Silicon Carbide Processing Technology: Issues and Challenges. Michael A. Capano School of ECE, Purdue University May, 2007
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1 Silicon Carbide Processing Technology: Issues and Challenges School of ECE, Purdue University May, 2007
2 Outline Introduction Epitaxial growth of 4H-SiC by hot-wall CVD (Si-face and C-face) 4H-SiC bipolar pin diodes (Si-face 8 o and Si-face 4 o ) Channel mobility in SiC MOSFETs Process-dependence of channel mobility 2 out of 83
3 Potential Applications for SiC Automobiles Radar/Communications Aircraft Spacecraft Power MEMS 3 out of 83
4 Polytypism: A Virtue and Curse of SiC Si C A B C 4 out of 83
5 Stacking Sequence of 3C- and 4H-SiC C Si c-axis 3C 4H B C A B C A B C A B C A 5 out of 83
6 Selected Properties of SiC Si 6H-SiC 4H-SiC 3C-SiC Bandgap (ev) Intrinsic carrier concentration (cm -3 ) 1.5 x x x x 10 2 Electron mobility (cm2/vs) ( c) 85 ( c) 800 ( c) 900 ( c) 1000 Hole mobility (cm2/vs) ? Breakdown field (V/cm) 3 x x x x 10 6 Saturation velocity (cm/s) 1.0 x x x x 10 7 Dielectric constant Thermal conductivity (W/cmK) out of 83
7 Doping of SiC SiC P/N junction p-type (Al, B) n-type (N, P) Methods for doping in-situ (CVD) ion implantation Note: diffusion to achieve selective doping is not an option in SiC Step bunching in implanted SiC Methods for annealing Argon ambient (severe roughening) Step spacing 1 µm Step bunching sensitive to anneal ambient and temperature SiH 4 /Ar ambient (smooth surfaces, narrow process window) Graphite-capped anneal (best results) 7 out of 83
8 4H-SiC Material Growth Bulk growth: Seeded sublimation (Modified-Lely) method Diameter: up to 100 mm; Boule length: 25~30mm Off-cut angle: 4 o or 8 o ; Polarity: C-face or Si-face Epitaxial growth: chemical vapor deposition (CVD), Liquid-phase epitaxy (LPE), Sublimation epitaxy CVD Horizontal cold-wall CVD reactor Horizontal hot-wall CVD reactor Vertical hot-wall CVD reactor Good temperature uniformity Higher growth rate and good film quality 8 out of 83
9 4H-SiC Bipolar Power Devices Pin diodes, Bipolar Junction Transistor (BJT), Insulated-Gate Bipolar Transistor (IGBT), and thyristors. Advantages of bipolar power devices: Low on-resistance due to conductivity modulation High temperature operation (without critical oxide layer) Status of 4H-SiC bipolar power devices: Pin diodes: V F 100 A/cm 2 ; V B = 19.2 kv BJT: β=10~120; BV CEO 9.2 kv IGBT: 20kV p-igbt, 31 A/cm 300 W/cm 2 9 out of 83
10 Material Issues in 4H-SiC Bipolar Power Devices High Breakdown Voltage 4H-SiC pin diode Au Ti/Al P + anode N - drift layer N D ~ low cm -3 Low Specific On-resistance Thickness & Doping Low defect densities N + buffer layer N + 4H-SiC substrate High Minority Carrier Lifetime Ni High Reliability Low Forward Voltage Drift Low Basal Plane Dislocation Density 10 out of 83
11 Horizontal Hot-wall SiC CVD Reactor Temperature: ~1600 o C RF coil Quartz tube Pressure: 50~150 mbar Precursor gases: Pyrometer Thermal insulation SiC substrate Gas outlet To pump SiH 4 (5% in H 2 ) pure C 3 H 8 C/Si ratio Graphite susceptor Carrier gas: H 2 Thermal insulation N-type doping: N 2 P-type doping: Horizontal hot-wall SiC CVD system TMA, B 2 H 6 Purge gas: Ar 11 out of 83
12 4H-SiC CVD Growth Process Temperature Heat up 1100 o C H 2 Clean Clea n H 2 H 2 + C 3 H 8 Etch Etch H 2 + C 3 H 8 ~1600 o C Buffer Layer N + Thick Epilayer N - SiH 4 +C 3 H 8 + H 2 4H-SiC CVD growth process Cool down Time Clean-Etch-Growth Clean to remove moisture H 2 /C 3 H 8 etch to remove polishing damage Highly-doped buffer layer is used to separate active device region from substrate 12 out of 83
