass spectrometer detector (GC/GC-MS)** 78/142/EEC /766/EEC ASTM D Council Directive 78/142/EEC of 30 January 1978 on the approximation of the laws of the Member States relating to materials and articles which contain vinyl chloride monomer and are intended to come into contact with foodstuffs (used for textile sample) Commission Directive 80/766/EEC of 8 July 1980 laying down the Community method of analysis for the official control of the vinyl chloride monomer level in materials and articles which are intended to come into contact with foodstuffs (used for textile sample) Extraction and Determination of Plasticizer Mixtures from Vinyl Chloride Plastics (Modifications: 1) use of GC-MS instead of GC - FID - 2) use of dichloromethane:methanol (1:1) instead of tetrachloromethane for all plastic samples) (withdrawn standard) Period of validity: to /38

8 ASU B ASU B DIN DIN EN BS EN DIN EN EN BS EN DIN EN ASU B BS EN DIN EN EN EPA 3540C Investigation of commodity products - Detection and determination of Pentachlorphenol in commodity products especially those made of leather and textile (Reference method) Verification of the use of azo dyes which can release 4-aminoazobenzene Determination of Chlorinated Organic Carriers (COC) in Textile Commodity Article by GC-MS Determination of selected organotin compounds by gas chromatography (Modifications: 1) only applied for textiles, leather, plastics and ink - 2) Extraction by ultrasonic extraction with ethanoic carbamate solution) (withdrawn standard) Textiles - Methods for the determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres Textiles - Methods for determination of certain aromatic amines derived from azo colorants Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene Investigation of consumer goods - Methods for determination of certain aromatic amines derived from azo colorants in textiles - Part 1: Detection of the use of certain azo dyes with and without extraction of the fibre Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Section Determination of phthalate content) Soxhlet Extraction (apply for Polybrominated Biphenyl (PBB), Polybrominated Diphenyl Ether (PBDE) analysis) Period of validity: to /38

9 EPA 3550C EPA 8082A EPA 8270D ISO BS EN ISO DIN EN ISO EN ISO ISO ISO/TS ISO/TS ISO/TS BS EN ISO DIN EN ISO ISO Ultrasonic Extraction (apply for Polybrominated Biphenyl (PBB), Polybrominated Diphenyl Ether (PBDE), Bisphenol A (BPA)). Polychlorinated biphenyls (PCBs) by gas chromatography (apply for PCBs, Short Chain Chlorinated Paraffin (C10-13) (SCCP) and Medium Chain Chlorinated Paraffin (C14-17) (MCCP) analysis) Semivolatile organic compounds by gas chromatographyl mass spectrometry (GC/MS) (apply for Short Chain Chlorinated Paraffin (C10-13) (SCCP), Medium Chain Chlorinated Paraffin (C14-17) (MCCP), Polyaromatic hydrocarbons (PAHs), Polybrominated Biphenyl (PBB) and Polybrominated Diphenyl Ether (PBDE) analysis) Safety of toys - Part 6: Certain phthalate esters in toys and children s products Textiles - Determination of the phthalate content - Tetrahydrofuran method Footwear - Critical substances potentially present in footwear and footwear components - Determination of organotin compounds in footwear materials Footwear - Critical substances potentially present in footwear and footwear components - Determination of phthalates in footwear materials Footwear - Critical substances potentially present in footwear and footwear components - Test method to quantitatively determine dimethyl fumarate (DMFU) in footwear materials Leather - Chemical tests - Determination of pentachlorophenol content (apply for Trichlorophenol (TCP), Tetrachlorophenol (TECP), Pentachlorophenol (PCP) analysis) Period of validity: to /38

