GTL in the Tail-End Phase of Gas Fields
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1 2 nd International Freiberg Conference on IGCC & XtL Technologies Freiberg, 8 th -12 th May, 2007 GTL in the Tail-End Phase of Gas Fields Focus on Small Size Units P. Bernoux 1, W. Kleinitz 2, C. Ryszfeld 1, E. Zindani 1 1 GAZ DE FRANCE R&D Division 2 GAZ DE FRANCE Produktion Exploration Deutschland GmbH
2 Tail-end production is characterized by High gas recovery factor (> 80%) Flowing pressure below pipeline pressure Non constant (decreasing( decreasing) gas production High surveillance activity Precipitation of NaCl,, CaCO 3 Expensive pipeline monitoring program klei/schm freiberg\vortrag ppt 2 / 19
3 EMS EMS Rütenbrock Hümmling Fehndorf Apeldorn N e t h e r l a n d s Schoonebeek Emlichheim Ringe Ringe Wielen Kalle (Gasfeld a.storage) Ratzel Esche Uelsen Annaveen Rühlertwist Adorf Scheerhorn Georgsdorf Annaveen Rühlermoor Adorf Hohenkörben Hebelermeer Dalum Varloh Meppen Schwefingen Bramberge Lingen Haselünne Kiel Rostock Lübeck Schwerin Wilhelmshaven Hamburg Oldenburg Bremen Berlin Potsdam Hannover Osnabrück Wolfsburg Magdeburg Münster Dessau Cottbus Halle Essen Hagen Kassel Leipzig Mülheim Dresden Bochum Krefeld Erfurt JenaGera Köln Wuppertal Aachen Bonn Zwickau Koblenz Wiesbaden Mainz Frankfurt am Main Offenbach Würzburg Darmstadt Mannheim Nürnberg Saarbrücken Heidelberg Regensburg Pforzheim Stuttgart Karlsruhe Augsburg München Freiburg Itterbeck-Halle Gasfield Gasfield, abandoned Gasstorage Frenswegen Nordhorn Dortmund-Ems-Kanal Dortmund-Ems-Kanal Oilfield Oilfield, abandoned km Bentheim Bentheim EMS EMS klei/schm freiberg\vortrag ppt 3 / 19 Production area of Emsland: structure map
4 Well 1 Well 2 Well 3 Well 4 Compressor GTL klei/schm freiberg\vortrag ppt 4 / 19 Typical evolution of p/z vs. produced gas
5 75 Annual Gas Production Mm³ (Vn) Winter 0 Summer Time, a klei/schm freiberg\vortrag ppt 5 / 19 Typical cyclic production
6 Gas quality (%vol) min max C C C3 < 0.6 C3+ < 0.4 CO N klei/schm freiberg\vortrag ppt 6 / 19 6 gas fields under consideration
7 Production data min max average p (bar) Q (m 3 (n)/h) klei/schm freiberg\vortrag ppt 7 / 19 6 gas fields under consideration
8 Gas Well SAV Compressor T Consumer 50 bar Metering Flare Heater 70 C Cooler (NH 3 ) 0,5 bar 5 C 0 bar 5 C Separator 220 bar 30 C Chiller Condensat Condense Tank 0 bar 125 C Glycol Regeneration Glycol-Pump Heat Exchanger Cooling Chart L T.-Separator 50 bar -18 C Glycol- Oil Separator 5,5 bar 20 C klei/schm freiberg\vortrag ppt 8 / 19 Gas treatment station in the tail-end phase
9 Cooler Heater Well FWKO bar, -18 C 300 bar, 30 C Gas // Gas Heaterchanger L.T.- Seperator Metering Station Consumer 0,5 0,5 bar bar 5 bar bar Transfer Station Pressure Reduction bar, 5 C bar, 10 C 3200m, 95 C 380bar Pipeline klei/schm freiberg\vortrag ppt 9 / 19 Production facilities
10 Expectations from GTL in Tail-End Operating with constant gas flow from the wells Unlocking of hidden gas reserves Non specific chemical composition of liquid hydrocarbon (unrefined syncrude) Use of moveable container units suppression of pipeline monitoring klei/schm freiberg\vortrag ppt 10 / 19
11 Basic data for pre-feasibility study Constant gas outflow: : 3000 m 3 (n)/h Gas pressure: 9 bar Gas quality: average gas fields quality Global approach Based on proven technologies klei/schm freiberg\vortrag ppt 11 / 19
12 Natural Gas Fischer Tropsch Synthesis Naphtha Diesel H 2 + CO (-CH 2 -) n Lube Waxes Syngas Production Product Upgrading & Separation klei/schm freiberg\vortrag ppt 12 / 19 Typical GTL process
13 Natural Gas 3000 m 3 (n)/h Steam H 2 membrane separation 50 C 16 bar Excess H 2 Oil / water separation Tail Gas H 2 :CO = 2.1 (-CH 2 -) n 800 C 250 C 350 C 20 bar 15 bar 70 bar H 2 :CO > 3 Water Syncrude +/- 300 bl/d Sulfur Removal Syngas Production SMR Fischer Tropsch Synthesis Fixed Bed Reactor (Co) Hydrocracking klei/schm freiberg\vortrag ppt 13 / 19 Selected GTL process
14 SMR Appropriate to low pressure Suitable for small capacities H 2 :CO > 3 compared to other technologies POx requires an expensive ASU N 2 ballast if ATR no energy recovery from residual gas klei/schm freiberg\vortrag ppt 14 / 19 Syngas production Selected technology
15 Cobalt Catalyst (vs. Iron) Higher conversion rate Lower by-product water formation H 2 :CO = 2.1 required But hydrocracking required (waxes) Fixed bed reactor Suitable for small capacities Good flexibility Well-known technology Fischer-Tropsch synthesis Selected technology klei/schm freiberg\vortrag ppt 15 / 19
16 Global mass balance Including water & H 2 recycling Input Natural Gas: : 2.3 t/h Water: 0.1 t/h Output Residual gas: : 0.7 t/h Syncrude: : 1.7 t/h Global energy balance Energy efficiency: : ~ 50% klei/schm freiberg\vortrag ppt 16 / 19
17 Realistic technical option Suitable gas quality Simple concept Partial use of by-products but economically unfavourable due to Downscaling Low energy efficiency Short duration for depreciation (duration of unit exploitation ~ years) klei/schm freiberg\vortrag ppt 17 / 19 Conclusion
18 Improvement of energy integration (residual gas, heat exchange optimisation) Innovative modular processes: micro-channel technologies CompactGTL Total / Velocys Considering other Gas-to-Liquids options Methanol MTO, DME? klei/schm freiberg\vortrag ppt 18 / 19 Perspectives
19 Thank you for your attention! GAZ DE FRANCE R&D Division 361, avenue du Président Wilson B.P Saint-Denis La Plaine cedex FRANCE GAZ DE FRANCE Produktion Exploration Deutschland GmbH Waldstrasse Lingen GERMANY klei/schm freiberg\vortrag ppt 19 / 19
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