Linseed Stand Oil, 45 P

Transcription

1 Revised edition: Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Linseed Stand Oil, 45 P Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Binding agent Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards 2

2 Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: Polymerized linseed oil. CAS No , EINECS REACH Reg No.: XXXX Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air and seek medical advice in case of complaints. Wash off with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes. Seek medical attention if irritation persists After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. If symptoms persist consult physician. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. CO2, extinguishing powder, water jet. Fight larger fire with water jet or alcohol resistant foam Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet. Special hazards: In case of fire: formation of carbon monoxide and dioxide, and 3

3 5. 3. Advice for Firefighters possibly acrolein. Adsorbed product tends to ignite spontaneously. Page 3 Protective equipment: Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system Personal precautions: Environmental Precautions Wear protective clothing. Avoid contact with eyes and skin. Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent spillage of large quantities into drains and surface waters Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with inert absorbent material and dispose as hazardous waste. Do not use flammable material, e.g. saw dust! Protective clothing, see Section 8. See Section 13 for information on disposal. Avoid contact with eyes. Do not breathe vapors, aerosols. Combustible materials, like textiles and paper, which have been soiled by the product, can self-ignite when the water content has evaporated. Contaminated materials have to be washed immediately with plenty of water Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash hands with soap and water. Avoid repeated and longterm contact with skin. Storage conditions: Requirements for storage areas and Store in tightly sealed containers in a dry and cool room. Protect from direct exposure to light. Store at temperatures between 10 and 30 C. 4

4 containers: Storage: In the original container. Water law provisions have to be met. Page 4 Information on fire and explosion protection: Storage class (VCI): Absorbed product has the tendency to self-ignite. Keep away from sources of ignition - do not smoke. Take measures to prevent electrostatic discharge. Do not spray on flames or glowing bodies. 10 Combustible liquids (TRGS 510, Storage of hazardous materials in transportable containers) Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled None known Parameters to be controlled (DE): Parameters to be controlled (EC): Derived No-Effect Level (DNEL): 0.25 mg/kg bw/d (consumer, swallowing, long-term exposition - systemic) 2.5 mg/kg bw/d (consumer, skin contact, long-term exposition - systemic) 5 mg/kg bw/d (worker, skin contact, long-term exposition - systemic) 0.43 mg/m3 (consumer, inhalation, long-term exposition - systemic) 1.76 mg/m3 (worker, inhalation, long-term exposition - systemic) Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Remove contaminated clothing immediately. Do not inhale gas/fumes/vapor/aerosol. Avoid contact with skin, eyes and clothing. Wash hands before breaks and after work. Respiratory protection: 5

5 Not required. Page 5 Hand protection: Protective glove material: Eye protection: Body protection: Protective gloves. The glove material has to be impermeable and resistant to the product / substance / preparation. Nitrile rubber Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Tightly fitting safety goggles (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: viscous bright yellow characteristic not determined C not determined Flash point: > 328 C Evaporation rate: Flammability (solid, gas): 425 C Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: < hpa Vapor density: Density: g/cm3 (20 C) 6

6 Solubility in water: < g/l Page 6 Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: > 6 logpow no information available Decomposition temperature: 350 C Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: dpa.s Product does not present an explosion hazard. not oxidizing not determined No further information. No decomposition if used according to specifications. Stable if used according to specifications. Finely distributed hot particles have the tendency to self-ignite. Avoid contact with heat, sparks, impact, friction, sparks and static discharge. Thermal decomposition: Avoid heat Imcompatible Materials Strong oxidizing agents Hazardous Decomposition Products Carbon monoxide and dioxide. 7

7 Acrolein Further Information 11. Toxicological Information Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: 4897 mg/kg (rat; OECD 401) NOAEL: > 1000 mg/kg/d (rat; OECD 422) LD50, dermal: > 2000 mg/kg (rat; OECD 402) LC50, inhalation: not determined Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Non irritating Non-irritating to eyes No information available No sensitizing effects known. No data available. No data available. No data available. No health impairments known or expected when used according to specifications. LC50: > 1000 mg/l (96h, Danio rerio; OECD 203) Daphnia toxicity: EC50: > 100 mg/l (48h, Daphnia magna; OECD 202) 8

8 Bacteria toxicity: EC50: > 100 mg/l (3h, active sludge; OECD 209) Page Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: EC50: > 100 mg/l (72h, Pseudokirchneriella subcapitata) Not readily biodegradable. log Pow: > 6 Expected to adsorb on soil. Not applicable. 1, slightly hazardous Must not be disposed together with household garbage. Do not let product enter water systems. Dispose of according to official local regulations. No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Classification code: 9

9 Tunnel no.: Page 9 IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Not classified as environmentally hazardous. Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Not classified as a dangerous good under transport regulations. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water (self-assessment) Not listed. Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Not applicable. A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.