10 ASU B ISO ISO ISO BS ISO DIN EN ISO ISO ZEK AfPS GS 2014:01 PAK GZTC CHEM-TOP GZTC CHEM-TOP GZTC CHEM-TOP Leather - Chemical tests - Determination of certain azo colorants in dyed leathers Water quality - Determination of selected organotin compounds - Gas chromatographic method (Modifications: 1) only applied for textiles, leather, plastics and ink - 2) Extraction by ultrasonic extraction with ethanoic carbamate solution) Soil quality - Determination of polycyclic aromatic hydrocarbons (PAH) - Gas chromatographic method with mass spectrometric detection (GC-MS) (Modifications: 1) only applied for textiles, leather, plastics and rubber) Testing and Validation of Polycyclic Aromatic Hydrocarbons (PAH) in the course of GS-Mark Certification Testing and Evaluation of Polycyclic Aromatic Hydrocarbons for the Granting of GS Mark Determination of ortho-phenyl phenol (OPP) in Textile Commodity Article by alkaline digestion / GCMS analysis Determination of Dimethyl fumarate (DMF) in leather, textile, paper and desiccant Determination organic compound of SVHC in product and material 2.2 Organic hazardous substances in textile, leather, rubber, plastic using high performance liquid chromatography / liquid chromatography mass spectrometer detector (HPLC/LC- MS)** ASU B DIN Verification of the use of azo dyes which can release 4-aminoazobenzene Textiles - Detection of Disperse Dyestuffs (apply for Carcinogenic dyestuffs, Allergenic disperse dyestuffs and Navy Blue colourants) Period of validity: to /38

11 EN BS EN DIN EN EN BS EN DIN EN ASU B EPA 3540C EPA 3550C EPA 8321B ISO EN EN Textiles - Methods for the determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene Investigation of consumer goods - Methods for determination of certain aromatic amines derived from azo colorants in textiles - Part 1: Detection of the use of certain azo dyes with and without extraction of the fiber Soxhlet Extraction (apply for Alkyphenol (AP), Alkylphenol Ethoxylate (APEO), Perfluorooctane Sulfonates(PFOS), Perfluorooctyl Acid(PFOA) and Triclosan analysis) Ultrasonic Extraction (apply for Alkyphenol (AP), Alkylphenol Ethoxylate (APEO), Perfluorooctane Sulfonates(PFOS), Perfluorooctyl Acid(PFOA), Triclosan, Tris-(2,3-dibromopropyl)-phosphate analysis) Solvent-extractable nonvolatile compounds by high performance liquid chromatography/thermospray/mass spectrometry (HPLC/TS/MS) or ultraviolet (UV) detection (apply for Perfluorooctane Sulfonates(PFOS) and Perfluorooctyl Acid(PFOA) analysis by HPLC/MS) Leather - Chemical tests - Part 1: Determination of formaldehyde content in leather by high performance liquid chromatography Chile use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Bisphenol A (BPA)) Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Determination of Bisphenol A (BPA)) Period of validity: to /38

12 GZTC CHEM-TOP Determination organic compound of SVHC in product and material 2.3 Heavy metals in textile, leather, rubber, plastic using inductively-couple plasma mass spectrometry (ICP-MS)** EN BS EN DIN EN EPA 3050B EPA 3051A EPA 3052 EPA 6010C EPA 6020A ISO ISO EN Footwear -Test methods for the assessment of ecological criteria (4.1 Determination of total heavy metals content) Acid digestion of sediments, sludges, and soils (Modifications: 1) Apply for Lead & Cadmium analysis in metal - 2) Digestion procedures is changed) Microwave assisted acid digestion of sediments, sludges, soils, and oils (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products, paper) Microwave assisted acid digestion of siliceous and organically based matrices (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products, paper) Inductively coupled plasma-atomic emission spectrometry Inductively coupled plasma-mass spectrometry Leather - Chemical determination of metal content - Part 1: Extractable metals Leather - Chemical determination of metal content - Part 2: Total metal content Chile use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Migration of certain elements) Period of validity: to /38

13 EN GZTC CHEM-TOP GZTC CHEM-TOP Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Determination of Migration of certain elements) Determination inorganic compound of SVHC in product and material Determination of extractable heavy metal (with reference ISO 105 E04:2013 for preparation of perspiration solution) 2.4 Heavy metals in textile, leather, rubber, plastic using atomic absorption spectrometry (AAS)** EN 1122 method B BS EN 1122 method B DIN EN 1122 method B EN 1811+A BS EN 1811+A DIN EN EN Amendment Plastics - Determination of cadmium - Wet decomposition method Reference test method for release of nickel from all post assemblies which are inserted into pierced parts of the human body and articles intended to come into direct and prolonged contact with the skin Method for the simulation of wear and corrosion for the detection of nickel release from coated items 2.5 Chromium VI in textile, leather, rubber, plastic using UV-VIS spectrophotometer* EN 420 Annex B BS EN 420 Annex B DIN EN 420 Annex B EPA 3060A Protective gloves - General requirements and test methods - Annex B: Leather - Chemical tests - Determination of chromium-vi content Alkaline digestion for hexavalent chromium Period of validity: to /38