13 Growth Modes 3C Nucleation On-axis or low off-angle substrate Low step density and long terrace length Island nucleation of 3C-SiC High temperature required for homoepitaxy 13 out of 83
14 Growth Modes Step-flow Growth Substrate with larger off-cut angle high step density and short terrace length Step-flow growth with stable polytype at lower temperature Good film quality from step-controlled epitaxy 14 out of 83
15 Doping Control Covalent radii of dopants* Species Radius (Å) Si 1.17 C 0.77 N 0.74 P 1.10 Al 1.26 B 0.82 B-H 1.10 C Si Si CX Si Site-competition epitaxy: Doping control by adjusting C/Si ratio Increase C/Si ratio, N: ; Al: Other factors: growth pressure growth temperature growth rate substrate polarity (C-face/Si-face) off-cut angle *Data from D. J. Darkin, et. al., Phys. Status Solidi B, 202 p305, out of 83
16 Defect Reduction Epitaxy A B C D Substrate Epitaxy F E Substrate Propagation of defects from substrate into epilayer Defects propagated from substrate: A/B: micropipes C: threading edge/screw dislocations (TED/TSD); D: carrot defects E/F: basal plane dislocations BPD conversion Growth conditions: C/Si ratio; growth rate, off-cut angle Pre-growth treatment: KOH etching Lithographic patterning 16 out of 83
17 Epilayer Characterization TED TSD BPD Nomarski micrograph of epilayer surface after 8 min KOH etching Thickness measurement: Fourier transform infrared spectroscopy (FTIR) Doping measurement: Mercury probe (C-V), MOSC (C-V) Surface morphology characterization: Nomarski microscopy, Atomic force microscopy (AFM) Defect etches: Molten KOH etching (5~10 min at 520 o C) 17 out of 83
18 Si-face: Experimental Results on Epitaxial Growth of 4H-SiC Effects of different off-cut angles Carrier lifetimes of epilayers on Si-face C-face: Optimization of growth process to minimize defect densities 18 out of 83
19 Growth rate 8 o off-angle Growth rate increases almost linearly with SiH 4 flow The growth rate is constant for C/Si ratio >1.0, drops at C/Si ratio of 0.5 The growth rates on 8 o sample are larger than those on 4 o sample 19 out of 83
20 Nitrogen Doping 8 o off-angle Nitrogen incorporation decreases with C/Si ratio (site-competition) Doping concentrations on 8 o sample are slightly higher than those on 4 o sample Nitrogen incorporation decreases with decreasing growth pressure 20 out of 83
21 Surface Morphology-Nomarski Epilayers on 4 o substrate show extensive step-bunching, not on 8 o substrates Large surface defect densities are low on both substrates (less than 10 cm -2 ) Micropipes can be observed on epilayers grown under high C/Si ratio 21 out of 83
22 Surface Morphology-AFM 10 micron 5 micron Macrosteps on 4 o sample have height nm, and spacings increase with decreasing C/Si ratio. Steps on 8 o sample have height less than 0.5 nm and constant spacings Step crossover and hillocks on epilayers grown under high C/Si ratio. 22 out of 83
23 Basal Plane Dislocations 4 o off-angle 8 o off-angle Molten KOH etch at 520 o C for 10 minutes, BPDs are identified as ovalshaped etch pits and marked with white circles. BPD density on 4 o sample is much lower than that on 8 o sample under same C/Si ratio (1.5). 23 out of 83
24 Basal Plane Dislocations BPD densities decrease with increasing C/Si ratio BPD densities are reduced by growing on 4 o samples, the lowest BPD densities is 2.6 cm -2 at C/Si ratio of 2.0 The image force on the BPD near the surface is believed to encourage BPD conversion to TED: 24 out of 83