14 EPA 7196A ASU B ISO BS EN ISO DIN EN ISO ISO Chromium, hexavalent (colorimetric) Investigation of consumer article - Detection of Chromium (VI) in leather by photometric method Leather - Chemical tests - Determination of chromium VI content Personal protective equipment - Test methods for footwear (6.11 Determination of chromium VI content) 2.5 ph value in textiles, leather, rubber, plastic using ph meter BS EN ISO DIN EN ISO EN ISO ISO AATCC BS EN ISO DIN EN ISO EN ISO ISO Textile - Determination of ph of aqueous extract ph of the Water-Extract from Wet Processed Textiles Leather - Determination of ph Period of validity: to /38

15 2.6 Formaldehyde in leather, rubber, plastic using UV-VIS spectrophotometer* BS EN ISO DIN EN ISO EN ISO ISO BS EN ISO DIN EN ISO EN ISO ISO AATCC Japanese Law No JIS L ISO Textiles - Determination of formaldehyde - Part 1: Free and hydrolyzed formaldehyde (water extraction method) Textiles - Determination of formaldehyde - Part 2: Released formaldehyde (vapour absorption method) Formaldehyde Release from Fabric, Determination of Sealed Jar Method Law for the Control of Household Products Containing Harmful Substances (Determination of formaldehyde in textile, leather and liquid sample) Japan Industrial Standards - Test Methods for Resin Finished Textile (only apply for formaldehyde) Leather - Chemical tests - Part 1: Determination of formaldehyde content in leather by colorimetric analysis Period of validity: to /38

16 2.7 Determination of formaldehyde in textiles JIS L BS EN ISO DIN EN ISO EN ISO ISO Japan Industrial Standards - Test Methods for Resin Finished Textile (only apply for formaldehyde) Textiles - Determination of formaldehyde - Part 1: Free and hydrolyzed formaldehyde (water extraction method) 2.8 Determination of organic compounds in textiles, leather and leather goods, toys, rubber and plastics as well as articles coming into contact with skin EN EN ASTM E Child use and care articles - Drinking equipment - Part 2: Chemical requirements and tests (Determination of Volatile Compound) Child use and care articles - Cutley and feeding utensils - Safety requirements and tests (Determination of Volatile Compound) Standard Practice for General Techniques for Obtaining Infrared Spectra for Qualitative Analysis (apply for PVC qualitative analysis) 3 Chemical tests of food contact material with selected sensory testing 3.1 Heavy metals in food contact material using induced-couple plasma (ICP) / atomic absorption spectrophotometer (AAS)** 84/500/EEC & 2005/31/EC AOAC Council Directive 84/500/EEC of 15 October 1984 on the approximation of the laws of the Member States relating to ceramic articles intended to come into contact with foodstuffs (Determination of Leachable Lead and Cadmium) Lead and Cadmium extracted from ceramic ware Atomic absorption spectroscopic method Period of validity: to /38

17 AOAC ASTM C ASTM C BS 6748+A BS DIN EN EN EN EN EN Italian D.M. (04/04/1985) and its amendments Lead and cadmium extracted from ceramic ware - Alternative Atomic Absorption Spectroscopic Method Standard Test Method for Lead and Cadmium Extracted from Glazed Ceramic Surfaces Standard Test Method for Lead and Cadmium Extracted from the Lip and Rim Area of Glass Tumblers Externally Decorated with Ceramic Glass Enamels Specification for limits of metal release from ceramic ware, glassware, glass ceramic ware and vitreous enamel ware Specification for Limits of metal release from painted surfaces of articles, liable to come into contact with foodstuffs Ceramics, glass, glass ceramics, vitreous enamels - Permissible limits for the release of lead and cadmium from articles intended for use in contact with foodstuffs Silicate surfaces Part1: Determination of the release of lead and cadmium from ceramic ware Silicate surfaces Part2: Determination of the release of lead and cadmium from silicate surfaces other than ceramic ware Child use and care articles - Soothers for babies and young children - Safety requirements and test methods (Determination of Migration of certain elements) Paper and board intended to come into contact with foodstuffs - Preparation of a cold water extract (Determination of Leachable heavy metal) Paper and board intended to come into contact with Foodstuffs: Preparation of a hot water extract (Determination of Leachable heavy metal) Paper and board intended to come into contact with Foodstuffs - Preparation of a cold water extract (Determination of Leachable heavy metal) Period of validity: to /38