25 BPD Reduction by Pre-growth Treatments Pre-growth treatments: KOH etching; Lithographic patterning Disadvantages: more process steps; rough surface after growth (CMP is needed); generate new defects KOH etching 200µm KOH 100 µm 3min Litho Patterning 10 µm 7 µm 100 µm 20 µm 30 µm 25 out of 83
26 BPD Reduction by Pre-growth Treatments BPD densities decrease with increasing KOH etching time up to 5 min. The lowest BPD densities with KOH etching technique is 40 cm -2. When excessive KOH etching is performed, BPD density increases dramatically. BPD densities achieved by patterning technique is around 50 cm -2 Very low BPD densities (< 10 cm -2 ) can be achieved using multiple KOH etching steps under optimized conditions. 26 out of 83
27 Mechanism for Enhanced BPD conversion *Z. Zhang, et al., APL 89, p081910, 2006 In the KOH etch pits, the BPD propagation is blocked and converted into TED If lateral growth dominates. During the normal growth, small etch pits may be produced during H 2 etching. Enhanced lateral growth under high C/Si ratio help to promote the BPD conversion under those conditions. 27 out of 83
28 Minority Carrier Lifetime Control Defect Z1/Z2 EH6/EH7 Ti D-center Position in the band gap (ev) E C -( ) E C -( ) E C -( ) E V +( ) *Data from J. Zhang, et al., JAP 93, p4708, 2003 Deep level trap densities: DLTS (deep-level trap spectroscopy) Z1/Z2; EH6/EH7; D-center; Ti Lifetime characterization: Electron beam induced current (EBIC) Time-resolved photoluminescence (PL) Pulsed MOS capacitor (C-t) Reverse recovery (RR) Growth parameter correlations: C/Si ratio; growth temperature; susceptor purity 28 out of 83
29 Deep-level Traps Densities DLTS spectrum Arrhenius plot EH6/EH7 Three deep level traps are detected by DLTS from a Schottky structure Concentration of the traps are relatively low, which should correspond to a long minority carrier lifetime 29 out of 83
30 Effects of C/Si Ratio on Deep-level Trap Densities DLTS is performed on several sets of samples grown under different C/Si ratios. Generally, Z1/Z2 and EH6/EH7 trap densities decrease with C/Si ratio. Trap densities vary from set to set, indicating other lifetime-limiting factors. 30 out of 83
31 Lifetime Measurement on n-type epilayer 1.07µsec λ =391nm 0.72µsec W1 W2 Si Face W3 Minority carrier diffusion length (L d ) is deduced of EBIC signal. The bulk minority carrier lifetime estimated from L d is around 1.45 μsec. Minority carrier lifetimes of a 182-μm epilayer measured by time-resolved PL is around 1 μsec. This is sufficient for IGBT device applications. 31 out of 83
32 Si-face: Experimental Results on Epitaxial Growth of 4H-SiC Effects of different off-cut angles Carrier lifetimes of epilayers on Si-face C-face: Optimization of growth process to minimize defect densities 32 out of 83
33 Why C-face 4H-SiC? Comparison of Si-face and C-face PARAMETERS Surface morphology Step bunching Si-face good good C-face good better Epilayers on C-face 4H-SiC show some good properties C-face is also suitable for low off-angle and on-axis growth BPD density On-axis growth Low off-angle growth Growth window n - doping P + doping high Not possible hard wide easy easy low possible easy narrow difficult difficult Narrow growth window and difficulties in controlling doping limit C-face device applications N-type C-face epitaxial growth on 4 o off-angle substrate will be discussed in this work 33 out of 83
34 C-face Epilayers by Standard Growth Process C-face Si-face VS 200µm C/Si ratio=2.0, 1600 o C 2 µm buffer + 10µm epilayer C/Si ratio=2.0, 1600 o C 5 µm buffer + 40µm epilayer Surface morphology of C-face epilayers is much worse than that of Si-face epilayers if the same standard growth process is used. 34 out of 83