18 Italian D.M. 21/03/1973 and its amendments JETRO NIOSH NTC NTC ISO ISO SOR/ GZTC CHEM-TOP Disciplina igienica degli imballaggi, recipienti, utensili, destinati a venire in contatto con le sostanze alimentari o con sostanze d uso personale (Determination of Leachable heavy metal) Specifications and Standards for Foods, Food Additives, etc. under the Food Sanitation Act (Abstracts) 2008 (Determination of Heavy Metal, Leachable heavy metal) Lead in Surface Wipe Samples Glassware and Glass Ceramic ware in contact with food - Release of lead and cadmium Permissible Limits and Method of Test Ceramic in the Baking in contact with foods, Cadmium and Lead Liberation, Permissible Limits and Method of Test Ceramic ware, glass-ceramic ware and glass dinnerware in contact with food - Release of lead and cadmium - Part 1:Test method Glass hollowware in contact with food - Release of lead and cadmium - Part1 Test method Glazed Ceramics and Glassware Regulations (Determination of Leachable heavy metal) Determination of migration of heavy metals from metal and alloy in contact with food 3.2 Overall migration from food contact material using balance* EN EN EN Materials and articles in contact with foodstuffs - Plastics - Part 1: Guide to the selection of conditions and test methods for overall migration Materials and articles in contact with foodstuffs - Plastics - Part 2: Test methods for overall migration into olive oil by total Immersion Materials and articles in contact with foodstuffs - Plastics - Part 3: Test methods for overall migration into aqueous food simulants by total immersion Period of validity: to /38

19 EN EN FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR Materials and articles in contact with foodstuffs - Plastics - Part 9: Test methods for overall migration into aqueous food simulants by article filling Materials and articles in contact with foodstuffs - Plastics - Part 14: Test methods for 'substitute tests' for overall migration from plastics intended to come into contact with fatty foodstuffs using test media iso-octane and 95 % ethanol Resinous and polymeric coatings Components of paper and paperboard in contact with aqueous and fatty foods closures with sealing gaskets for food containers melamine-formaldehyde resins in molded articles acrylonitrile/styrene copolymer ethylene-vinyl acetate copolymers Nylon resins Olefin polymer Polycarbonate resins polyethylene phthalate polymers Poly (tetramethylene terephthalate) Urea-formaldehyde resins in molded articles Period of validity: to /38

20 FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR FDA 21 CFR JETRO Mineral reinforced nylon resins polyester resins, cross-linked Polyethersulfone resins polyoxymethylene copolymer Polyoxymethylene homopolymer polyphenylene sulfide resins rubber articles intended for repeated use Specifications and Standards for Foods, Food Additives, etc. Under the Food Sanitation Act (Abstracts) Specific migration from food contact material using gas chromatography / gas chromatography mass spectrometer detector (GC/GC-MS)* EN EN BS EN FDA 21 CFR Child use and care articles - Soothers for babies and young children - Safety requirements and test methods (Determination of Nitrosamine and Nitrosatable) Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 1: Guide to test methods for the specific migration of substances from plastics to foods and food simulants and the determination of substances in plastics and the selection of conditions of exposure to food stimulants (Determination of migration of PAHs, phthalates) Polystyrene and rubber-modified polystyrene (Determination of residual styrene monomer) Period of validity: to /38

21 3.4 Specific migration from food contact material using high performance liquid chromatography / liquid chromatography mass spectrometer detector (HPLC/LC-MS)* EN BS EN EN CEN/TS Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 1: Guide to test methods for the specific migration of substances from plastics to foods and food simulants and the determination of substances in plastics and the selection of conditions of exposure to food stimulants (Determination of PFOS&PFOA) Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 2: Determination of terephthalic acid in food stimulants Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 13: Determination of 2,2-bis(4-hydroxyphenyl)propane (Bisphenol A) in food stimulants 3.5 Specific migration from food contact material using UV-VIS spectrophotometer* ASU L CEN/TS EN EN EN JETRO Evaluation of primary amines in aqueous foodstuffs Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 23: Determination of formaldehyde and hexamethylenetetramine in food stimulants Paper and board intended to come into contact with foodstuffs - Determination of formaldehyde in an aqueous extract Paper and board intended to come into contact with foodstuffs - Preparation of a cold water extract (Determination of Formaldehyde) Paper and board intended to come into contact with Foodstuffs - Preparation of a hot water extract (Determination of Formaldehyde) Specifications and Standards for Foods, Food Additives, etc. Under the Food Sanitation Act (Abstracts) 2008 (Determination of Formaldehyde, Migration of phenol) ISO 4614: Plastics-Melamine-formaldehyde mouldings-determination of extractable formaldehyde Period of validity: to /38

22 3.6 Volatile compound from food contact material using balance* Bundesgesundheitsbl 14 (1971) 265 Bundesgesundheitsbl 46 (2003) 362 EN French Arrêté du 25 Annex III Volatile Organic Matter of plastics Volatile Organic Matter of silicone rubber Child use and care articles - Soothers for babies and young children - Safety requirements and test methods (Determination of Volatile Compound) Volatile Organic Matter of silicone rubber 3.7 Chemical test of food contact material with selected sensory testing ASTM D DIN EN FDA 21 CFR FDA 21 CFR GZTC CHEM TOP Kunststoffe im Lebensmittelverkehr Part B IIIX Standard Test Methods for Density and Specific Gravity (Relative Density) of Plastics by Displacement Sensory analysis-testing of packaging materials and packages for foodstuffs Paper and board intended to come into contact with foodstuffs - Sensory analysis - Part 2: Off-flavour (taint) Nylon resins (Determination of Gravity, Solubility) Mineral reinforced nylon resins (Determination of Ashes) Determination of Chronium in Steel and alloy: Potentiometric method Colour Release Period of validity: to /38

23 4 Chemical tests of toys and fashion jewellery 4.1 Heavy metals in paint, coating, paper, textile, leather, plastic, metal using inducedcouple plasma (ICP) / atomic absorption spectrophotometer (AAS)* ASTM E ASTM E ASTM F EN BS EN DIN EN ISO AS/NZS ISO Health Canada, Product Safety Bureau, Test method C Health Canada, Product Safety Bureau, Test method C Health Canada, Product Safety Bureau, Test method C Standard Test Method for Determination of Lead by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), Flame Atomic Absorption Spectrometry (FAAS), or Graphite Furnace Atomic Absorption Spectrometry (GFAAS) Techniques Standard Practice for Preparation of Dried Paint Samples by Hotplate or Microwave Digestion for Subsequent Lead Analysis Standard Consumer Safety Specification for Toy Safety - Clause (apply for soluble heavy metal and total lead content in paint and surface coating) Safety of toys - Part 3: Migration of certain elements Safety of toys - Safety aspects related to mechanical and physical properties (Determination of migration of certain elements) Determination of Total Lead in Surface Coating Materials by Closed Vessel Microwave Digestion (Modifications: 1) Use ICP-OES instead of AAS) Determination of Leachable Arsenic (As), Selenium (Se), Cadmium (Cd), Antimony (Sb), and Barium (Ba) in Applied Coatings (Modifications: 1) Use ICP-OES instead of ICP-MS) Determination of Total Mercury in Surface Coating Materials and Applied Coatings Period of validity: to /38