35 Surface Morphology under different N 2 flow and C/Si ratios 2.0 µm [1120] µm 2.5 µm 0 Under high N 2 flow, surface starts to deteriorate at C/Si ratio of 2.0. Triangular pits are aligned perpendicular to the off-cut direction Under low N 2 flow, triangular pits start to appear on surface at higher C/Si ratio with density of 10 cm -2 (C/Si=2.0) and 17 cm -2 (C/Si=3.0) µm 35 out of 83
36 Nitrogen-induced Step Bunching nm µm nm All images are 3µm 3µm collected by AFM in tapping mode µm Macrostep bunching has been observed under high N 2 flow conditions. No step bunching is found on samples grown under low N 2 flow conditions Step-height is about 10~15 nm on samples under high N 2 flow; while step-height is about 0.25~0.5nm (1~2 bilayers) on samples under low N 2 flow. 36 out of 83
37 Effects of C/Si Ratio on Surface Roughness and Doping Concentration RMS roughness (nm) N2: 1800 sccm N2: sccm Doping Concentration (cm -3 ) N2: 1800 sccm N2: sccm SIMS C-V C/Si ratio C/Si ratio Surface roughness is about one order of magnitude higher for high N 2 flow condition. RMS increases with C/Si ratios for heavily-doped samples. Site-competition effect has been observed on the lightly-doped epilayers, but not on the heavily-doped epilayers. 37 out of 83
38 Effects of N 2 flow on Surface Roughness and Doping Concentration RMS roughness (nm) C/Si atio= Nitrogen Flow (sccm) Doping Concentration (cm -3 ) SIMS C/Si ratio= Nitrogen Flow (sccm) Surface roughness decreases with N 2 flow. Step-bunching can be significantly reduced with proper N 2 flow setting. Doping concentration under high N 2 flow condition decreases only slightly with N 2 flow. 38 out of 83
39 Effect of Growth Temperature on Defect Densities 1600 o C 1620 o C Triangular defect Defect Densities (cm -2 ) 1E+05 1E+04 1E+03 1E+02 1E+01 1E+00 1E-01 Growth Pit Triagular Pit Growth Temperature 1640 o C Growth Pits 200µm C/Si ratio=2.0, N 2 : sccm Shallow growth pit densities increase with growth temperature, while the triangular pit densities decrease. The optimum growth temperature is around 1620 o C. 39 out of 83
40 Modified C-face Epitaxial growth process Device layer C/Si ratio>2.0; Low N 2 flow Temperature=1620 o C Buffer layer C/Si ratio=1.0; High N 2 flow (~500 sccm) C-face 4H-SiC substrate Grow buffer layer at lower C/Si ratio under proper N 2 flow condition. Grow device layer at higher C/Si ratio to obtain low doping concentration. Grow at optimum growth temperature to minimize both the triangular defects and growth pits. 40 out of 83
41 High-voltage Pin Diodes Fabrication Au Ti/Al P + N - drift layer N D ~ low cm -3 N + buffer layer N + 4H-SiC Substrate Ni Forward operation of the 4H-SiC pin diodes will be discussed with an emphasis on forward voltage degradation issue. 41 out of 83
42 8 o Pin Diodes Forward Characteristics V F at 100 A/cm 2 is 4.1 V for 100-micron diameter device, and V F increase with device size. The diodes exhibit an ideality factor of 2.0 in the low current region. 42 out of 83
43 Forward Voltage Stressing on 8 o off-angle Substrates V F at 100 A/cm 2 increases from 4.1 V to 5.8 V after 34 hours of stressing at 100 A/cm 2. V F drifts for a period of time, and then stabilizes during the test. 43 out of 83
44 Forward Voltage Drift on 8 o off-angle Substrate Larger devices (0.5mm 2 ) are stressed at 100 A/cm 2 for 2 hours cross the wafer. The averaged V F drifts over ten diodes is about 4 V. The largest drift measured is about 12 V. 44 out of 83
45 Forward Voltage Instability Si (g) Si (g) C (g) 100mA, 300mA, 1mA, 500mA, 2sec 4sec5sec C (g) Nucleation site Light emission microscopy (LEM) is used to monitor the motion of stacking fault (SF). SF is nucleated at BDP and expand under the forward bias. *M. Skowronski, et al., JAP 92 (8), p4699, out of 83
46 4 o Pin Diodes Forward Characteristics PiN diodes are built on 50 µm thick 4 o off-angle epilayer with doping of cm -3 grown under C/Si ratio of 2.0. V F at 100 A/cm 2 is 3.3 V for 100-micron diameter device, and V F increase with device size. The diodes exhibit an ideality factor of 1.7 in the low current region. 46 out of 83
47 Forward Voltage Stressing on 4 o off-angle Substrates V F at 100 A/cm 2 drops from 3.49 V to 3.45 V after 22 hours of stressing at 100 A/cm 2 due to the heating effect during the stress. After cooling, V F drifts is measured to be about 50 mv for this diode. 47 out of 83
48 Forward Voltage Drift on 4 o off-angle Substrate Larger devices (0.5mm 2 ) are stressed at 100 A/cm 2 for 2 hours cross the wafer. The averaged V F drifts over ten diodes is less than 100mV. The largest drift measured is only 300 mv. 48 out of 83
49 Conclusions: SiC Epitaxy A thorough study of epilayers grown on substrates with different off-cut angle is performed for the first time. High quality Si-face 4H-SiC epilayers with low defect densities: surface defect densities < 10 cm -2, BPD density ~2.6 cm -2 (4 o substrate). A detailed investigation of epitaxial growth on 4 o off-angle C-face 4H-SiC is performed for the first time. C-face epilayers with low surface defect densities are grown under optimized growth conditions. High purity Si-face 4H-SiC n-type thick epilayers with low deep level trap densities and long carrier lifetime (~1 μsec). Correlation between deep level trap densities and C/Si ratio is established. Thick epilayer with thickness of 182 μm, doping of 1x10 14 cm -3 and high minority carrier lifetime is grown at Purdue and is being used for n- channel IGBT fabrication. Pin diode with V F of 3.3 V at 100 A/cm 2 and minimal forward voltage drift (<100 mv) is demonstrated on low off-angle epilayers for the first time. 49 out of 83
50 MOS Channel Mobility: Background MOS inversion layer mobility in 4H-SiC is low (typically ~10-20 cm 2 /Vs) 4H-SiC exhibits a high density of interface states in the upper half of the bandgap Post-oxidation annealing in nitric oxide (NO) can reduce D IT and increase µ EFF 50 out of 83
51 Interface State Density on SiC Measured on P-Type SiC Measured on N-Type SiC Interface State Density (ev -1 cm -2 ) (0001) Silicon Face 6H-SiC 4H-SiC 6H-SiC 4H-SiC E C (6H) E C (4H) E - E v (ev) 51 out of 83
52 Interface States and MOS Mobility Metal Oxide 4H-SiC E C Few electrons in the inversion layer E F V G E V E F Distribution of interface states across the bandgap Large negative charge trapped in interface states 52 out of 83
53 Effect of Interface States Room Temperature High Temperature Metal Oxide 4H-SiC Metal Oxide 4H-SiC E C E C VG E F E V V G E F E V E i - i -E F large F E i - i -E F small F 53 out of 83
54 Effect of Nitric Oxide POA on D IT Interface State Density (ev (ev -1-1 cm -2-2 ) ) H-SiC LPCVD H Burn 2 Wet Ox LPCVD Dry Ox ONO NO NO Wet Ox H2 Burn NO NO NH 3 NH 3 Samples without POA Samples with Nitric Oxide POA E C - E (ev) 54 out of 83
55 Oxidation Schedule 1150 C Wet O 2 (Pyrogenic) 150 m 30 m Ar Wet O 2 (Pyrogenic) load 30 m 30 m unload 950 C H 2 :O 2 =6:5 H 2 O:O 2 =3:1 120 m 850 C 15 m (optional) NO NO Anneal, 1175 C, C, 2 hr. hr. (flow rate rate L // min.)