24 EN 1122 method B BS EN 1122 method B DIN EN 1122 method B EN 1811+A BS EN 1811+A DIN EN EN Amendment EPA 3050B EPA 3051A EPA 3052 EPA 6010C EPA 6020A CPSC-CH-E CPSC-CH-E Plastics - Determination of cadmium - Wet decomposition method Reference test method for release of nickel from all post assemblies which are inserted into pierced parts of the human body and articles intended to come into direct and prolonged contact with the skin Method for the simulation of wear and corrosion for the detection of nickel release from coated items Acid digestion of sediments, sludges, and soils (Modifications: 1) Apply for Lead & Cadmium analysis in metal - 2) Digestion procedures is changed) Microwave assisted acide digestion of sediments, sludges, soils, and oils (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products and paper) Microwave assisted acid digestion of siliceous and organically based matrices (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products and paper) Inductively coupled plasma-atomic emission spectrometry Inductively coupled plasma-mass spectrometry Standard operation procedure - Determination to total lead in child metal product (including child metal jewelry) Standard Operating Procedure for Determining Total Lead (Pb) in Non-metal Children's Products CPSC-CH-E Standard Operating Procedure for Determining Lead (Pb) in Paint and Other Similar Surface Coatings Period of validity: to /38

25 4.2 Organic hazardous substances in paint, coating, paper, textile, leather, plastic using gas chromatography / gas chromatography mass spectrometer detector (GC/GC-MS)* ASTM D EN BS EN DIN EN EPA 3540C EPA 3550C EPA 8082A EPA 8270D EN BS EN DIN EN ASU B Extraction and Determination of Plasticizer Mixtures from Vinyl Chloride Plastics (Modifications:1) use of GC-MS instead of GC-FID; 2) use of dichloromethane:methanol (1:1) instead of tetrachloromethane for all plastic samples) (withdrawn standard) Child use and care articles - Cutlery and feeding utensils - Safety requirements and tests (Section Determination of phthalate content) Soxhlet Extraction (apply for Polybrominated Biphenyl (PBB), Polybrominated Diphenyl Ether (PBDE)) Ultrasonic Extraction (apply for Polybrominated Biphenyl (PBB), Polybrominated Diphenyl Ether (PBDE)) Polychlorinated biphenyls (PCBs) by gas chromatography (apply for PCBs, Short Chain Chlorinated Paraffin (C10-13) (SCCP) and Medium Chain Chlorinated Paraffin (C14-17) (MCCP) analysis) Semivolatile organic compounds by gas chromatographyl mass spectrometry (GC/MS) (apply for Short Chain Chlorinated Paraffin (C10-13) (SCCP), Medium Chain Chlorinated Paraffin (C14-17) (MCCP), Polyaromatic hydrocarbons (PAHs), Polybrominated Biphenyl (PBB) and Polybrominated Diphenyl Ether (PBDE) analysis) Textiles - Methods for the determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible without extraction Textiles - Methods for the determination of certain aromatic amines derived from azo colorants - Part 2: Detection of the use of certain azo colorants accessible by extracting the fibres Period of validity: to /38

26 ISO ISO ISO ZEK AfPS GS 2014:01 PAK CPSC-CH-C Leather - Chemical tests - Determination of certain azo colorants in dyed leathers Soil quality - Determination of polycyclic aromatic hydrocarbons (PAH) - Gas chromatographic method with mass spectrometric detection (GC-MS) (Modifications: 1) only applied for textiles, leather, plastics and rubber) Testing and Validation of Polycyclic Aromatic Hydrocarbons (PAH) in the course of GS-Mark Certification Testing and Evaluation of Polycyclic Aromatic Hydrocarbons for the Granting of GS Mark Standard Operating Procedure for Determination of Phthalates 4.3 Organic hazardous substances in paint, coating, paper, textile, leather, plastic using high performance liquid chromatography / liquid chromatography mass spectrometer detector (HPLC/LC-MS)* EPA 3540C EPA 3550C EPA 8321B Soxhlet Extraction (apply for Alkyphenol (AP), Alkylphenol Ethoxylate (APEO), Perfluorooctane Sulfonates(PFOS) and Perfluorooctyl Acid(PFOA) analysis) Ultrasonic Extraction (apply for Alkyphenol (AP), Alkylphenol Ethoxylate (APEO), Perfluorooctane Sulfonates(PFOS) and Perfluorooctyl Acid(PFOA) analysis) Solvent-extractable nonvolatile compounds by high performance liquid chromatography/thermospray/mass spectrometry (HPLC/TS/MS) or ultraviolet (UV) detection (apply for Perfluorooctane Sulfonates(PFOS) and Perfluorooctyl Acid(PFOA)analysis by HPLC/MS) Period of validity: to /38