56 Basic MOSFET Equations I D = µ 0 1 ( V V ) C +θ G T ox W L ( VG VT ) VDS µeff g m I D µ 0 = = (1 ( VG V V +θ G T )) 2 C ox W L V DS I D g m = µ C W L V ( V V 0 ox DS G T ) 56 out of 83
57 Parameter Extraction I D /g m 1/2 µ0c W L ox V DS V T V G I D g m = µ C W V ( V V 0 ox DS G T L ) 57 out of 83
58 Temperature Dependence of I D / g m Without NO Anneal E C I D / g m 1/ Increasing T 352 C 169 C 102 C 56 C 18 C V G E F E V E i - i E F small E C Gate Voltage (V) V G E ii - E F large E F E V
59 Effect of NO Anneal Without NO Anneal With NO Anneal I D / g m 1/ C 18 C I D / g m 1/ C 19 C Gate Voltage (V) Gate Voltage (V) I D g m = µ C W V ( V V 0 ox DS G T L ) 59 out of 83
60 Effective Mobility (µ EFF ) Without NO Anneal With NO Anneal Effective Mobility (cm 2 /Vs) C 56 C 18 C C Effective Mobility (cm 2 /Vs) C C Gate Voltage (V) Gate Voltage (V) µ EFF = µ 0 / [1+θ(V G - V T )] 60 out of 83
61 Field-Effect Mobility (µ FE ) Field-Effect Mobility (cm 2 /Vs) Without NO Anneal C C C Gate Voltage (V) Field-Effect Mobility (cm 2 /Vs) With NO Anneal 19 C 344 C Gate Voltage (V) 61 out of 83
62 Parameters for Effective Mobility µ 0 Effective Mobility (cm 2 /Vs) Measured µ EFF = µ 0 / [1+θ(V G - V T )] V T Gate Voltage (V) 62 out of 83
63 Zero-Field Mobility (µ 0 ) Zero-Field Mobility (cm 2 /Vs) Without NO Anneal Zero-Field Mobility (cm 2 /Vs) With NO Anneal Temperature ( C) Temperature ( C) µ EFF = µ 0 / [1+θ(V G - V T )] 63 out of 83
64 Threshold Voltage (V T ) Without NO Anneal With NO Anneal Threshold Voltage (V) Threshold Voltage (V) Temperature ( C) Temperature ( C) µ EFF = µ 0 / [1+θ(V G - V T )] 64 out of 83
65 Mobility Parameters for NO-Annealed Samples µ EFF = µ 0 / [1+θ(V G - V T )] µ 0 = T x10-3 T x10-6 T 3 V T = T x10-5 T x10-8 T 3 θ = x10-5 T x10-7 T x10-10 T 3 where T is temperature in Celsius and 20 < T < 350
66 Comparison for NO Annealed FETs Effective Mobility (cm 2 /Vs) Measured Mobility C C Gate Voltage (V) C Gate Voltage (V) 344 C Effective Mobility (cm 2 /Vs) Mobility from Equations µ EFF = µ 0 / [1+θ(V G - V T )] 66 out of 83
67 Conclusions We have characterized the temperature dependence of MOSFET mobility in 4H-SiC Post-oxidation annealing in NO... - reduces interface state density - reduces threshold voltage - reduces temperature dependence - increases mobility
68 Matrix of Experiments NO Post-Ox Anneal (none) NO Gate Material Poly Metal X W Y Z A E C B F D 1200 C, Ar 1400 C Pillbox Implant Anneal Purdue Auburn Oxidation Procedure 68 out of 83
69 Experimental Comparisons Effect of S/D implant activation anneal Effect of gate oxidation procedure (AU vs PU) Effect of post-oxidation anneal in NO Effect of gate material (poly vs metal) Effect of ohmic contact anneal Effect of E-beam metal evaporation 69 out of 83
70 Measurement Techniques Constant Voltage Technique -- Hold V DS constant at ~ 50 mv -- Measure I D vs V G -- Mobility is erroneous if S/D are non-ohmic Constant Current Technique (NEW) -- Hold I D constant at 10, 50, or 90 na -- Measure V DS vs V G -- Eliminates effect of non-ohmic S/D contacts 70 out of 83
71 Comparison of Measurement Techniques 40 Before Contact Anneal 40 After Contact Anneal Mobility (cm 2 /Vs) Sample B: 4H-SiC N-MOSFET Implant Anneal :1200 C, Ar Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Contact Anneal: none Gate Voltage (V) MOSFET sample B before ohmic contact anneal. The S/D contacts are non-ohmic, and the constant voltage technique measures an artificially low mobility. Mobility (cm 2 /Vs) Sample B: 4H-SiC N-MOSFET Implant Anneal :1200 C, Ar Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Contact Anneal: 850 C Gate Voltage (V) MOSFET sample B after ohmic contact anneal. The S/D contacts are now ohmic, and the constant voltage technique measures a much higher mobility. 71 out of 83