27 EN BS EN DIN EN ASU B ISO ISO Textiles - Methods for the determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible without extraction Textiles - Methods for the determination of certain aromatic amines derived from azo colorants - Part 2: Detection of the use of certain azo colorants accessible by extracting the fibres Leather - Chemical tests - Determination of certain azo colorants in dyed leathers 4.4 Formaldehyde in textile using UV-VIS spectrophotometer* BS EN ISO BS EN ISO BS EN ISO DIN EN ISO EN ISO ISO Textiles - Determination of formaldehyde - Part 1: Free and hydrolyzed formaldehyde (water extraction method) Textiles - Determination of formaldehyde - Part 1: Free and hydrolyzed formaldehyde (water extraction method) 4.5 Chromium VI in paint, coating, textile, plastic using UV-VIS spectrophotometer* EPA 3060A EPA 7196A Alkaline digestion for hexavalent chromium Chromium, hexavalent (colorimetric) Period of validity: to /38

28 5. Chemical tests of automotives and automotive parts with selected sensory testing 5.1 Heavy metals in paint, coating, textile, leather, polymer, metal using inductively-coupled plasma mass spectrometry (ICP-MS) * EPA 3050B EPA 3052 EPA 6010C EPA 6020A IEC IEC Acid digestion of sediments, sludges, and soils (Modifications: 1) Apply for Lead & Cadmium analysis in metal - 2) Digestion procedures is changed) Microwave assisted acid digestion of siliceous and organically based matrices Inductively coupled plasma-atomic emission spectrometry Inductively coupled plasma-mass spectrometry Determination of certain substances in Electrotechnical Products- Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS Determination of certain substances in Electrotechnical Products- Part 5: Cadmium, Lead and Chromium in polymers and electronics and Cadmium and lead in metals by AAS, AFS, ICP-OES and ICP-MS 5.2 Heavy metals in paint, coating, textile, leather, polymer, metal using atomic absorption spectrophotometer (AAS)* BS EN 1122 method B DIN EN 1122 method B EN 1122 method B IEC IEC Plastics - Determination of cadmium - Wet decomposition method Determination of certain substances in Electrotechnical Products- Part 4: Mercury in polymers, metals and electronics by CV-AAS, CV-AFS, ICP-OES and ICP-MS Determination of certain substances in Electrotechnical Products- Part 5: Cadmium, Lead and Chromium in polymers and electronics and Cadmium and lead in metals by AAS, AFS, ICP-OES and ICP-MS Period of validity: to /38

29 5.3 Chromium VI in paint, coating, textile, leather, polymer, metal using UV-VIS spectrophotometer* BS EN ISO DIN EN ISO ISO BS EN DIN EN EN EPA 3060A EPA 7196A IEC ISO BS EN ISO EN ISO Leather - Chemical tests - Determination of chromium VI content Determination of hexavalent chromium in corrosion protection layers- qualitative analysis Alkaline digestion for hexavalent chromium Chromium, hexavalent (colorimetric) Electrotechnical products - Determination of levels of six regulated substances (lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers) (apply for hexavalent chromium) Metallic and other inorganic coatings - Chromate conversion coatings on zinc, cadmium, aluminium-zinc alloys and zincaluminium alloys - Test methods 5.4 Volatile organic compounds of non-metallic materials using gas chromatography / gas chromatography mass spectrometer detector (GC/GC-MS)* EPA 5021A VDA Volatile organic compounds in various sample matrices using equilibrium headspace analysis Determination of Organic Substances As Emitted From Automotive Interior Products Using A 1 M[3] Test Cabinet - Part 1: Standard-Emission Period of validity: to /38