72 Notes on Subsequent Mobility Plots On all subsequent plots, mobility is measured by the new constant current technique. In the constant current mobility plots, each data point is derived from measurements on 5-8 MOSFETs at each of four channel lengths (80, 100, 120, and 140 µm), for a total of MOSFETs. Each plot consists of two curves measured at drain currents of 50 and 90 na, respectively. The mobility determined at 50 na is plotted as solid symbols and the mobility at 90 na is plotted as open symbols. 72 out of 83
73 40 1: Effect of Post-Oxidation NO Annealing 1200 C Implant Anneal 1400 C Implant Anneal Mobility (cm 2 /Vs) B: with NO anneal Samples A & B: 4H-SiC N-MOSFET Implant Anneal :1200 C, Ar Oxide: Auburn Wet Ox + ReOx Gate: Poly Contact Anneal: 850 C Mobility (cm 2 /Vs) F: with NO anneal Samples E & F: 4H-SiC N-MOSFET Implant Anneal :1400 C, pillbox Oxide: Auburn Wet Ox + ReOx Gate: Poly Contact Anneal: 850 C 5 A: w/o NO anneal 5 E: w/o NO anneal Gate Voltage (V) MOSFET samples without NO annealing (A) and with NO annealing (B). The implant is annealed at 1200 C in Ar. Ohmic contacts are annealed at 850 C. The improvement in mobility is obvious Gate Voltage (V) MOSFET samples without NO annealing (E) and with NO annealing (F). The implant is annealed at 1400 C in a SiC pillbox. Ohmic contacts are annealed at 850 C. The improvement in mobility is obvious. 73 out of 83
74 40 2: Effect of Implant Anneal Conditions Before Contact Anneal 40 After Contact Anneal 35 B: 1200 C, Ar 35 B: 1200 C, Ar Mobility (cm 2 /Vs) F: 1400 C SiC Pillbox Samples B & F: 4H-SiC N-MOSFET Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Contact Anneal: none Gate Voltage (V) MOSFET sample B (annealed at 1200 C in Ar) and F (annealed at 1400 C in a SiC pilbox) before contact annealing. The sample annealed at 1200 C has slightly higher mobility. Mobility (cm 2 /Vs) F: 1400 C SiC Pillbox Samples B & F: 4H-SiC N-MOSFET Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Contact Anneal: 850 C Gate Voltage (V) MOSFET sample B (annealed at 1200 C in Ar) and F (annealed at 1400 C in a SiC pilbox) after contact annealing at 850 C. The mobility of the 1400 C sample is improved slightly by contact annealing but the mobility of the 1200 C sample is unchanged. 74 out of 83
75 40 3: Effect of Ohmic Contact Anneal 1200 C Implant Anneal C Implant Anneal Mobility (cm 2 /Vs) After Contact Anneal Before Contact Anneal Sample B: 4H-SiC N-MOSFET Implant Anneal :1200 C, Ar Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Gate Voltage (V) MOSFET sample B before contact anneal and after contact anneal. The implant is annealed at 1200 C in Ar and the oxide is annealed in NO. Very little change in mobility is observed. Mobility (cm 2 /Vs) After Contact Anneal Before Contact Anneal Sample F: 4H-SiC N-MOSFET Implant Anneal :1400 C, pillbox Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Gate Voltage (V) MOSFET sample F before contact anneal and after contact anneal. The implant is annealed at 1400 C in a SiC pillbox and the oxide is annealed in NO. The mobility is improved slightly by the 850 C contact anneal. 75 out of 83
76 4: Effect of Gate Material 40 Mobility (cm 2 /Vs) Poly Gate Metal (Mo) Gate Samples D & F: 4H-SiC N-MOSFET Implant Anneal :1400 C, pillbox Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Contact Anneal: 850 C Gate Voltage (V) MOSFET samples D (Mo gate) and F (poly gate). The implant is annealed at 1400 C in a SiC pillbox. Ohmic contacts are annealed at 850 C. Very little change in mobility is observed. 76 out of 83
77 Mobility (cm 2 /Vs) : Effect of Gate Oxide Procedure Auburn Oxidation Samples A, B, E, F: 4H-SiC N-MOSFET Implant Anneal :1200 C & 1400 C, Ar Oxide: Auburn Wet Ox + ReOx Gate: Poly Contact Anneal: 850 C B: 1200 C impl. ann. and NO anneal F: 1400 C impl. ann. and NO anneal Mobility (cm 2 /Vs) Samples W, X, Y, Z: 4H-SiC N-MOSFET Implant Anneal :1200 C & 1400 C, Ar Oxide: Purdue Wet Ox + ReOx Gate: Poly Contact Anneal: 850 C X: 1200 C impl. ann. and NO anneal Purdue Oxidation W: 1400 C impl. ann. and NO anneal Z: 1400 C impl. ann. 10 A: 1200 C impl. ann. E: 1400 C impl. ann Gate Voltage (V) Y: 1200 C impl. ann MOSFET samples A, B, E, and F are oxidized at Auburn and W, X, Y, and Z are oxidized at Purdue. Samples A, B, E, and F are fabricated on the same wafer, and samples W, X,Y, and Z are fabricated on a different wafer. Samples A, B, X, and Y are implant annealed at 1200 C in Ar. Samples E and F are implant annealed at 1400 C in a SiC pillbox, and samples W and Z are implant annealed at 1400 C in Ar. Samples B, F, W, and X are NO annealed at Auburn. All have poly gates fabricated at Purdue, and all received an 850 C ohmic contact anneal in vacuum at Purdue. The samples oxidized at Purdue appear to have higher mobility, especially at low gate voltage. 10 Gate Voltage (V) 77 out of 83
78 6: Effect of E-Beam Evaporation 40 Mobility (cm 2 /Vs) Before E-beam Ni Evap. After E-beam Ni evap. Sample F: 4H-SiC N-MOSFET Implant Anneal :1400 C, pillbox Oxide: Auburn Wet Ox + ReOx Oxide Anneal: NO Gate: Poly Contact Anneal: 850 C Gate Voltage (V) MOSFET sample F before and after E-beam evaporation of Ni. The original Ni ohmic contacts were deposited by sputtering. The implant is annealed at 1400 C in a SiC pillbox and the oxide is annealed in NO. The mobility is not affected by E-beam evaporation. 78 out of 83
79 Conclusions Effect of post-oxidation anneals in NO NO annealing increases the mobility by about a factor of five (from ~ 5 to ~ 30 cm 2 /Vs) (c.f. plot 1). Effect of gate oxidation procedure (AU vs PU) Purdue oxides have higher mobility than Auburn oxides at low gate fields. Both oxides are improved significantly by post-oxidation NO annealing (c.f. plot 5). 79 out of 83
80 Conclusions (Cont d) Effect of S/D implant anneal conditions The mobility of Auburn oxides is slightly higher when the implant is annealed at 1200 C in Ar, compared to 1400 C in a pillbox (c.f. plot 2). The mobility of Purdue oxides is slightly higher when the implant is annealed at 1400 C in Ar, compared to 1200 C in Ar (c.f. plot 5). 80 out of 83
81 Conclusions (Cont d) Effect of ohmic contact anneal On samples that are implant annealed at 1200 C in Ar, the ohmic contact anneal has no effect on mobility (c.f. plot 3). On samples that are implant annealed at 1400 C in a SiC pillbox, an ohmic contact anneal at 850 C improves the mobility slightly (c.f. plot 3). 81 out of 83
82 Conclusions (Cont d) Effect of gate material (metal vs poly) Gate material (Mo vs polysilicon) has no effect on MOSFET mobility (c.f. plot 4). Effect of E-beam evaporation of ohmic contacts E-beam evaporation has no effect on MOSFET mobility (c.f. plot 6). 82 out of 83
83 Acknowledgement James Cooper, Purdue University Dr. Robert Stahlbush, Naval Research Lab Prof. Marek Skowronski s group, Carnegie Mellon University Wenzhou Chen, Micron Technologies Funding provided by DARPA, ONR and the Indiana 21 st Century Fund 83 out of 83
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