30 VDA VDA Determination of organic emission of non-metallic materials from vehicle interior Thermal desorption analysis of organic emissions for the characterization of non-metallic automobile interior materials 5.5 Volatile organic compounds of non-metallic materials using high performance liquid chromatography / liquid chromatography mass spectrometer detector (HPLC/LC-MS)* VDA Determination of organic substances as emitted from automotive interior products using a 1m3 test chamber 5.6 Formaldehyde in non-metallic materials using UV-VIS spectrophotometer* VDA PV Determination of Formaldehyde from Vehicle Interior with Modified flask method Determination of Formaldehyde emission 5.7 Organic hazardous substances in paint, coating, textile, leather, polymers, metals using gas chromatography / gas chromatography mass spectrometer detector (GC/GC-MS)* IEC Electrotechnical products - Determination of levels of six regulated substances (lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers) (apply for polybrominated biphenyls, polybrominated diphenyl ethers) 5.8 Heavy metals and bromine in paint, coating, textile, leather, polymers, metals using x-ray fluorescence spectrometry* IEC Determination of certain substances in electrotechnical products - Part 3-1: Screening - Lead, mercury, cadmium, total chromium and total bromine by X-ray fluorescence spectrometry Period of validity: to /38

31 5.9 Selected sensory testing of automotives and automotive parts VDA Determination of the odour characteristics of trim material in motor vehicles 6. Physico-chemical tests of food 6.1 Pesticide residues of plant origin using gas chromatography mass spectrometer detector / liquid chromatography-tandem mass spectrometer detector (GC-MS / LC-MS-MS) EN 15662:2008 BS EN 15662:2008 Foods of plant origin-determination of pesticide residues using GC-MS and/or LC-MS/MS following acetonitrile extraction/partitioning and clean-up by dispersive SPE-QuEChERSmethod 6.2 Fat in foods using Gas Chromatography-Flame ionization detector (GC-FID) AOAC :2001 Fat (Total, Saturated, and Unsaturated) in Foods Hydrolytic Extraction Gas Chromatographic Method 7 Test methods applied in connection with national regulations and/or standards 7.1 US Public Law and CPSC 16 CFR Part 1303 ASTM E ASTM E CPSC-CH-E CPSC-CH-E CPSC-CH-E Standard Test Method for Determination of Lead by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), Flame Atomic Absorption Spectrometry (FAAS), or Graphite Furnace Atomic Absorption Spectrometry (GFAAS) Techniques Standard Practice for Preparation of Dried Paint Samples by Hotplate or Microwave Digestion for Subsequent Lead Analysis Standard operation procedure - Determination to total lead in child metal product (including child metal jewellery) Standard Operating Procedure for Determining Total Lead (Pb) in Non-metal Children's Products Standard Operating Procedure for Determining Lead (Pb) in Paint and Other Similar Surface Coatings Period of validity: to /38

32 CPSC-CH-C ASTM F ASTM D EPA 3051A EPA 3052 ASTM E Standard Operating Procedure for Determination of Phthalates Standard Consumer Safety Specification for Toy Safety Clause (apply for soluble heavy metal and total lead content) Extraction and Determination of Plasticizer Mixtures from Vinyl Chloride Plastics (Modifications: 1) use of GC-MS instead of GC-FID - 2) use of dichloromethane:methanol (1:1) instead of tetrachloromethane for all plastic samples) (withdrawn standard) Microwave assisted acide digestion of sediments, sludges, soils, and oils (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products and paper) Microwave assisted acid digestion of siliceous and organically based matrices (apply for Metal, liquid, textiles, leather, ink, plastic, Electronic products and paper) Standard Test Method for Determination of Lead by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), Flame Atomic Absorption Spectrometry (FAAS), or Graphite Furnace Atomic Absorption Spectrometry (GFAAS) Techniques 7.2 Perfluorooctane Sulfonates (PFOS) EPA 3550C EPA 8321B Ultrasonic Extraction (apply for PFOS analysis) Solvent-extractable nonvolatile compounds by high performance liquid chromatography/thermospray/mass spectrometry (HPLC/TS/MS) or ultraviolet (UV) detection (apply for PFOS analysis by HPLC/MS) 7.3 Nonylphenol (NP), Nonylphenol Ethoxylate (NPEO) EPA 3540C Soxhlet Extraction (apply for NP & NPEO analysis) Period of validity: to /38